Gravimetric Analysis
International Series of Monographs on Analytical Chemistry, Vol. 7
Published on 3. September 2013
814 pages
978-1-4832-2267-7 (ISBN)
Description
Analytical Chemistry, Volume 7: Gravimetric Analysis, Part II describes the experimental procedures for the gravimetric analysis of Groups I to V cations. This book is composed of 43 chapters that also present sample preparation, separation, and precipitation protocols. The first six chapters include Group I cations, such as silver, lead, mercury, copper, bismuth, and cadmium, followed by chapters on Group II cations, including arsenic, antimony, tin, germanium, gold, platinum, selenium, and tellurium. The subsequent chapters explore the gravimetric determination of Group III cations, namely, aluminum, iron, chromium, nickel, cobalt, zinc, manganese, titanium, zirconium, hafnium, thorium, scandium, niobium and tantalum, molybdenum, tungsten, vanadium, uranium, thallium, indium, gallium, and beryllium. The remaining chapters are devoted to analysis of various forms of Groups IV and V cations. This book will prove useful to analytical and inorganic chemists, teachers, and students in the allied fields.
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Content
Group I Cations 5. Silver 5.1. Determination in the Form of Silver Chloride 5.2. Determination in the Form of Silver Bromide 5.3. Determination as Metallic Silver after Reduction with Ascorbic Acid 5.4. Determination in the Form of Metallic Silver by Electrolysis 5.5. Determination of Silver by Fire-Assay 5.6.-5.17. The Separation of Ag References 6. Lead 6.1. Determination in the Form of Lead Sulphate 6.2. Determination in the Form of Lead Chromate 6.3. Electrolytic Deposition of Lead in the Form of Lead Dioxide 6.4. Determination in the Form of Lead Chloride 6.5. Determination in the Form of Lead Sulfite 6.6.-6.21. The Separation of Pb References 7. Mercury 7.1.-7.3. Determination in the Form of Mercury(II) Sulphide 7.4. Determination in the Form of Mercury(I) Chloride 7.5. Determination in the Form of Metallic Mercury after Reduction with Ascorbic Acid 7.6. Determination in the Form of Metallic Mercury by Electrolysis 7.7. Determination in the Form of Metallic Mercury by a Dry Method 7.8. Determination of Mercury(I) Ions in the Form of Mercury(I) Chromate 7.9. Determination of Mercury(I) Ions in the Form of Mercury(I) Iodate 7.10.-7.16. The Separation of Hg References 8. Copper 8.1. Determination in the Form of Metallic Copper by Electrolysis 8.2. Determination in the Form of Copper(I) Thiocyanate 8.3. The Determination of Copper by Precipitation in the Form of its Sulphide 8.4. Determination of Copper in the Form of Copper(I) Iodide 8.5. Determination of Copper in the Form of Copper(II) Oxide 8.6. Determination of Copper in the Form of Copper(II) Quinaldinate 8.7. Precipitation of Copper(II) Ions with 8-Hydroxyquinoline 8.8.-8.23. The Separation of Cu References 9. Bismuth 9.1. Determination in the Form of Bismuth(III) Oxide 9.2. Precipitation in the Form of basic Bismuth Carbonate 9.3. Precipitation in the Form of basic Bismuth Formate 9.4. Determination in the Form of Bismuthyl Chloride 9.5. Determination in the Form of Bismuthyl Iodide 9.6. Determination in the Form of Bismuth(III) Phosphate 9.7. Determination in the Form of Bismuth(III) Sulphide 9.8. The Deposition of Metallic Bismuth by Electrolysis 9.9. Precipitation of Bismuth in the Metallic Form Using Formaldehyde 9.10.-9.21. The Separation of Bi References 10. Cadmium 10.1. Determination in the Form of Cadmium Sulphate 10.2. Determination in the Form of Cadmium Sulphide 10.3. Determination by Precipitation in the Form of Cadmium Ammonium Phosphate 10.4. Deposition in the Form of Metallic Cadmium by Electrolysis 10.5. Determination in the Form of Cadmium Hydrazine Iodide 10.6. Determination in the Form of Cadmium Quinaldinate 10.7. Precipitation of Cadmium with 8-Hydroxyquinoline 10.8.-10.17. The Separation of Cd ReferencesGroup II Cations 11. Arsenic 11.1. Determination of Arsenic in the Form of Arsenic(III) Sulphide 11.2. Determination of Arsenic in the Form of Arsenic(V) Sulphide 11.3. Determination in the Form of Arsenic(III) Sulphide and Sulfur 11.4. Precipitation in the Form of Magnesium Ammonium Arsenate 11.5. Determination in the Form of Silver Arsenate 11.6.-11.19. The Separation of As References 12. Antimony 12.1. Determination in the Form of Antimony(III) Sulphide 12.2. Determination in the Form of Antimony Tetroxide 12.3.-12.10. The Separation of Sb References 13. Tin 213 13.1. Precipitation of Tin in the Form of Stannic Acid 13.2.
