
The Enzymes
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Content
- Front Cover
- The Enzymes: Carboxylation and Decarboxylation (Nonoxidative) Isomerization
- Copyright Page
- Contents
- List of Contributors
- Preface
- Contents of Other Volumes
- Chapter 1. Pyruvate Carboxylase
- I. Introduction
- II. Properties and Mechanism
- III. Structure
- IV. Regulatory Properties
- V. Conclusion
- Chapter 2. Acyl-CoA Carboxylases
- I. Introduction
- II. ß-Methylcrotonyl-CoA Carboxylase
- III. Propionyl-CoA Carboxylase
- IV. Acetyl-CoA Carboxylase
- Chapter 3. Transcarboxylase
- I. Introduction
- II. Molecular Properties of Transcarboxylase
- III. Catalytic Properties of Transcarboxylase
- Chapter 4. Formation of Oxalacetate by C02 Fixation on Phosphoenolpyruvate
- I. Introduction
- II. Phosphoenolpyruvate Carboxylase (PEPC)
- III. Phosphoenolpyruvate Carboxykinase (PEPCK)
- IV. Phosphoenolpyruvate Carboxytransphosphorylase (PEPCTrP)
- V. Concluding Remarks
- Chapter 5. Ribulose-1,5-Diphosphate Carboxylase
- I. Introduction
- II. Molecular Properties
- III. Catalytic Process
- Chapter 6. Ferredoxin-Linked Carboxylation Reactions
- I. Introduction
- II. Enzymes Catalyzing Ferredoxin-Linked Carboxylation Reactions
- III. Reductive Carboxylic Acid Cycle of Bacterial Photosynthesis
- IV. Reductive Monocarboxylic Acid Cycle of Fermentative Metabolism
- V. Concluding Remarks
- Chapter 7. Amino Acid Decarboxylases
- I. Introduction
- II. Metabolic Importance of the Decarboxylases
- III. Distribution and General Properties of Decarboxylases
- IV. Mechanism of Action
- V. The Active Site of Amino Acid Decarboxylases
- VI. Subunit Structure
- Chapter 8. Acetoacetate Decarboxylase
- I. Introduction
- II. Properties of the Enzyme
- III. Catalytic Properties
- Chapter 9. Aldose-Ketose Isomerases
- I. Introduction
- II. Glucose-6-phosphate Isomerase
- III. Mannose-6-phosphate Isomerase
- IV. Glucosamine-6-phosphate Isomerase
- V. Ribose-5-phosphate Isomerase
- VI. Arabinose-5-phosphate Isomerase
- VII. Triosephosphate Isomerase
- VIII. Aldose-Ketose Isomerases Acting on Nonphosphorylated Sugars
- Chapter 10. Epimerases
- I. Introduction
- II. UDP-D-Glucose 4'-Epimerase
- III. Other Epimerases That Potentially Involve Oxidation-Reduction
- IV. Epimerases Which Probably Proceed by a Keto-Enol Rearrangement
- V. Noncarbohydrate Epimerases
- Chapter 11. Cis-Trans lsomerization
- I. Enzymic Cis-Trans Isomerization about Carbon-Carbon Double Bonds
- II. Nonenzymic Cis-Trans Isomerization about Carbon-Carbon Double Bonds
- Chapter 12. Phosphomutases
- I. Introduction
- II. Phosphoglucomutase
- III. Other Sugar Phosphate Mutases
- IV. Phosphoglycerate Mutase
- V. Diphosphoglycerate Mutase
- Chapter 13. Amino Acid Racemases and Epimerases
- I. Introduction
- II. History and Survey
- III. Assay Methods
- IV. Specificity, Equilibria, and Kinetics
- V. Cofactors
- VI. Mechanism of Action
- VII. Physiological Aspects
- Chapter 14. Coenzyme B12-Dependent Mutases Causing Carbon Chain Rearrangements
- I. Introduction
- II. Methylmalonyl-CoA Mutase
- III. Glutamate Mutase
- IV. a-Methyleneglutarate Mutase
- Chapter 15. B12 Coenzyme-Dependent Amino Group Migrations
- I. Introduction
- II. Deaminases
- III. Enzymes That Catalyze Migrations of ?-Amino Groups of Diamino Acids
- IV. Reaction Mechanisms
- V. Role of Amino Group Migration Reactions in Bacterial Fermentations
- Chapter 16. lsopentenylpyrophosphate Isomerase
- I. Introduction
- II. The Catalytic Reaction
- Chapter 17. lsomerization in the Visual Cycle
- I. Introduction
- II. Site of Visual Pigments in the Photoreceptor
- III. Molecular Properties of Visual Pigments
- IV. Interaction of Light with Visual Pigment
- V. Visual Pigment Regeneration following Illumination
- Retinal Isomerase
- VI. Concluding Remarks
- Chapter 18. ?5-3-Ketosteroid Isomerase
- I. Introduction
- II. ?5-3-Ketosteroid Isomerase of Pseudomonas testosteroni
- III. ?5-3-Ketosteroid Isomerases of Animal Tissues
- Author Index
- Subject Index
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