Graphite Intercalation Compounds and Applications
Published on 27. March 2003
453 pages
978-0-19-535184-2 (ISBN)
Description
Graphite intercalation compounds are a new class of electronic materials that are classified as graphite-based host guest systems. They have specific structural features based on the alternating stacking of graphite and guest intercalate sheets. The electronic structures show two-dimensional metallic properties with a large variety of features including superconductivity. They are also interesting from the point of two-dimensional magnetic systems. This book presents the synthesis, crystal structures, phase transitions, lattice dynamics, electronic structures, electron transport properties, magnetic properties, surface phenomena, and applications of graphite intercalation compounds. The applications covered include batteries, highly conductive graphite fibers, exfoliated graphite and intercalated fullerenes and nanotubes.
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Toshiaki Enoki | Morinobu Endo | Masatsugu Suzuki
Graphite Intercalation Compounds and Applications
Book
04/2003
Oxford University Press Inc
€322.90
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Content
- Intro
- Contents
- 1 Introduction
- References
- 2 Synthesis and Intercalation Chemistry
- 2.1 Donor Intercalation Compounds
- 2.2 Ternary Intercalation Compounds
- 2.3 Acceptor Intercalation Compounds
- 2.4 Bi-intercalation Compounds
- References
- 3 Structures and Phase Transitions
- 3.1 Overview and Definition
- 3.2 Liquid State in Stage-2 Alkali Metal GICs
- 3.3 Phase Transition in Stage-2 Alkali Metal GICs
- 3.4 In-Plane Structure Model in High-Stage Alkali Metal GICs
- 3.5 Liquid-Solid Transition in K GIC
- 3.6 Two-Dimensional Melting in Stage-1 Rb GIC
- 3.7 Staging Structure
- 3.8 Hendricks-Teller Stage Disorder
- 3.9 Fractional Stage
- 3.10 Stripe Domain Phase in Br[sub(2)] GIC
- 3.11 Phase Transition in SbCl[sub(5)] GIC
- 3.12 Ordering Kinetics
- References
- 4 Lattice Dynamics
- 4.1 Phonon Dispersion in Alkali Metal GICs (Theory)
- 4.2 Phonon Dispersion in Alkali Metal GICs (Experiment)
- 4.3 Raman Scattering
- 4.4 Donor-Acceptor Graphite Bi-intercalation Compound
- 4.5 Intercalate Diffusion
- References
- 5 Electronic Structures
- 5.1 Band Structure of Graphite, and Tight Binding Model for GICs
- 5.2 Acceptor GICs
- 5.3 Alkali Metal GICs
- 5.4 GICs with Novel Intercalates
- References
- 6 Electron Transport Properties
- 6.1 In-Plane Electron Transport Process
- 6.2 c-Axis Conduction Process
- 6.3 Weak Localization
- 6.4 Transport Properties of Magnetic GICs
- 6.5 Superconductivity
- References
- 7 Magnetic Properties
- 7.1 Overview
- 7.2 Stage-2 CoCl[sub(2)] GIC
- 7.3 Stage-2 MnCl[sub(2)] GIC
- 7.4 Stage-2 CuCl[sub(2)] GIC
- 7.5 Stage-2 FeCl[sub(3)] GIC
- 7.6 Stage-1 Eu GIC (EuC[sub(6)])
- 7.7 Magnetic Ternary (Quaternary) GICs
- References
- 8 Surface Properties and Gas Adsorption
- 8.1 Gas Physisorption in Alkali Metal GICs
- 8.2 Surface Properties and Monolayer
- References
- 9 GICs and Batteries
- 9.1 Application of Intercalated Graphite in Primary Battery System
- 9.2 Secondary Battery Applications as Li Ion Battery
- References
- 10 Highly Conductive Graphite Fibers
- 10.1 Introduction
- 10.2 Structure and Staging
- 10.3 Intercalate-Induced Enhancement of Conductivity
- 10.4 Stability of Intercalated Graphite Fibers
- 10.5 Fluorine-Intercalated Graphite Fibers with Ionic Bonding
- 10.6 Conclusions
- References
- 11 Exfoliated Graphite Formed by Intercalation
- 11.1 Introduction
- 11.2 Structural Variation after the Exfoliation Process
- 11.3 Exfoliation Process
- 11.4 Exfoliated Graphite Fibers
- 11.5 Applications
- 11.6 Conclusions
- References
- 12 Intercalated Fullerenes and Carbon Nanotubes
- 12.1 Introduction
- 12.2 Preparation and Structure of Pristine and Intercalated Fullerenes
- 12.3 Preparation and Structure of Intercalated Carbon Nanotubes and Potential Applications
- 12.4 Conclusions
- References
- Index
- A
- B
- C
- D
- E
- F
- G
- H
- I
- J
- K
- L
- M
- N
- O
- P
- Q
- R
- S
- T
- U
- V
- W
- X
- Z
