High Resolution Nuclear Magnetic Resonance Spectroscopy

ForewordPreface10. Correlations of 1H Resonance Spectral Parameters with Molecular Structure Alkanes 10.1 Chemical Shifts of Alkane Derivatives 10.1.1 Correlation of Electronegativity of Substituents with 1H Chemical Shifts of Methyl Derivatives, CH3X 10.1.2 Correlation of Chemical Shift Parameters with the Electronegativity of Substituents in Ethyl Derivatives 10.1.3 Propyl and Isopropyl Derivatives 10.1.4 Contributions to the Shielding of Hydrogen Nuclei from C-H and C-C Bond Anisotropic Effects 10.2 Spin-Spin Coupling Constants in Alkane Derivatives 10.2.1 Coupling Constants between Geminal Hydrogen Nuclei on Saturated Carbon Atoms 10.2.2 Coupling Constants between Hydrogen Nuclei on Adjacent Carbon Atoms 10.2.3 Signs of H-H Coupling Constants 10.2.4 Long Range Coupling Constants between Hydrogen Cuclei in Saturated Systems 10.3 Miscellaneous Alkyl Compounds 10.3.1 Group IVB Methyl Derivatives 10.3.2 Alkyl Derivatives of Elements having Nuclear Magnetic Moments 10.3.3 Miscellaneous Metal Alkyl Derivatives 10.3.4 2,3-Disubstituted Butanes 10.3.5 Cyclopropane and Its Derivatives 10.3.6 Cyclohexane Derivatives Alkenes 10.4 Vinyl Derivatives, CH2=CHX 10.4.1 Correlation between Geminal Coupling Constants, JGEM/HH, and the H-C-H Bond Angles 10.4.2 Vicinal Coupling Constants in Alkenes 10.4.3 Correlation between Coupling Constants and the Electronegativities of the Substituents in Vinyl Derivatives 10.4.4 Changes in Chemical Shifts in Vinyl Groups with Changes in the Electronegativity of the Substituents 10.4.5 Correlation of Chemical Shifts in Vinyl Systems with Hammett a-Constants 10.4.6 Correlation of Chemical Shifts in Vinyl Systems with Group Dipole Moments 10.4.7 Anomalous 1H Chemical Shifts in Vinyl Systems 10.4.8 Vinyl Chloride and Chloroethylenes 10.4.9 Propene-1, Butene-1 and Hexene-1 10.4.10 Spin Coupling Constants in Alkene-1 Derivatives 10.5 Disubstituted Olefines 10.5.1 Cis- and Trans-Disubstituted Olefines 10.5.2 2-Substituted Propenes 10.5.3 2,3-Disubstituted Propenes 10.5.4 The Effects of Methyl Group Substitution on the 1H Resonance Spectra of Ethylenic Molecules 10.6 Trisubstituted Olefines 10.6.1 1-Substituted Isobutenes 10.6.2 aß-Unsaturated Esters 10.7 Long Range Spin Coupling via Olefinic Systems 10.8 Miscellaneous Olefines 10.8.1 Conjugated Dienes 10.8.2 Metal Alkene Derivatives 10.8.3 Methyl Groups in Conjugated Polyenes 10.8.4 Induced Ring Currents in Annulenes Acetylenes 10.9 Acetylene and Related Molecules 10.9.1 Propargyl Kalides, XCH2C=CH 10.10 Spin-Spin Coupling Constants in Acetylenic Systems 10.11 Solvent Effects on the Chemical Shifts of Hydrogen Nuclei in Acetylenic Molecules Aromatic Molecules 10.12 Benzene Derivatives 10.12.1 The Effects of Solvents on the Resonance Spectra of Aromatic Compounds 10.12.2 Mono-substituted Benzenes 10.12.3 Correlation of 1H Chemical Shifts in Mono-substituted Benzenes with Hammett s-Constants 10.12.4 Disubstituted Benzene Derivatives 10.12.5 Halogenated Benzene Derivatives 10.12.6 Substituted Xylenes 10.12.7 Hydroxy Benzenes 10.12.8 Aromatic Alkoxy Compounds 10.12.9 Aromatic Aldehydes 10.12.10 Trisubstituted Benzenes 10.12.11 Biphenyls 10.12.12 Indene 10.12.13 Aromatic Ring Currents 10.13 Polynuclear Aromatic Molecules 10.14 Spin-Spin Coupling in Aromatic Molecules 10.15 Aromatic Ions 10.15.1 Triaryl Carbonium Ions 10.15.2 9,10-Dimethyl-1,2-Benzanthracene Carbonium Ion and Other Aromatic Carbonium Ions 10.15.