Spectroscopic Properties of Inorganic and Organometallic Compounds
Volume 10
1st Edition
Published on 31. October 2007
504 pages
978-1-84755-494-9 (ISBN)
Description
Spectroscopic Properties of Inorganic and Organometallic Compounds provides a unique source of information on an important area of chemistry. Divided into sections mainly according to the particular spectroscopic technique used, coverage in each volume includes: NMR (with reference to stereochemistry, dynamic systems, paramagnetic complexes, solid state NMR and Groups 13-18); nuclear quadrupole resonance spectroscopy; vibrational spectroscopy of main group and transition element compounds and coordinated ligands; and electron diffraction. Reflecting the growing volume of published work in this field, researchers will find this Specialist Periodical Report an invaluable source of information on current methods and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading experts in their specialist fields, this series is designed to help the chemistry community keep current with the latest developments in their field. Each volume in the series is published either annually or biennially and is a superb reference point for researchers. www.rsc.org/spr
More details
Series
Edition
1. Auflage
Language
English
Place of publication
Cambridge
United Kingdom
Target group
Professional and scholarly
ISBN-13
978-1-84755-494-9 (9781847554949)
DOI
10.1039/9781847554949
Copyright in bibliographic data and cover images is held by Nielsen Book Services Limited or by the publishers or by their respective licensors: all rights reserved.
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01/1977
Royal Society of Chemistry
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Content
- Spectroscopic Properties Of Inorganic And Organometallic Compounds
- Contents
- Chapter 1 Nuclear Magnetic Resonance Spectroscopy
- 1 Introduction
- 2 Stereochemistry
- Complexes of Group I and II Elements
- Complexes of Sc, Y, U, Ti, and Zr
- Complexes of V, Nb, and Ta
- Complexes of Cr, Mo, and W
- Complexes of Mn and Re
- Complexes of Fe, Ru, and Os
- Complexes of Co, Rh, and Ir
- Complexes of Ni, Pd, and Pt
- Complexes of Cu, Ag, and Au
- Complexes of Zn, Cd, and Hg
- 3 Dynamic Systems
- Fluxional Molecules
- Lithium
- Titanium, Niobium, and Tantalum
- Chromium, Molybdenum, and Tungsten
- Manganese and Rhenium
- Iron, Ruthenium, and Osmium
- Cobalt, Rhodium, and Iridium
- Nickel, Palladium, and Platinum
- Copper and Zinc
- Boron and Aluminium
- Silicon, Germanium, and Tin
- Phosphorus and Arsenic
- Selenium and Chlorine
- Equilibria
- Solvation Studies of Ions
- Ionic Equilibria
- Equilibria among Uncharged Species
- Course of Reactions
- Lithium and Magnesium
- Vanadium and Molybdenum
- Cobalt and Iridium
- Nickel and Platinum
- Gold, Zinc, and Mercury
- Boron and Thallium
- Silicon, Tin, and Lead
- Phosphorus and Selenium
- 4 Paramagnetic Complexes
- Compounds of the Lanthanides and Actinides
- 5 Solid-state N.M.R. Spectroscopy
- Motions in Solids
- Structure of Solids
- Molecules Sorbed onto Solids
- Water Sorbed onto Solids
- Other Molecules Sorbed onto Solids
- 6 Group III Compounds
- Boron Hydrides and Carbaboranes
- Other Compounds of Boron
- Complexes of other Group III Elements
- 7 Compounds of Silicon, Germanium, Tin, and Lead
- 8 Compounds of Group V Elements
- 9 Compounds of Groups VI, VII, Krypton, and Xenon
- 10 Appendix
- Chapter 2 Nuclear Quadrupole Resonance Spectroscopy
- 1 Introduction
- 2 Instrumentation
- 3 Main-group Elements
- Group I (Deuterium, Sodium-23)
- Group III (Aluminium-27, Gallium-69 Gallium-71, and Indium-115)
- Group V (Nitrogen-14, Arsenic-75, Antimony-121, Antimony-123, and Bismuth-209)
- Group VI (Oxygen-17)
- Group VII (Chlorine-35, Chlorine-37, Bromine-79 Bromine-81, and Iodine-127)
- 4 Transition Metals
- Cobalt-59
- Copper-63 and Copper-65
- Niobium-93
- Rhenium-185 and Rhenium-187
- Chapter 3 Microwave Spectroscopy
- 1 Introduction
- 2 Diatomic Molecules
- 3 Triatomic Molecules
- 4 Tetra-atomic Molecules
- 5 Inorganic and Organometallic Molecules containing Five or More Atoms
- Chapter 4 Vibrational Spectra of Small Symmetric Species and of Single Crystals
- 1 General Introduction
- 2 Spectra of Small Symmetric Species
- Diatomic Species
- Triatomic Species
- Tetra-atomic Species
- Penta-atomic Species
- Hexa-atomic Species
- Hepta-atomic Species
- 3 Single-crystal and other Solid-state Spectroscopy
- 'Simple' Lattice Types
- Mixed Oxides, Fluorides, and other Ternary Phases
- Sheet and Chain Structures
- Silicates
- Oxoanionic Crystals
- Complex Cationic Salts
- Complex Anionic Salts
- Molecular Crystals
- 4 Vibrational Spectra of Solutions
- Aqueous Solutions
- Non-aqueous Solutions
- Chapter 5 Characteristic Vibrational Frequencies of Compounds containing Main-group Elements
- 1 Group I Elements (including Hydrogen)
- 2 Group II Elements
- 3 Group III Elements
- Compounds containing B-H Bonds
- Compounds containing Al-H Bonds
- Compounds containing M-C Bonds (M = B, Al, In, or Tl)
- Compounds containing B-N or Al-N Bonds
- Compounds containing B-P or Ga-As Bonds
- Compounds containing M-O Bonds (M = B, Al, or Ga)
- Compounds containing B-S and B-Se Bonds
- Compounds containing M-Halogen Bonds (M = B, Al, Ga, or In)
- 4 Group IV Elements
- Compounds containing Si-H or Ge-H Bonds
- Compounds containing M-C Bonds (M = C, Si, or Ge)
- Compounds containing M-C Bonds (M = Sn or Pb)
- Compounds containing Si-Si or Sn-Sn Bonds
- Compounds containing M-N Bonds (M = Si, Ge, or Sn)
- Compounds containing Si-P, Si-As or Ge-P Bonds
- Compounds containing M-O Bonds (M = C, Si, Ge, Sn, or Pb)
- Silicates and Related Species
- Compounds containing M-X Bonds (M = C, Si, Ge, or Sn
- X = S, Se, or Te)
- Compounds containing M-Halogen Bonds (M = C, Si, Ge, Sn, or Pb)
- 5 Group V Elements
- Compounds containing N-H or P-H Bonds
- Compounds containing E-C Bonds (E = P, As, or Sb)
- Compounds containing N-N or P-P Bonds
- Compounds containing N-E Bonds (E = P, As, Sb, or Bi)
- Compounds containing E-O Bonds (E = N, P, As, or Sb)
- Compounds containing E-S (E = N, P, or As) or E-Se (E = P or As) Bonds
- Compounds containing E-Halogen Bonds (E = P, As, Sb, or Bi)
- 6 Group VI Elements
- Compounds containing Se-C, Se-Si, Se-Ge, or Te-C Bonds
- Compounds containing E-O Bonds (E = S, Se, or Te)
- Compounds containing S-S, Se-Se, or Te-Te Bonds
- Compounds containing E-Halogen Bonds (E = S, Se, or Te)
- 7 Group VII Elements
- 8 Group VIII Elements
- Chapter 6 Vibrational Spectra of Transition-element Compounds
- 1 Introduction
- 2 More Significant and General Aspects
- Detailed Studies
- Use of Isotopic Substitution
- Matrix-isolation Studies
- Resonance Raman Spectra
- Mixed-valence Compounds
- Polynuclear Pseudohalide Complexes
- Metal-Metal Vibrations
- General Series of Complexes
- 3 Scandium and Yttrium
- 4 Titanium, Zirconium, and Hafnium
- 5 Vanadium, Niobium, and Tantalum
- 6 Chromium, Molybdenum, and Tungsten
- 7 Manganese, Technetium, and Rhenium
- 8 Iron, Ruthenium, and Osmium
- 9 Cobalt, Rhodium, and Iridium
- 10 Nickel, Palladium, and Platinum
- 11 Copper, Silver, and Gold
- 12 Zinc, Cadmium, and Mercury
- 13 Lanthanoids
- 14 Actinoids
- 15 Conclusions
- Chapter 7 Vibrational Spectra of Some Co-ordinated Ligands
- 1 Carbon Donors
- 2 Carbonyl and Thiocarbonyl Complexes
- 3 Nitrogen Donors
- Molecular Nitrogen, Azido- and Related Complexes
- Amines and Related Ligands
- Oximes
- Ligands containing C=N- Groups
- Cyanides and Isocyanides
- Nitrosyls
- 4 Phosphorus and Arsenic Ligands
- 5 Oxygen Donors
- Molecular Oxygen, Peroxo- and Hydroxy-complexes
- Acetylacetonates and Related Complexes
- Carboxylato-complexes
- Keto, Alkoxy, Phenoxy, and Ether Ligands
- Nitrates and Nitrato-complexes
- Ligands containing O-N, O-P, or O-As Bonds
- Ligands containing O-S Bonds
- Ligands containing O-Cl Bonds
- 6 Sulphur and Selenium Donors
- 7 Potentially Ambident Ligands
- Cyanates, Thiocyanates, and their Iso-analogues
- Ligands containing N or P and O Atoms
- Ligands containing N or P nd S Atoms
- Ligands containing S and O Atoms
- Chapter 8 Mössbauer Spectroscopy
- 1 Introduction
- Books and Reviews
- 2 Theoretical
- 3 Instrumentation and Methodology
- 4 Iron-57
- General Topics
- Nuclear Parameters and Isomer Shift Calibrations
- Alloy-type Systems
- Frozen Solutions and Diffusion Phenomena
- 57Fe Impurity Studies
- 57Co Source Experiments and Decay After-effect Phenomena
- Miscellaneous Studies
- Compounds of Iron
- High-spin Iron(II) Compounds
- High-spin Iron(III) Compounds
- Spin-crossover Systems and Unusual Electric States
- Biological and Related Compounds
- Low-spin and Covalent Complexes
- Oxide and Chalcogenide Systems containing Iron
- Binary Oxides and Hydroxides
- Spinel Oxides
- Other Oxides
- Minerals
- Chalcogenides
- 5 Tin-119
- General Topics
- Tin(II) Compounds
- Inorganic Tin(IV) Compounds
- Organotin(IV) Compounds
- 6 Other Elements
- Main-group Elements
- Krypton (83Kr)
- Antimony (121Sb)
- Tellurium (125Te)
- Iodine (127I and 129I)
- Xenon (129Xe)
- Caesium (133Cs)
- Transition-metal Elements
- Nickel (61Ni)
- Zinc (67Zn)
- Ruthenium (99Ru)
- Tantalum (181Ta)
- Tungsten (182W, 184W and 186W)
- Osmium (187Os)
- Rhenium (187Re)
- Iridium (193Ir)
- Platinum (195Pt)
- Gold (197Au)
- Mercury (199Hg and 201Hg)
- Lanthanide and Actinide Elements
- Samarium (149Sm)
- Europium (151Eu and 153Eu)
- Gadolinium (154Gd, 155Gd, and 157Gd)
- Dysprosium (160Dy and 161Dy)
- Erbium (166Er)
- Thulium (169Tm)
- Ytterbium (170Yb and 171Yb)
- Neptunium (237Np)
- Americium (243Am)
- 7 Bibliography
- Author Index
