
Electronic Structure and Magnetism of Inorganic Compounds
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Content
- Electronic Structure and Magnetism of Inorganic Compounds
- Contents
- Chapter 1 Electronic Spectra
- 1 Introduction
- 2 Polarized and Low-temperature Crystal Spectra
- Discrete Complexes in Crystals
- Monatomic Ligands
- Oxides
- Halides
- Polyatomic Ligands
- Continuous Lattices
- Doped crystals
- Pure crystals
- Vibronic Effects
- Far- and Extreme-ultraviolet Spectra
- 3 Co-operative Phenomena in Clusters and Solids
- Crystal Effects and Interionic Charge Transfer
- Magnetic Interaction Effects
- Discrete Clusters
- Pairs of Magnetic Ions in Continuous Diamagnetic Lattices
- One-dimensional Magnetic Crystals
- Three-dimensional Magnetic Lattices
- 4 Complexes of Macrocycles and Stereochemically Unusual Complexes
- Complexes of Macrocyclic Ligands
- Unusual Stereochemistries
- 5 Complexes of Conjugated Ligands
- 6 Organometallic Compounds
- 7 Pressure and Solvent Effects
- 8 Spectra in Melts and Glasses
- 9 Theoretical Aspects of Inorganic Electronic Spectroscopy
- 10 Experimental Techniques
- 11 Main Groups
- Group I
- Group II
- Group III
- Group IV
- Group V
- Group VI
- Group VII
- Group VIII
- 12 Transition Metals
- Studies Embracing Two or More Groups of Transition-metal Ions
- Titanium, Zirconium, and Hafnium
- Vanadium, Niobium, and Tantalum
- Chromium, Molybdenum, and Tungsten
- Manganese, Technetium, and Rhenium
- Iron, Ruthenium, and Osmium
- Cobalt, Rhodium, and Iridium
- Cobalt(II)
- Cobalt(III)
- Nickel, Palladium, and Platinum
- Copper, Silver, and Gold
- 13 The Lanthanides and Actinides
- Lanthanides
- Cerium
- Praseodymium
- Neodymium
- Samarium
- Europium
- Gadolinium
- Dysprosium
- Holmium
- Erbium
- Ytterbium
- Terbium
- Actinides
- Uranium
- Americium
- Berkelium
- 14 Table of Compounds not Referred to in Detail
- Chapter 2 Natural and Magnetic Optical Activity
- 1 Natural Optical Activity
- Introduction
- Reviews
- Instruments
- Theory
- Relation of Structure and Optical Activity
- Simple Systems
- Absolute Configurations
- Induced Optical Activity
- Model Compounds
- Stereospecificity
- Miscellaneous Results
- 2 Magnetic Optical Activity
- Reviews
- Theory
- Instruments
- M.C.D. Measurements
- Allowed Transitions
- Forbidden Transitions
- Rare-earth Ions
- Impurity Centres
- Porphyrin Systems
- Physical Applications
- Other Applications
- 3 Differential Scattering of Circularly Polarized Light
- Chapter 3 Magnetic Susceptibility Measurements
- 1 Introduction
- 2 Reviews
- 3 Instrumentation
- 4 Theory
- 5 Magnetic Anisotropy of Crystalline Materials
- 6 Spin Equilibrium Compounds
- 7 Exchange Coupling in Inorganic Solids
- Ferromagnetism
- Weak Ferromagnetism and Ferrimagnetism
- Antiferromagnetism
- Titanium
- Vanadium
- Chromium
- Manganese
- Iron
- Cobalt
- Nickel
- Copper
- Miscellaneous
- 8 Other Average Susceptibility Measurements
- 9 Table of Compounds not Referred to in Detail
- Chapter 4 Photoelectron Spectroscopy
- 1 Introduction
- 2 Advances in Experimental Technique
- Electron Kinetic Energy Analysers
- Deflection Analysers
- Non-dispersive (Retarding Field) Analysers
- Source Technology
- Synchrotron Sources
- U.V. Sources
- X-Ray Sources
- Detection Systems
- Commercial Instruments
- Gas-phase Studies
- High-resolution X-P.E. Work
- The Study of High-energy Species
- Solid-state Work
- U.V.-P.E. Studies on Solids
- The Determination of Sampling Depths
- Sample Preparation
- Charging Effects
- Calibration of Spectra
- Temperature-dependent Effects
- Liquid-phase Measurements
- Angular Distribution Studies
- Coincidence Studies
- 3 Theoretical Aspects
- Photoionization Cross-sections
- Qualitative Theoretical Treatments
- Quantitative Theoretical Treatments
- Molecular Calculations
- Angular Distribution Studies
- Theoretical Treatments
- Spin Polarization of Photoelectrons
- Photoelectric Emission from Solids
- Autoionization
- Autodetachment
- Shake-up and Shake-off Processes
- Valence Shell Ionizations
- Core Ionizations
- Exchange Effects
- Crystal Field Effects
- The Calculation of Ionization Energies
- Valence Shell Ionization Energies
- Koopmans' approximation
- Beyond Koopmans' theorem
- Core Ionization Energies
- Koopmans' approximation
- Direct calculations
- Intermediate calculations
- Valence Electron Ionization Energies of Solids
- Linewidths of Core P.E. Signals
- 4 Chemical Applications of X-P.E. Spectroscopy (ESCA)
- Analytical Aspects
- Elemental Analysis
- Determination of Oxidation States
- Surface Phases
- Chemical Shift Studies-Theoretical Aspects
- Ionic Crystals
- Molecular Systems
- Potential models
- The thermochemical (equivalent-cores) approach
- Other models
- Correlation of Core IE Shifts with Other Spectroscopic Data
- U.V.-P.E. Ionization Energies
- N.M.R. Chemical Shifts
- Mössbauer Isomer Shifts
- Qualitative Aspects of Chemical Shift Studies
- Differentiation of Non-equivalent Atoms of the Same Element
- Non-metallic elements
- Mixed-valence compounds
- Binding Energy Trends in Selected Compounds
- Materials involving strong co-operative interactions
- Compounds of the main-group elements
- Transition-metal compounds
- Compounds of the lanthanide elements
- 5 Valence Region Spectra of Continuous Solids (Photoemission)
- Theoretical Background
- Metallic Elements
- Band Bending and Other Effects
- Semiconductors
- Metallic Compounds
- Compilation of References to Photoemission Work
- 6 Molecular Photoelectron Spectroscopy - Valence Region Studies
- Discussion of Selected Results
- Simple Hydrides
- The Perfluoro-effect
- Group IIIB Compounds
- Group IVB Compounds
- Group VB Compounds
- Interhalogens
- Noble-gas Compounds
- Compounds of the Transition Elements
- Appendix: Table of Ab Initio Calculations on Inorganic Molecules Reported during 1972
- Author Index
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