
Electronic Structure and Magnetism of Inorganic Compounds
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Content
- Electronic Structure and Magnetism of Inorganic Compounds
- Contents
- Chapter 1 Photoelectron Spectroscopy
- 1 Introduction
- 2 Ultraviolet Molecular Photoelectron Spectroscopy
- Instrumental
- A Compilation of U.V.-P.E. References
- Assignment Criteria
- Angular Distribution Measurements
- Calculations
- Discussion of Selected Results
- Small Molecules, Radical Species, and Excited States
- Boron Compounds
- Group IVB Compounds
- Transition-metal Compounds
- 3 X-Ray Photoelectron Spectroscopy
- Experimental Aspects
- Instrumental
- Commercial instrumentation
- Sources
- Deconvolution
- Sample Handling
- Probing depth of p.e. spectroscopy
- Surface cleanliness
- The Calibration Problem
- Compilation of References to Core X-P.E. Studies
- Chemical Shift Studies of Core Ionizations
- Theoretical Aspects
- The use of ab initio calculations
- The correlation of core ionization energies with molecular charge distributions
- The effect of lattice potentials
- The correlation of core binding energies and other physicochemical data
- The Differentiation of Non-equivalent Atoms of the same Element
- Non-metallic elements
- Mixed valence compounds (of the metallic elements)
- Surface compounds
- Qualitative Interpretation of Core Ionization Energy Trends in Inorganic Compounds
- Transition-metal compounds
- Compounds of the main-group elements
- Dependency of core binding energies on oxidation state
- Secondary Structure in X-P.E. Spectra
- Shake-up Structure
- Exchange Fine Structure
- Valence Ionizations in Molecular Systems
- Gas-phase Studies
- Molecules in the Solid State
- 4 The X-Ray and U.V. Photoelectron Spectroscopy of the Valence Levels of Continuous Solids
- 5 Concluding Remarks
- Chapter 2 Electronic Spectra
- 1 Introduction
- 2 Polarized and Low-temperature Crystal Spectra
- 3 Co-operative Phenomena in Clusters and Solids
- Crystal Effects and Interionic Charge Transfer
- Magnetic Interaction Effects
- 4 Complexes of Macrocycles and Stereochemically Unusual Ligands
- 5 Complexes of Conjugated Ligands
- 6 Organometallic Compounds
- 7 Solvent and other Environmental Effects
- 8 Spectra in Melts and Glasses
- 9 Theoretical Aspects of Inorganic Electronic Spectroscopy
- 10 Experimental Techniques
- 11 Main Groups
- Group I
- Group II
- Group III
- Group IV
- Group V
- Group VI
- Group VII
- 12 The Transition Elements
- Small Molecules
- Studies embracing more than Two Groups of Transition-metal Ions
- Titanium
- Vanadium, Niobium, and Tantalum
- Chromium, Molybdenum, and Tungsten
- Manganese and Rhenium
- Iron, Ruthenium, and Osmium
- Cobalt, Rhodium, and Iridium
- Cobalt(II)
- Cobalt(III)
- Rhodium and Iridium
- Nickel, Palladium, and Platinum
- Nickel
- Palladium and Platinum
- Copper and Silver
- 13 The Lanthanides and Actinides
- Lanthanides
- Actinides
- 14 Table of Compounds not Referred to in Detail
- Chapter 3 Optical Activity
- 1 Natural Optical Activity
- Introduction
- Reviews
- Instruments
- Theory
- Relation of Structure and Optical Activity
- Theoretical Aspects
- Configurational Activity
- Conformational Effects
- Sector Rules and Vicinal Effects
- Exciton Interactions
- Empirical Applications
- Assignment of Electronic Transitions
- Induced Optical Activity
- Miscellaneous Work
- 2 Magnetic Optical Activity
- Reviews, Theory, and Instruments
- M.C.D. Measurements
- Allowed Transitions
- Forbidden Transitions
- Colour Centres
- Physical Applications
- Other Applications
- 3 Other Field-induced Phenomena
- Magnetic Fields
- Electric Fields
- 4 Differential Scattering of Circularly Polarized Light
- Chapter 4 Magnetic Susceptibility Measurements
- 1 Introduction
- 2 Reviews
- 3 Instrumentation
- 4 Theory
- 5 Magnetic Anisotropy of Crystalline Materials
- 6 Spin Equilibrium Compounds
- 7 Exchange Coupling in Materials
- Ferromagnetism
- Weak Ferromagnetism
- Antiferromagnetism
- Vanadium
- Chromium
- Manganese
- Iron
- Cobalt
- Nickel
- Copper
- Miscellaneous
- 8 Other Average Susceptibility Measurements
- 9 Table of Compounds not Referred to in Detail
- Chapter 5 Molecular Calculations
- 1 Introduction
- 2 Table of Ab Initio Calculations on Inorganic Molecules Reported in 1971
- 3 General Discussion
- Chemical Applications
- Electronic Distribution
- 4 Correlation Energy
- Author Index
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