
Electronic Structure and Magnetism of Inorganic Compounds
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Content
- Electronic Structure and Magnetism of Inorganic Compounds
- Contents
- Chapter 1 Photoelectron Spectroscopy
- 1 The Theory of Photoelectron Emission from Atoms and Molecules
- 2 Ultraviolet Molecular Photoelectron Spectroscopy
- A. Instrumental Advances
- Light Source
- Sample Handling
- Electron Analysis
- B. A Compilation of U.V.-P.E. References
- C. Assignment Criteria
- Calculations
- Fine Structure
- Empirical Approaches
- D. Complementary Techniques
- E. Discussion of Some Selected Results
- Compounds of the Main-group Elements
- Transition-metal Compounds
- 3 X-Ray Photoelectron Spectroscopy
- A. Experimental Methods
- The Calibration Problem
- Surface-charging and other Effects
- B. Additional Structure in X-P.E. Spectra
- Auger Lines
- Structure due to Additional Lines in the Exciting Radiation
- 'Shake-up' and 'Shake-off' Processes
- Discrete Energy Loss (DEL) Processes
- C. Compilation of References
- Gas Phase
- Solid State
- D. General Discussion of Results
- Valence Region Studies
- Core Level Studies
- Some Conclusions
- Chapter 2 Electronic Spectra
- 1 Polarised and Low-temperature Crystal Spectra
- 2 Co-operative Phenomena in Clusters and Solids
- A. Intermolecular Charge Transfer and Mixed-valency Effects
- B. Magnetic Interaction and Metal-Metal Bonding Effects
- 3 Complexes of Macrocycles and Stereochemically Unusual Ligands
- 4 Complexes of Conjugated Ligands
- 5 Organometallic Compounds
- 6 Solvent Effects
- 7 Spectra in Melts and Glasses
- 8 Theoretical Aspects of Inorganic Electronic Spectroscopy
- 9 Experimental Techniques
- 10 The Main-group Elements
- Group II
- Group III
- Group IV
- Group V
- Group VI
- Group VII
- 11 The Transition Elements
- Small Molecules
- Studies embracing more than Two Groups of Transition-metal Ions
- Zirconium and Hafnium
- Vanadium, Niobium, and Tantalum
- Chromium, Molybdenum, and Tungsten
- Manganese and Rhenium
- Iron, Ruthenium, and Osmium
- Cobalt, Rhodium, and Iridium
- Nickel, Palladium, and Platinum
- Copper
- 12 The Lanthanides and Actinides
- Lanthanides
- Actinides
- 13 Table of Compounds not referred to in detail
- Chapter 3 Optical Activity
- 1 Natural Optical Activity
- General Introduction
- Nomenclature
- Reviews
- Instruments
- Computational Work
- Relation of Structure and Optical Activity
- Configurational Activity
- Sector Rules and Vicinal Effects
- Exciton Interactions
- Empirical Applications
- Assignment of Electronic Transitions
- Structural and Conformational Studies
- Other Applications
- Optical Identification of Absolute Configuration
- 2 Magnetic Optical Activity
- General
- Theory, Reviews, and Instruments
- Magnetic Circular Dichroism Measurements
- Allowed Transitions
- Forbidden Transitions
- Physical Applications
- Other Applications
- 3 Other Field-induced Phenomena
- Electric Fields
- Magnetic Fields
- Chapter 4 Magnetic Susceptibility Measurements
- 1 Introduction
- 2 Anisotropic and Temperature-dependent Measurements
- 3 Metal Clusters and Polymeric Compounds
- A. First Transition Series
- Vanadium
- Chromium
- Manganese
- Iron
- Nickel
- Copper
- B. Second and Third Transition Series
- Niobium and Tantalum
- Molybdenum
- Technetium
- Rhodium and Iridium
- General
- 4 Ferro-and Antiferro-magnetic Interactions in Solids
- 5 Paramagnetic Complexes
- A. Spin-state Equilibria and Other Interesting Magnetic Properties
- Iron
- Cobalt
- Nickel
- Other Metal Ions
- B. Unusual Ligands and Stereochemistries
- 6 Table of Compounds not Referred to in Detail
- Chapter 5 Theoretical Calculations
- 1 Introduction
- 2 Table of Ab Initio Calculations on Inorganic Molecules Reported in 1970 and late 1969
- 3 Evaluation of Ab Initio MO Calculations
- 4 The Calculation of Molecular Properties
- A. Molecular Geometry
- B. Energy Terms
- Orbital Energies
- Dissociation Energies
- Internal Energy Barriers
- Transition Energies
- C. Charge Distribution in Molecules
- Electron Distribution
- 5 Ligand Field Theory
- A. Transition Metals
- B. Lanthanides and Actinides
- Author Index
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