Macrocycles
Construction, Chemistry and Nanotechnology Applications
Published on 8. February 2011
608 pages
978-1-119-98993-6 (ISBN)
Description
Macrocyclic molecules contain rings made up of seven or more atoms.They are interesting because they provide building blocks forsynthesizing precise two or three dimensional structures - animportant goal in nanotechnology. For example, they can be used todevelop nanosized reaction vessels, cages, switches and shuttles,and have potential as components in molecular computers. They alsohave applications as catalysts and sensors.
Macrocycles: Construction, Chemistry andNanotechnology Applications is an essentialintroduction this important class of molecules and describes how tosynthesise them, their chemistry, how they can be used asnanotechnology building blocks, and their applications. A widerange of structures synthesised over the past few decades arecovered, from the simpler cyclophanes and multi-ring aromaticstructures to vases, bowls, cages and more complex multi-ringsystems and 3D architectures such as "pumpkins",interlocking chains and knots. Topics covered include:
* principles of macrocycle synthesis
* simple ring compounds
* multi-ring aromatic structures
* porphyrins and phthalocanines
* cyclophanes
* crown ethers, cryptands and spherands
* calixarenes, resorcinarenes, cavitands, carcerands, andheterocalixarenes
* cyclodextrins
* cucurbiturils
* cyclotriveratylenes
* rotaxanes
* catenanes
* complex 3D architectures, including trefoils and knots
Macrocycles: Construction, Chemistry andNanotechnology Applications distills the essence ofthis important topic for undergraduate and postgraduate students,and for researchers in other fields interested in getting a generalinsight into this increasingly important class of molecules.
Reviews / Votes
"Macrocycles : Construction, Chemistry and NanotechnologyApplications distils the essence of this important topic forundergraduate and postgraduate students, and for researchers inother fields who are interested in getting a general insight intothis increasingly important class of molecules." (Chimie Nouvelle, 1 March 2013) "Figures aside, the book provides a good introduction tonovices in the field and points readers to the key references inthe macrocyclic chemistry." (Chemistry World,2012)More details
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Persons
Dr Frank Davis
Cranfield University, UK
Dr Davis is a research fellow at Cranfield University, specialisingin the biochemical and supramolecular aspects of electrochemistry.As well as pursuing academic research he has undertaken contractresearch for organisations such as Unilever Research (PortSunlight), ITM Power Ltd (Sheffield), Timestrip (Hitchen) andDEFRA, and spent a 4-year research post within Gillette UK
Professor Séamus Higson
Cranfield University, UK
Séamus Higson is Professor of Bio- and Electro-Analysis atCranfield University which he joined in August 2002. His previouscareer spans academic departments of chemistry, medicine andmaterials science and this is reflected in his research. ProfessorHigson also serves within an advisory and / or consultativecapacity for a number of public bodies and also acts as TechnicalDirector for Microarray Ltd - a company formed upon science andpatents originating from his group. His current research isprimarily focussed towards practical implementation of electroanalytical science and analytical biochemistry for biomedical,environmental and industrial process control applications.
Content
Preface.
1 Introduction.
1.1 Simple Ring Compounds.
1.2 Three-Dimensional Aliphatic Carbon Structures.
1.3 Annulenes.
1.4 Multi-Ring Aromatic Structures.
1.5 Porpyrins and Phthalocanines.
1.6 Conclusions.
References.
2 Cyclophanes.
2.1 Introduction.
2.2 Cyclophanes with One Aromatic System and AliphaticChain.
2.3 Cyclophanes with More than One Aromatic Ring.
2.4 Napthalenophanes and Other Aromatic Systems.
2.5 Cyclophanes Containing Heteroaromatic Systems.
2.6 Ferrocenophanes.
2.7 Conclusions.
Bibliography.
References.
3 Crown Ethers, Cryptands and Other Compounds.
3.1 Introduction.
3.2 Crown Ethers.
3.3 Simple Complexes with Crown Ethers.
3.4 Azacrowns, Cyclens and Cyclams.
3.5 Crowns Containing Other Heteroatoms.
3.6 Lariat and Bibracchial Crown Ethers.
3.7 Cryptands.
3.8 Spherands.
3.9 Combined and Multiple Systems.
3.10 Applications of Crown Ethers and Related Compounds.
3.11 Conclusions.
Bibliography.
References.
4 Calixarenes.
4.1 Introduction.
4.2 History.
4.3 Structures of Calixarenes.
4.4 Chemical Modification of Calixarenes.
4.5 Complexes with Calixarenes.
4.6 Bis and Multicalixarenes.
4.7 Oxacalixarenes, Azacalixarenes and Thiacalixarenes.
4.8 Resorcinarenes: Synthesis and Structure.
4.9 Cavitands and Carcerands.
4.10 Conclusions.
Bibliography.
References.
5 Heterocalixarenes and Calixnaphthalenes.
5.1 Introduction.
5.2 Calixnaphthalenes.
5.3 Tropolone-Based Macrocycles.
5.4 Calixfurans.
5.5 Calixpyrroles.
5.6 Calixindoles, Calixpyridines and Calixthiophenes.
5.7 Conclusions.
Bibliography.
References.
6 Cyclodextrins.
6.1 Introduction.
6.2 Complex Formation by Cyclodextrins.
6.3 Cyclodextrins of Other Sizes.
6.4 Modification Reactions of Cyclodextrins.
6.5 Selectivity of Cyclodextrins.
6.6 Multiple Cyclodextrin Systems.
6.7 Polymeric Cyclodextrins.
6.8 Cyclodextrins Combined with Other Macrocyclic Systems.
6.9 Therapeutic Uses of Cyclodextrins.
6.10 Other Uses of Cyclodextrins.
6.11 Conclusions.
Bibliography.
References.
7 Cyclotriveratylenes and Cryptophanes.
7.1 Introduction.
7.2 Synthesis of Cyclotriveratrylenes.
7.3 Modification of Cyclotriveratrylenes.
7.4 Synthesis of Optically Active Cyclotriveratrylenes.
7.5 Modification of the Bridging Groups.
7.6 Modification of the Aromatic Rings with OrganometallicGroups.
7.7 Selective Binding Applications of Cyclotriveratrylenes.
7.8 Analogues of CTV.
7.9 Synthesis and Structure of Cryptophanes.
7.10 Modification of Cryptophanes.
7.11 Complexes with Cryptophanes.
7.12 Cryptophane-Xenon Complexes.
7.13 Other Uses of Cryptophanes.
7.14 Hemicryptophanes.
7.15 Conclusions.
Bibliography.
References.
8 Cucurbiturils.
8.1 Introduction.
8.2 Complexation Behaviour of Simple Cucurbiturils.
8.3 Modification of Cucurbiturils.
8.4 Uses of Cucurbiturils.
8.5 Hemicucurbiturils.
8.6 Conclusions.
Bibliography.
References.
9 Rotaxanes and Catenanes.
9.1 Introduction.
9.2 Rotaxanes.
9.3 Catenanes.
9.4 Conclusions.
Bibliography.
References.
10 Other Supramolecular Systems, Molecular Motors, Machinesand Nanotechnological Applications.
10.1 Introduction.
10.2 Other Molecular Systems.
10.3 Molecular Devices, Motors and Machines.
10.4 Conclusions.
Bibliography.
References.
Index.
