
Spectroscopic Properties of Inorganic and Organometallic Compounds
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Content
- Spectroscropic Properties Of Inorganic And Organometallic Compounds
- Contents
- Chapter 1 Nuclear Magnetic Resonance Spectroscopy
- 1 Introduction
- 2 Stereochemistry
- 2.1 Complexes of Groups 1 and 2
- 2.2 Complexes of Group 3, the Lanthanides and Actinides
- 2.3 Complexes of Group 4
- 2.4 Complexes of Group 5
- 2.5 Complexes of Group 6
- 2.6 Complexes of Group 7
- 2.7 Complexes of Group 8
- 2.8 Complexes of Group 9
- 2.9 Complexes of Group 10
- 2.10 Complexes of Group 11
- 2.11 Complexes of Group 12
- 3 Dynamic Systems
- 3.1 Fluxional Molecules
- 3.1.1 Group 1
- 3.1.2 Scandium
- 3.1.3 Yttrium
- 3.1.4 Samarium
- 3.1.5 Titanium
- 3.1.6 Zirconium
- 3.1.7 Niobium and Tantalum
- 3.1.8 Chromium, Molybdenum and Tungsten
- 3.1.9 Manganese
- 3.1.10 Rhenium
- 3.1.11 Iron
- 3.1.12 Ruthenium
- 3.1.13 Osmium
- 3.1.14 Cobalt
- 3.1.15 Rhodium
- 3.1.16 Iridium
- 3.1.17 Nickel
- 3.1.18 Palladium
- 3.1.19 Platinum
- 3.1.20 Copper
- 3.1.21 Silver
- 3.1.22 Gold
- 3.1.23 Zinc
- 3.1.24 Boron
- 3.1.25 Aluminium
- 3.1.26 Gallium
- 3.1.27 Thallium
- 3.1.28 Silicon
- 3.1.29 Germanium
- 3.1.30 Lead
- 3.1.31 Phosphorus
- 3.1.32 Antimony
- 3.1.33 Bismuth
- 3.1.34 Oxygen
- 3.1.35 Sulfur
- 3.1.36 Tellurium
- 3.2 Equilibria
- 3.2.1 Solvation Studies of Ions
- Lithium
- Sodium and Potassium
- Lanthanides
- Uranium
- Zirconium
- Tungsten
- Ruthenium
- Nickel
- Platinum
- Copper
- Gold
- Aluminium
- Silicon
- Phosphorus
- Chalco gens and Halides
- Xenon
- 3.2.2 Ionic Equilibria
- Group 1
- Group 2
- Scandium and Yttrium
- Lanthanum and the Lanthanides
- Uranium
- Zirconium
- Vanadium
- Chromium
- Rhenium
- Iron
- Ruthenium
- Cobalt
- Rhodium
- Nickel
- Palladium
- Platinum
- Copper
- Silver
- Gold
- Zinc
- Cadmium
- Boron
- Aluminium
- Gallium
- Thallium
- Carbon
- Silicon
- Tin
- Lead
- Nitrogen
- Bismuth
- Fluorine
- Chlorine
- 3.2.3 Equilibria among Uncharged Species
- Lithium
- Magnesium
- Yttrium
- Ytterbium
- Titanium
- Zirconium
- Vanadium
- Niobium
- Molybdenum
- Rhenium
- Iron
- Ruthenium and Osmium
- Cobalt
- Rhodium
- Iridium
- Nickel
- Palladium
- Platinum
- Copper
- Silver
- Zinc
- Cadmium
- Mercury
- Boron
- Aluminium
- Indium
- Silicon, Tin and Lead
- Antimony
- Xenon
- 3.3 Course of Reactions
- 3.3.1 Lithium
- 3.3.2 Beryllium
- 3.3.3 Magnesium
- 3.3.4 Calcium
- 3.3.5 Uranium
- 3.3.6 Titanium, Zirconium and Hafnium
- 3.3.7 Vanadium
- 3.3.8 Chromium, Molybdenum and Tungsten
- 3.3.9 Technetium
- 3.3.10 Manganese
- 3.3.11 Rhenium
- 3.3.12 Iron
- 3.3.13 Ruthenium
- 3.3.14 Osmium
- 3.3.15 Cobalt
- 3.3.16 Rhodium and Iridium
- 3.3.17 Nickel
- 3.3.18 Palladium
- 3.3.19 Platinum
- 3.3.20 Silver
- 3.3.21 Gold
- 3.3.22 Zinc
- 3.3.23 Mercury
- 3.3.24 Boron
- 3.3.25 Aluminium
- 3.3.26 Gallium
- 3.3.27 Silicon
- 3.3.28 Germanium
- 3.3.29 Tin
- 3.3.30 Phosphorus
- 3.3.31 Selenium
- 4 Paramagnetic Complexes
- 4.1 The Transition Metals
- 4.1.1 Vanadium
- 4.1.2 Molybdenum and Tungsten
- 4.1.3 Manganese
- 4.1.4 Rhenium
- 4.1.5 Iron
- 4.1.6 Osmium
- 4.1.7 Cobalt
- 4.1.8 Rhodium
- 4.1.9 Nickel
- 4.1.10 Copper
- 4.2 Complexes of the Lanthanides and Actinides
- 4.2.1 Lanthanides
- 4.2.2 Actinides
- 5 Solid-state NMR Spectroscopy
- 5.1 Motion in Solids
- 5.2 Structure of Solids
- 5.3 Molecules Sorbed onto Solids
- 5.3.1 Water Sorbed onto Solids
- 5.3.2 Atoms and Other Molecules Sorbed onto Solids
- 6 Group 13 Compounds
- 6.1 Boron Hydrides and Carboranes
- 6.2 Other Compounds of Boron
- 6.3 Complexes of Other Group 13 Elements
- 7 Group 14 Compounds
- 8 Group 15 Compounds
- 9 Compounds of Groups 16, 17 and 18
- 10 Appendix
- Chapter 2 Nuclear Quadrupole Resonance Spectroscopy
- 1 Introduction
- 2 Main Group Elements
- 2.1 Group 1 (Lithium-7)
- 2.2 Group 2 (Barium-137)
- 2.3 Group 13 (Aluminium-27, Gallium-69 and Indium-115)
- 2.4 Group 15 (Nitrogen-14, Arsenic-75, Antimony-121 and -123, and Bismuth-209)
- 2.5 Group 17 (Chlorine-35 and -37, Bromine-79 and -81, and Iodine-127)
- 3 Transition Metals and Lanthanides
- 3.1 Vanadium-51
- 3.2 Manganese-55
- 3.3 Cobalt-59
- 3.4 Copper-63 and -65
- 3.5 Ruthenium-101
- 3.6 Lanthanum-139
- 3.7 Rhenium-185 and -187
- References
- Chapter 3 Characteristic Vibrations of Main Group Elements
- 1 Group 1
- 2 Group 2
- 3 Group 13
- 3.1 Boron
- 3.2 Aluminium
- 3.3 Gallium
- 3.4 Indium and Thallium
- 4 Group 14
- 4.1 Carbon
- 4.2 Silicon
- 4.3 Germanium
- 4.4 Tin
- 4.5 Lead
- 5 Group 15
- 5.1 Nitrogen
- 5.2 Phosphorus
- 5.3 Arsenic
- 5.4 Antimony
- 5.5 Bismuth
- 6 Group 6
- 6.1 Oxygen
- 6.2 Compounds Containing Sulfur or Selenium Rings or Chains
- 6.3 Other Sulfur and Selenium Compounds
- 6.4 Tellurium
- 7 Group 17
- 8 Group 18
- References
- Chapter 4 Vibrational Spectra of Transition Element Compounds
- 1 Scandium, Yttrium and the Lanthanides
- 2 Titanium, Zirconium and Hafnium
- 3 Vanadium, Niobium and Tantalum
- 4 Chromium, Molybdenum and Tungsten
- 5 Manganese, Technetium and Rhenium
- 6 Iron, Ruthenium and Osmium
- 7 Cobalt, Rhodium and Iridium
- 8 Nickel, Palladium and Platinum
- 9 Copper, Silver and Gold
- 10 Zinc, Cadmium and Mercury
- 11 Actinides
- References
- Chapter 5 Vibrational Spectra of Some Co-ordinated Ligands
- 1 Carbon, Silicon and Tin Donors
- 2 Boron and Indium Donors
- 3 Carbonyl Complexes
- 4 Nitrogen Donors
- 4.1 Molecular Nitrogen, Azido- and Related Groups
- 4.2 Amines and Related Ligands
- 4.3 Ligands Containing &C=N- Groups
- 4.4 Cyanides, Isocyanides and Related Complexes
- 4.5 Nitrosyl and Thionitrosyl Complexes
- 5 Phosphorus, Arsenic and Antimony Donors
- 6 Oxygen Donors
- 6.1 Molecular Oxygen, Peroxo, Aquo and Related Complexes
- 6.2 Carboxylate and Related Complexes
- 6.3 Keto-, Alkoxy-, Ether and Related Coplexes
- 6.4 Ligands Containing O-N or O-P Bonds
- 6.5 Ligands Containing O-S or O-Te Bonds
- 6.6 Ligands Containing O-Cl or O-I Bonds
- 7 Sulfur, Selenium and Tellurium Donors
- 8 Potentially Ambident Ligands
- 8.1 Cyanates, Thio- and Selenocyanates and Their Iso-analogues
- 8.2 Ligands Containing N and O or P and O Donor Atoms
- 8.3 Ligands Containing N and S, P and O or P and S Donor Atoms
- 8.4 Ligands Containing S and O Donor Atoms
- References
- Chapter 6 Gas-phase Molecular Structures Determined by Electron Diffraction
- 1 Introduction
- 2 Compounds of Elements in Groups 1, 2 and 13
- 3 Compounds of Elements in Group 14
- 4 Compounds of Elements in Group 15
- 5 Compounds of Elements in Group 16
- 6 Compounds of Transition Elements and Actinides
- References
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