
Spectroscopic Properties of Inorganic and Organometallic Compounds
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Content
- Spectroscopic Properties of Inorganic and Organometallic Compounds
- Contents
- 1 Nuclear Magnetic Resonance Spectroscopy
- 1 Introduction
- 2 Stereochemistry
- 2.1 Complexes of Groups 1 and 2
- 2.2 Complexes of Group 3, the Lanthanides and Actinides
- 2.3 Complexes of Group 4
- 2.4 Complexes of Group 5
- 2.5 Complexes of Group 6
- 2.6 Complexes of Group 7
- 2.7 Complexes of Group 8
- 2.8 Complexes of Group 9
- 2.9 Complexes of Group 10
- 2.10 Complexes of Group 11
- 2.11 Complexes of Group 12
- 3 Dynamic Systems
- 3.1 Fluxional Molecules
- 3.1.1 Group 1
- 3.1.2 Barium
- 3.1.3 Group 3 and the Lanthanides
- 3.1.4 Uranium
- 3.1.5 Titanium
- 3.1.6 Zirconium
- 3.1.7 Hafnium
- 3.1.8 Vanadium
- 3.1.9 Niobium
- 3.1.10 Tantalum
- 3.1.11 Chromium, Molybdenum and Tungsten
- 3.1.12 Manganese
- 3.1.13 Rhenium
- 3.1.14 Iron
- 3.1.15 Ruthenium
- 3.1.16 Osmium
- 3.1.17 Cobalt
- 3.1.18 Rhodium and Iridium
- 3.1.19 Nickel
- 3.1.20 Palladium and Platinum
- 3.1.21 Copper
- 3.1.22 Silver and Gold
- 3.1.23 Zinc
- 3.1.24 Cadmium
- 3.1.25 Mercury
- 3.1.26 Boron
- 3.1.27 Aluminium
- 3.1.28 Gallium
- 3.1.29 Indium
- 3.1.30 Thallium
- 3.1.31 Silicon
- 3.1.32 Germanium and Tin
- 3.1.33 Nitrogen
- 3.1.34 Phosphorus
- 3.1.35 Bismuth
- 3.2 Equilibria
- 3.2.1 Solvation Studies of Ions
- Group 1 . Alkali Metals
- Calcìum
- Europium
- Gadolinium
- Ytterbium
- Actinides
- Vanadium
- Iridium
- Copper
- Boron, Aluminium and Gallium
- Antimony
- Oxygen
- 3.2.2 Ionic Equilibria
- Group 1
- Beryllium
- Magnesium, Calcium, Strontium and Barium
- Yttrium, Lanthanum and the Lanthanides
- Uranium
- Titanium
- Zirconium
- Vanadium
- Niobium
- Molybdenum and Tungsten
- Technetium and Rhenium
- Iron
- Ruthenium
- Cobalt
- Rhodium
- Palladium and Platinum
- Copper
- Silver
- Gold
- Zinc
- Cadmium
- Mercury
- Boron
- Aluminium
- Gallium
- Silicon
- Tin
- Lead
- Phosphorus
- Antimony
- 3.2.3 Equilibria among Uncharged Species
- Lithium
- Titanium
- Chromium
- Molybdenum
- Tungsten
- Rhenium
- Iron
- Ruthenium
- Cobalt
- Rhodium
- Palladium
- Platinum
- Copper
- Zinc and Cadmium
- Mercury
- Boron
- Aluminium, Gallium and Indium
- Tin
- Phosphorus
- Selenium
- 3.3 Course of Reactions
- Hydrogen
- Alkali Metals
- Titanium and Zirconium
- Vanadium
- Niobium and Tantalum
- Chromium
- Molybdenum
- Tungsten
- Technetium and Rhenium
- Iron
- Ruthenium
- Osmium
- Cobalt
- Rhodium and Iridium
- Nickel
- Palladium and Platinum
- Copper
- Gold
- Zinc
- Boron
- Aluminium and Gallium
- Silicon, Gallium and Tin
- Tin
- Nitrogen
- Phosphorus
- 4 Paramagnetic Complexes
- 4.1 The Transition Metals
- Chromium
- Molybdenum and Tungsten
- Manganese
- Iron
- Ruthenium and Osmium
- Cobalt
- Nickel
- Copper
- 4.2 Complexes of the Lanthanides and Actinides
- Lanthanides
- Actinides
- 5 Solid-state NMR Spectroscopy
- 5.1 Motion in Solids
- 5.2 Structure of Solids
- 5.3 Molecules Sorbed onto Solids
- 5.3.1 Water Sorbed onto Solids
- 5.3.2 Atoms and Other Molecules Sorbed onto Solids
- 6 Group 13 Compounds
- 6.1 Boron Hydrides and Carboranes
- 6.2 Other Compounds of Boron
- 6.3 Complexes of Other Group 13 Elements
- 7 Group 14 Compounds
- 8 Group 15 Compounds
- 9 Compounds of Groups 16,17 and 18
- 10 Appendix
- 2 Nuclear Quadrupole Resonance Spectroscopy
- 1 Introduction
- 2 Main Group Elements
- 2.1 Group 1 (Deuterium-2)
- 2.2 Group 13 (Boron-10 and -11, Aluminium-27, Gallium49 and -71 and Indium-115)
- 2.3 Group 15 (Nitrogen-14, Arsenic-75, Antimony-121 and -123 and Bismuth- 209)
- 2.4 Group 17 (Chlorine-35 and -37, Bromine-79 and -81, and Iodine-127)
- 3 Transition Metals and Lanthanides
- 3.1 Vanadium-51
- 3.2 Manganese-55
- 3.3 Copper-63 and -65
- 3.4 Ruthenium-99 and -101
- 3.5 Palladium-105
- 3.6 Lanthanum-139
- References
- 3 Characteristic Vibrations of Compounds of Main Group Elements
- 1 Group 1
- 2 Group2
- 3 Group13
- 3.1 Boron
- 3.2 Aluminium
- 3.3 Gallium
- 3.4 Indium and Thallium
- 4 Group14
- 4.1 Carbon
- 4.2 Silicon
- 4.3 Germanium
- 4.4 Tin
- 4.5 Lead
- 5 Group 15
- 5.1 Nitrogen
- 5.2 Phosphorus
- 5.3 Arsenic
- 5.4 Antimony
- 5.5 Bismuth
- 6 Group16
- 6.1 Oxygen
- 6.2 Compounds Containing Sulfur or Selenium Rings or Chains
- 6.3 Other Sulfur and Selenium Compounds
- 6.4 Tellurium
- 7 Group17
- 8 Group18
- References
- 4 Vibrational Spectra of Transition Element Compounds
- 1 Scandium, Yttrium and the Lanthanides
- 2 Titanium, Zirconium and Hafnium
- 3 Vanadium, Niobium and Tantalum
- 4 Chromium, Molybdenum and Tungsten
- 5 Manganese, Technetium and Rhenium
- 6 Iron, Ruthenium and Osmium
- 7 Cobalt, Rhodium and Iridium
- 8 Nickel, Palladium and Platinum
- 9 Copper, Silver and Gold
- 10 Zinc, Cadmium and Mercury
- 11 Actinides
- References
- 5 Vibrational Spectra of Some Co-ordinated Ligands
- 1 Carbon and Silicon Donors
- 2 Boron Donors
- 3 Carbonyl and Thiocarbonyl Complexes
- 4 Nitrogen Donors
- 4.1 Molecular Nitrogen, Azido and Related Groups
- 4.2 Amines and Related Ligands
- 4.3 Ligands Containing &C=N- Groups
- 4.4 Cyanides, Isocyanides and Related Complexes
- 4.5 Nitrosyl Complexes
- 5 Phosphorus, Arsenic, Antimony and Bismuth Donors
- 6 Oxygen Donors
- 6.1 Molecular Oxygen, Peroxo, Aquo and Related Complexes
- 6.2 Carboxylate and Related Complexes
- 6.3 Keto, Alkoxy, Ether and Related Complexes
- 6.4 Ligands Containing O-N or O-P Bonds
- 6.5 Ligands Containing O-S or O-Se Bonds
- 6.6 Ligands Containing O-CI Bonds
- 7 Sulfur and Selenium Donors
- 8 Potentially Ambident Ligands
- 8.1 Cyanaets, Thio- and Selenocyanates and Their Iso-analogues
- 8.2 Ligands Containing N and O or P and O Donor Atoms
- 8.3 Ligands Containing N and P, N and S or P and S Donor Atoms
- 8.4 Ligands Containing S and O Donor Atoms
- References
- 6 Mössbauer Spectroscopy
- 1 Introduction
- 1.1 Books and Reviews
- 2 Theoretical
- 3 Methodology
- 4 Instrumentation
- 5 Iron-57
- 5.1 General Topics and Metallic Iron
- 5.2 Impurity Studies, Matrix Isolation, Polymers and Intercalation Compounds
- 5.3 Compounds of Iron
- 5.3.1 High-spin Iron(II) Compounds
- 5.3.2 High-spin Iron (III) Compounds
- 5.3.3 Mixed Valence Compounds and Unusual Valence States
- 5.3.4 Spin-crossover Compounds and Unusual Spin States
- 5.3.5 Low-spin and Covalent Compounds
- 5.4 Biological Systems and Related Compounds
- 5.5 Oxide and Chalcogenide Compounds of Iron
- 5.5.1 Hydroxides
- 5.5.2 Wüstite and Related Oxides
- 5.5.3 Haematite, Maghemite and Related Oxides
- 5.5.4 Magnetite and Spinel-type Oxides
- 5.5.5 Nunocrystalline Iron Oxides
- 5.5.6 Superconducting Ceramics and Related Systems
- 5.5.7 Other Oxides
- 5.5.8 Inorganic Oxide Glasses Containing Iron
- 5.5.9 Chalcogenides
- 5.6 Applications of Iron-57 Mössbauer Spectroscopy
- 5.6.1 Catalysts
- 5.6.2 Minerals and Coal
- 5.6.3 Steels and Corrosion Studies
- 5.6.4 Other Applications
- 6 Tin-119
- 6.1 General and Impurity Studies
- 6.2 Tin Alloys
- 6.3 Inorganic Tin(II) Compounds
- 6.4 Inorganic Tin(IV) Compounds
- 6.5 Organotin Compounds
- 7 Other Elements
- 7.1 Main Group Elements
- 7.1.1 Antimony (Sb-121)
- 7.1.2 Tellurium (Te-125)
- 7.1.3 Iodine (I-127 and I-129)
- 7.1.4 Caesium (Cs-133)
- 7.2 Transition Metal Elements
- 7.2.1 Nickel (Ni-61)
- 7.2.2 Zinc (Zn-67)
- 7.2.3 Ruthenium (Ru-99)
- 7.2.4 Silver (Ag-109)
- 7.2.5 Iridium (Ir-193)
- 7.2.6 Gold (Au-197)
- 7.3 Lanthanide and Actinide Elements
- 7.3.1 Europium (Eu-151)
- 7.3.2 Praseodymium (Pr-141)
- 7.3.3 Samarium (Sm-147 and Sm-149)
- 7.3.4 Gadolinium (Gd-155)
- 7.3.5 Dysprosium (Dy-161)
- 7.3.6 Holmium (Ho-165)
- 7.3.7 Erbium (Er-167)
- 7.3.8 Thulium (Tm-169)
- 7.3.9 Ytterbium ( Yb-I 70)
- 7.3.10 Neptunium (Np-237)
- 7.3.11 Uranium (U-238)
- 8 Backscatter and Conversion Electron Spectroscopy
- 8.1 Theory and Instrumentation
- 8.2 Films and Implantation Studies
- 8.3 Corrosion Studies and Steels
- 8.4 Alloys
- 8.5 Oxides
- 8.6 Other Elements
- 9 Synchrotron Radiation Mössbauer Spectroscopy
- References
- 7 Gas-phase Molecular Structures Determined by Electron Diraction
- 1 Introduction
- 2 Compounds of Elements in Groups 12 and 13
- 3 Compounds of Elements in Group 14
- 4 Compounds of Elements in Group 15
- 5 Compounds of Elements in Group 16
- 6 Compounds of Transition Elements and Actinides
- 7 Conclusion
- References
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