
Petroleum Refining Design and Applications Handbook, Volume 2
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There is a renaissance that is occurring in chemical and process engineering, and it is crucial for today's scientists, engineers, technicians, and operators to stay current. This book offers the most up-to-date and comprehensive coverage of the most significant and recent changes to petroleum refining, presenting the state-of-the-art to the engineer, scientist, or student. Useful as a textbook, this is also an excellent, handy go-to reference for the veteran engineer, a volume no chemical or process engineering library should be without.
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A. Kayode Coker PhD, is Engineering Consultant for AKC Technology, an Honorary Research Fellow at the University of Wolverhampton, U.K., a former Engineering Coordinator at Saudi Aramco Shell Refinery Company (SASREF) and Chairman of the department of Chemical Engineering Technology at Jubail Industrial College, Saudi Arabia. He has been a chartered chemical engineer for more than 30 years. He is a Fellow of the Institution of Chemical Engineers, U.K. (C. Eng., FIChemE), and a senior member of the American Institute of Chemical Engineers (AIChE). He holds a B.Sc. honors degree in Chemical Engineering, a Master of Science degree in Process Analysis and Development and Ph.D. in Chemical Engineering, all from Aston University, Birmingham, U.K., and a Teacher's Certificate in Education at the University of London, U.K. He has directed and conducted short courses extensively throughout the world and has been a lecturer at the university level. His articles have been published in several international journals. He is an author of six books in chemical engineering, a contributor to the Encyclopedia of Chemical Processing and Design, Vol 61 and a certified train - the mentor trainer. A Technical Report Assessor and Interviewer for chartered chemical engineers (IChemE) in the U.K. He is a member of the International Biographical Centre in Cambridge, U.K. (IBC) as Leading Engineers of the World for 2008. Also, he is a member of International Who's Who of ProfessionalsTM and Madison Who's Who in the U.S.
Content
Preface xv
Acknowledgements xvii
13 Rules of Thumb-Summary 1
13.0 Introduction 1
14 Process Planning, Scheduling, and Flowsheet Design 19
14.1 Introduction 19
14.2 Organizational Structure 20
14.2.1 Process Design Scope 21
14.3 Role of the Process Design Engineer 23
14.4 Computer-Aided Flowsheeting 24
14.5 Flowsheets-Types 26
14.5.1 Block Diagram 26
14.5.2 Process Flowsheet or Flow Diagram 26
14.5.3 Piping Flowsheet or Mechanical Flow Diagram, or Piping and Instrumentation Diagram (P&ID) 27
14.5.4 Combined Process and Piping Flowsheet or Diagram 32
14.5.5 Utility Flowsheets or Diagrams (ULDs) 32
14.5.6 Special Flowsheets or Diagrams 36
14.5.7 Special or Supplemental Aids 36
14.6 Flowsheet Presentation 36
14.7 General Arrangements Guide 36
14.8 Computer-Aided Flowsheet Design/Drafting 38
14.9 Flowsheet Symbols 40
14.10 Line Symbols and Designations 43
14.11 Materials of Construction for Lines 46
14.12 Test Pressure for Lines 47
14.13 Working Schedules 56
14.14 Information Checklists 61
14.15 Basic Engineering and Front End Engineering Design (FEED) 63
References 64
15 Fluid Flow 65
15.1 Introduction 65
15.2 Flow of Fluids in Pipes 65
15.3 Scope 70
15.4 Basis 72
15.5 Incompressible Flow 72
15.6 Compressible Flow: Vapors and Gases 73
15.7 Important Pressure Level References 75
15.8 Factors of "Safety" for Design Basis 75
15.9 Pipe, Fittings, and Valves 75
15.10 Pipe 75
15.11 Total Line Pressure Drop 78
15.11.1 Relationship Between the Pipe Diameter and Pressure Drop (¿P) 80
15.11.2 Economic Balance in Piping and Optimum Pipe Diameter 82
15.12 Reynolds Number, Re (Sometimes Used NRe) 83
15.13 Pipe Relative Roughness 85
15.14 Darcy Friction Factor, f 85
15.15 Friction Head Loss (Resistance) in Pipe, Fittings, and Connections 94
15.15.1 Pressure Drop in Straight Pipe: Incompressible Fluid 94
15.16 Oil System Piping 96
15.16.1 Density and Specific Gravity 97
15.16.2 Specific Gravity of Blended Products 98
15.16.3 Viscosity 98
15.16.4 Viscosity of Blended Products 100
15.16.5 Blending Index, H 101
15.16.6 Vapor Pressure 101
15.16.7 Velocity 101
15.16.8 Frictional Pressure Drop, ft of Liquid Head 104
15.16.9 Hazen-Williams Equation 105
15.16.10 Transmission Factor 107
15.16.11 Miller Equation 112
15.16.12 Shell-MIT Equation 113
15.17 Pressure Drop in Fittings, Valves, and Connections 116
15.17.1 Incompressible Fluid 116
15.17.2 Velocity and Velocity Head 116
15.17.3 Equivalent Lengths of Fittings 117
15.17.4 L/D Values in Laminar Region 120
15.17.5 Validity of K Values 122
15.17.6 Laminar Flow 122
15.17.7 Expressing All Pipe Sizes in Terms of One Diameter 124
15.17.8 Loss Coefficient 128
15.17.9 Sudden Enlargement or Contraction 134
15.17.10 For Sudden Contractions 134
15.17.11 Piping Systems 136
15.18 Resistance of Valves 136
15.19 Flow Coefficients for Valves, Cv 137
15.20 Flow Meters 138
15.20.1 Process Design of Orifice Meter 138
15.20.2 Nozzles and Orifices 142
Conclusion 167
15.21 Estimation of Pressure Loss Across Control Valves 169
15.22 The Direct Design of a Control Valve 173
15.23 Water Hammer 173
15.24 Friction Pressure Drop for Compressible Fluid Flow 175
15.24.1 Compressible Fluid Flow in Pipes 176
15.24.2 Maximum Flow and Pressure Drop 177
15.24.3 Sonic Conditions Limiting Flow of Gases and Vapors 177
15.24.4 The Mach Number, Ma 182
15.24.5 Critical Pressure Ratio 197
15.24.6 Adiabatic Flow 200
15.24.7 The Expansion Factor, Y 201
15.24.8 Misleading Rules of Thumb for Compressible Fluid Flow 203
15.24.9 Other Simplified Compressible Flow Methods 204
15.24.10 Friction Drop for Flow of Vapors, Gases and Steam 205
15.25 Darcy Rational Relation for Compressible Vapors and Gases 213
15.26 Velocity of Compressible Fluids in Pipe 215
15.27 Procedure 228
15.28 Friction Drop for Compressible Natural Gas in Long Pipe Lines 231
15.29 Panhandle-A Gas Flow Formula 235
15.30 Modified Panhandle Flow Formula 237
15.31 American Gas Association (AGA) Dry Gas Method 237
15.32 Complex Pipe Systems Handling Natural (or Similar) Gas 237
15.33 Two-Phase Liquid and Gas Flow in Process Piping 239
15.33.1 Flow Patterns 239
15.33.2 Flow Regimes 242
15.33.3 Pressure Drop 243
15.33.4 Erosion-Corrosion 248
15.33.5 Total System Pressure Drop 250
15.33.6 Pipe Sizing Rules 257
15.33.7 A Solution for All Two-Phase Problems 261
15.33.8 Gas-Liquid Two-Phase Vertical Down Flow 270
15.33.9 Pressure Drop in Vacuum Systems 277
15.33.10 Low Absolute Pressure Systems for Air 279
15.33.11 Vacuum for Other Gases and Vapors 281
15.33.12 Pressure Drop for Flashing Liquids 284
15.33.13 Sizing Condensate Return Lines 286
15.34 UniSim Design PIPESYS 295
15.35 Pipe Line Safety 300
15.36 Mitigating Pipeline Hazards 301
15.37 Examples of Safety Design Concerns 301
15.38 Safety Incidents Related With Pipeworks and Materials of Construction 303
15.39 Lessons Learned From Piping Designs 319
15.40 Design of Safer Piping 320
15.40.1 Best Practices for Process Piping 320
15.40.2 Designing Liquid Piping 321
15.40.3 Best Practices for Liquid Piping 322
Nomenclature 324
Greek Symbols 326
Subscripts 327
References 327
16 Pumps 331
16.1 Pumping of Liquids 331
16.2 Pump Design Standardization 336
16.3 Basic Parts of a Centrifugal Pump 336
16.4 Centrifugal Pump Selection 341
16.5 Hydraulic Characteristics for Centrifugal Pumps 359
16.6 Suction Head or Suction Lift, hs 367
16.7 Discharge Head, hd 369
16.8 Velocity Head 369
16.9 Friction 370
16.10 Net Positive Suction Head (NPSH) and Pump Suction 370
16.11 General Suction System 378
16.12 Reductions in NPSHR 384
16.13 Charting NPSHR Values of Pumps 384
16.14 Net Positive Suction Head (NPSH) 386
16.15 NPSH Requirement for Liquids Saturation With Dissolved Gases 388
16.16 Specific Speed 390
16.17 Rotative Speed 394
16.18 Pumping Systems and Performance 395
16.19 Power Requirements for Pumping Through Process Lines 399
16.20 Affinity Laws 405
16.21 Centrifugal Pump Efficiency 417
16.22 Effects of Viscosity 421
16.23 Temperature Rise and Minimum Flow 436
16.24 Centrifugal Pump Specifications 440
16.25 Number of Pumping Units 441
16.26 Rotary Pumps 448
16.27 Reciprocating Pumps 452
16.28 Pump Selection 456
16.29 Selection Rules-of-Thumb 456
16.30 Case Studies 459
16.31 Pump Cavitations 464
16.32 Pump Fundamentals 474
16.33 Operating Philosophy 475
16.34 Piping 485
16.35 Troubleshooting Checklist for Centrifugal Pumps 485
Nomenclature 493
Subscripts 494
Greek Symbols 495
References 495
17 Compression Equipment 497
17.1 Introduction 497
17.2 General Application Guide 498
17.3 Specification Guides 499
17.4 General Considerations for Any Type of Compressor Flow Conditions 501
17.4.1 Fluid Properties 501
17.4.2 Compressibility 502
17.4.3 Corrosive Nature 502
17.4.4 Moisture 502
17.4.5 Special Conditions 502
17.5 Reciprocating Compression 503
17.6 Suction and Discharge Valves 514
17.7 Specification Sheet 523
17.8 Performance Considerations 524
17.9 Compressor Performance Characteristics 557
17.10 Hydrogen Use in the Refinery 594
17.10.1 IsoTherming Technology for Kerosene, Vacuum Gas Oil, and Diesel Hydroprocessing 595
Nomenclature 829
Greek Symbols 832
Subscripts 832
References 833
Glossary of Petroleum and Technical Terminology 837
Appendix D 929
Appendix E 1005
Index 1019
About the Author 1025
13
Rules of Thumb-Summary
13.0 Introduction
An engineering Rule of Thumb is an outright statement regarding suitable sizes or performance of equipment that avoids all requirements for extended calculations. These are safely applied by engineers who are substantially familiar with the topics. However, such rules should be of value for approximate design and cost estimation, and should not provide the inexperienced engineer with perspective and a foundation where detailed and computer-aided results can be determined.
Experienced engineers often know where to find information and how to make accurate calculations; they also retain a minimum body of information in mind, which is made up largely of shortcuts and heuristics. The compilation below may fit into such a minimum body of information that boosts to the memory or extension in some instances into less often encountered areas.
COMPRESSORS, FANS, BLOWERS, AND VACUUM PUMPS
- 1. Fans are used to raise the pressure by about 3% [12 in. (30 cm) water], blowers raise to less than 2.75 barg (40 psig), and compressors to higher pressures, although the blower range is commonly included in the compressor range.
- 2. For vacuum pumps use the following: Reciprocating piston type down to 133.3 Pa (1 torr) Rotary piston type down to 0.133 Pa (0.001 torr) Two lobe rotary type down to 0.0133 Pa (0.0001 torr) Steam jet ejectors 1 stage down to 13.3 k Pa (100 torr) 3 stage down to 133.3 Pa (1 torr) 5 stage down to 6.7 Pa (0.05 torr)
- 3. A three-stage ejector needs 100 kg steam/kg air to maintain a pressure of 133.3 Pa (1 torr).
- 4. In-leakage of air to evacuated equipment depends on the absolute pressure (torr) and the volume of the equipment, V in m3 (ft3), according to W = kV2/3 kg/h (lb/h), with k = 0.98 (0.2) when P > 90 torr, k = 0.39 (0.08) when P is between 0.4 and 2.67 kPa (3 and 20 torr), and k = 0.12 (0.025) at p less than 133.3 Pa (1 torr).
- 5. Theoretical adiabatic horsepower
where T1 is inlet temperature in Rankine, R = °F + 460 and a = (k - 1)/k, k = Cp/Cv. Theoretical reversible adiabatic power = m?1RT1[({P2/P1}a - 1)]/a, where T1 is inlet temperature, R = Gas Constant, ?1 = compressibility factor, m = molar flow rate, a = (k - 1)/k and k = Cp/Cv. Values of °R = 8.314 J/mol K = 1.987 Btu/lb mol R = 0.7302 atm ft3/lb mol° R.
- 6. Outlet temperature for reversible adiabatic process
- 7. To compress air from 37.8° C (100°F), k = 1.4, compression ratio = 3, theoretical power required = 62 hp/million ft3/day, outlet temperature 152.2°C (306°F).
- 8. Exit temperature should not exceed 167-204° C (350-400° F); for diatomic gases (Cp/Cv = 1.4), this corresponds to a compression ratio of about 4.
- 9. Compression ratio should be about the same in each stage of a multistage unit, ratio = (Pn/P1)1/n, with n stages.
- 10. Efficiencies of reciprocating compressors: 65% at compression ratio of 1.5, 75% at 2.0, and 80-85% at 3-6.
- 11. Efficiencies of large centrifugal compressors, 2.83-47.2m3/s (6000-100,000 acfm) at suction, are 76-78%.
- 12. Rotary compressors have efficiencies of 70%, except liquid liner type which have 50%.
CONVEYORS FOR PARTICULATE SOLIDS
- 1. Screw conveyors are suited to transport of even sticky and abrasive solids up inclines of 20° or so. They are limited to distances of 3.81 m (150 ft) or so because of shaft torque strength. A 304.8 mm (12 in.) diameter conveyor can handle 28.3-84.95 m3/h (1000-3000 ft3/h), at speeds ranging from 40 to 60 rpm.
- 2. Belt conveyors are for high capacity and long distances (a mile or more, but only several hundred feet in a plant), up inclines of 30° maximum. A 609.6-mm (24 in.) wide belt can carry 84.95 m3/h (3000 ft3/h) at a speed of 0.508 m/s (100 ft/min), but speeds up to 3.048 m/s (600 ft/min) are suited to some materials. Power consumption is relatively low.
- 3. Bucket elevators are suited to vertical transport of sticky and abrasive materials. With 508 × 508-mm (20 × 20-in.) buckets, capacity can reach 28.3 m3/h (1000 ft3/h) at a speed of 0.508 m/s (100 ft/min), but speeds up to 1.524 m/s (300 ft/min) are used.
- 4. Drag-type conveyors (Redler) are suited to short distances in any direction and are completely enclosed. Units range in size from 19.4 × 10-4 to 122.6 × 10-4 m2 (3-19 in.2) and may travel from 0.15 m/s (30 ft/min) (fly ash) to 1.27 m/s (250 ft/min) (grains). Power requirements are high.
- 5. Pneumatic conveyors are for high capacity, short distance (122 m (400 ft)) transport simultaneously from several sources to several destinations. Either vacuum or low pressure 0.4-0.8 barg (6-12 psig) is used with a range of air velocities from 10.7 to 36.6 m/s (35-120 ft/s); depending on the material and pressure and air requirements, 0.03-0.2 m3/m3 (1-7 ft3/ft3) of solid is transferred.
COOLING TOWERS
- 1. Water in contact with air under adiabatic conditions eventually cools to the wet bulb temperature.
- 2. In commercial units, 90% of saturation of the air is feasible.
- 3. Relative cooling tower size is sensitive to the difference between the exit and the wet bulb temperatures: ?T, °F 5 15 25 Relative volume 2.4 1.0 0.55
- 4. Tower fill is of a highly open structure so as to minimize pressure drop, which is in standard practice a maximum of 497.6 Pa (2 in. of water).
- 5. Water circulation rate is 48.9-195.7 L/min m2 (1-4 gpm/ft2) and air rate is 6344-8784 kg/h m2 (1300-1800 lb/h ft2) or 1.52-2.03 m/s (300-400 ft/min).
- 6. Chimney-assisted natural draft towers are hyperboloidally shaped because they have greater strength for a given thickness; a tower 76.2 m (250 ft) high has concrete walls 127-152.4 mm (5-6 in.) thick. The enlarge cross section at the top aids in dispersion of exit humid air into the atmosphere.
- 7. Countercurrent-induced draft towers are the most common in process industries. They are able to cool water within 2°F of the wet bulb.
- 8. Evaporation losses are 1% of the circulation for every 10°F of cooling range. Windage or drift losses of mechanical draft towers are 0.1-0.3% Blowdown of 2.5-3.0% of the circulation is necessary to prevent excessive salt buildup.
CRYSTALLIZATION FROM SOLUTION
- 1. Complete recovery of dissolved solids is obtainable by evaporation, but only to the eutectic composition by chilling. Recovery by melt crystallization also is limited by the eutectic composition.
- 2. Growth rates and ultimate sizes of crystals are controlled by limiting the extent of supersaturation at any time.
- 3. The ratio S = C/Csat of prevailing concentration to saturation concentration is kept near the range 1.02-1.05.
- 4. In crystallization by chilling, the temperature of the solution is kept almost 1-2°F below the saturation temperature at the prevailing concentration.
- 5. Growth rates of crystals under satisfactory conditions are in the range of 0.1-0.8 mm/h. The growth rates are approximately the same in all directions.
- 6. Growth rates are influenced greatly by the presence of impurities and of certain specific additives, which vary from case to case.
DISINTEGRATION
- 1. Percentages of material greater than 50% of the maximum size are about 50% from rolls, 15% from tumbling mills, and 5% from closed-circuit ball mills.
- 2. Closed-circuit grinding employs external size classification and return of oversize for regrinding. The rules of pneumatic conveying are applied to the design of air classifiers. Closed circuit is most common with ball and roller mills.
- 3. Jaw crushers take lumps of several feet in diameter to 102 mm (4 in.). Stroke rates are 100-300/min. The average feed is subjected to 8-10 strokes before it becomes small enough to escape. Gyratory crushers are suited to slabby feeds and makes a more rounded product.
- 4. Roll crushers are made either smooth or with teeth. A 610-mm (24-in.) toothed roll can accept lumps of 356 mm (14 in.) diameter. Smooth rolls affect reduction ratios up to about 4. Speeds are 50-90 rpm. Capacity is about 25% of the maximum, corresponding to a continuous ribbon of material passing through the rolls.
- 5. Hammer mills beat the material until it is small enough to pass through the screen at the bottom of the casing....
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