
Physics of Solar Energy and Energy Storage
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Join the fight for a renewable world with this indispensable introduction
Solar energy is one of the most essential tools in the fight to create a sustainable future. A wholly renewable and cost-effective energy source capable of providing domestic, business, and industrial energy, solar energy is expected to become a $223 billion a year industry by 2026. The future of global energy production demands researchers and engineers who understand the physics of harnessing, storing, and distributing solar energy.
Physics of Solar Energy and Energy Storage begins to meet this demand, with a thorough, accessible overview of the required fundamentals. Now fully updated to reflect the past decade of research amidst a growing understanding of the scale of our collective challenge, it promises to train the next generation of researchers and engineers who will join this vital effort.
Readers of the second edition of Physics of Solar Energy and Energy Storage will find:
* A particular focus on lithium-ion rechargeable batteries
* Detailed discussions of photovoltaic solar systems, concentrating solar systems, passive solar heating, and more
* Homework problems and exercises throughout to reinforce learning
Physics of Solar Energy and Energy Storage is ideal for mechanical, chemical, or electrical engineers working on solar or alternative energy projects, as well as researchers and policymakers in related fields.
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Person
C. Julian Chen is an adjunct professor and Senior Research Scientist in the Department of Applied Physics and Applied Mathematics at Columbia University since 2007. Prior to his time as an academic, he spent fifteen years in IBM's TJ Watson Research Center, where he performed research on scanning tunneling microscopy (STM). To continue STM research, he served as a Professor of Physics at Hamburg University for three years.
Content
- Cover
- Title Page
- Copyright
- Contents
- List of Figures
- List of Tables
- Preface to the Second Edition
- Preface to the First Edition
- Chapter 1: Introduction
- 1.1 Shaping a More Livable World
- 1.1.1 Fossil Fuels and Beyond
- 1.1.2 The Paris Agreement
- 1.1.3 Phasing Out Coal-Generated Power
- 1.1.4 Phasing Out ICE Vehicles
- 1.1.5 Economics of Renewable Energy
- 1.2 Solar Energy
- 1.3 Solar Photovoltaics
- 1.3.1 Birth of Modern Solar Cells
- 1.3.2 Basic Terms and Concepts on Solar Cells
- 1.3.3 Types of Solar Cells
- 1.4 A Rechargeable Battery Primer
- 1.4.1 Whittingham's Initial Invention
- 1.4.2 Goodenough's Improved Cathode
- 1.4.3 Yoshino's Improved Anode
- 1.4.4 Current Status
- 1.5 Other Renewable Energy Resources
- 1.5.1 Hydroelectric Power
- 1.5.2 Wind Power
- 1.5.3 Biomass and Bioenergy
- 1.5.4 Shallow Geothermal Energy
- 1.5.5 Deep Geothermal Energy
- 1.5.6 Tidal Energy
- Chapter 2: Nature of Solar Radiation
- 2.1 Light as Electromagnetic Waves
- 2.1.1 Maxwell's Equations
- 2.1.2 Vector Potential and Scalar Potential
- 2.1.3 Electromagnetic Waves
- 2.1.4 Plane Waves and Polarization
- 2.1.5 Sinusoidal Waves
- 2.2 Interface Phenomena
- 2.2.1 Relative Dielectric Constant and Refractive Index
- 2.2.2 Energy Balance and Poynting Vector
- 2.2.3 Fresnel Formulas
- 2.2.4 Optics of metals
- 2.3 Blackbody Radiation
- 2.3.1 Rayleigh-Jeans Law
- 2.3.2 Planck Formula and Stefan-Boltzmann's Law
- 2.4 Photoelectric Effect and Concept of Photons
- 2.4.1 Einstein's Theory of Photons
- 2.4.2 Millikan's Experimental Verification
- 2.4.3 Electron as a Field
- 2.5 Einstein's Derivation of Blackbody Formula
- Chapter 3: Origin of Solar Energy
- 3.1 Basic Parameters of the Sun
- 3.1.1 Distance
- 3.1.2 Mass
- 3.1.3 Radius
- 3.1.4 Emission Power
- 3.1.5 Surface Temperature
- 3.1.6 Composition
- 3.2 Kelvin-Helmholtz Time Scale
- 3.3 Energy Source of the Sun
- 3.3.1 The p - p Chain
- 3.3.2 Carbon Chain
- 3.3.3 Internal Structure of the Sun
- Chapter 4: Tracking Sunlight
- 4.1 Rotation of Earth: Latitude and Longitude
- 4.2 Celestial Sphere
- 4.2.1 Coordinate Transformation: Cartesian Coordinates
- 4.2.2 Coordinate Transformation: Spherical Trigonometry
- 4.3 Treatment in Solar Time
- 4.3.1 Obliquity and Declination of the Sun
- 4.3.2 Sunrise and Sunset Time
- 4.3.3 Direct Solar Radiation on an Arbitrary Surface
- 4.3.4 Direct Daily Solar Radiation Energy
- 4.3.5 The 24 Solar Terms
- 4.4 Treatment in Standard Time
- 4.4.1 Sidereal Time and Solar Time
- 4.4.2 Right Ascension of the Sun
- 4.4.3 Time Difference Originated from Obliquity
- 4.4.4 Aphelion and Perihelion
- 4.4.5 Time Difference Originated from Eccentricity
- 4.4.6 Equation of Time
- 4.4.7 Declination of the Sun
- 4.4.8 Analemma
- Chapter 5: Interaction of Sunlight with Earth
- 5.1 Interaction of Radiation with Matter
- 5.1.1 Absorptivity, Reflectivity, and Transmittivity
- 5.1.2 Emissivity and Kirchhoff's Law
- 5.1.3 Bouguer-Lambert-Beer's Law
- 5.2 Interaction of Sunlight with Atmosphere
- 5.2.1 AM1.5 Reference Solar Spectral Irradiance
- 5.2.2 Annual Insolation Map
- 5.3 Penetration of Solar Energy into Earth
- Chapter 6: Thermodynamics of Solar Energy
- 6.1 Definitions
- 6.2 First Law of Thermodynamics
- 6.3 Second Law of Thermodynamics
- 6.3.1 Carnot Cycle
- 6.3.2 Thermodynamic Temperature
- 6.3.3 Entropy
- 6.4 Thermodynamic Functions
- 6.4.1 Free Energy
- 6.4.2 Enthalpy
- 6.4.3 Gibbs Free Energy
- 6.4.4 Chemical Potential
- 6.5 Ideal Gas
- 6.6 Ground Source Heat Pump and Air Conditioning
- 6.6.1 Theory
- 6.6.2 Coefficient of Performance
- 6.6.3 Vapor-Compression Heat Pump and Refrigerator
- 6.6.4 Ground Heat Exchanger
- Chapter 7: A Quantum Mechanics Primer
- 7.1 The Static Schr¨odinger Equation
- 7.1.1 Wavefunctions in a One-Dimensional Potential Well
- 7.1.2 The Bra-and-Ket Notations
- 7.1.3 The Harmonic Oscillator
- 7.1.4 The Hydrogen Atom
- 7.1.5 The Stern-Gerlach Experiment
- 7.1.6 Nomenclature of Atomic States
- 7.1.7 Degeneracy and Wavefunction Hybridization
- 7.2 Many-Electron Systems
- 7.2.1 The Self-Consistent Field (SCF) Method
- 7.2.2 Slater Determinates and the Hartree-Fock Method .
- 7.2.3 Density-Functional Theory (DFT)
- 7.2.4 HOMO and LUMO
- 7.3 The Chemical Bond
- 7.3.1 Bonding Energy and Antibonding Energy
- 7.3.2 The Hydrogen Molecular Ion
- 7.3.3 Types of Chemical Bonds
- 7.4 The Solid State
- 7.4.1 Bloch Waves and Energy Bands
- 7.4.2 Effective Mass
- 7.4.3 Conductor, Semiconductor, and Insulator
- 7.4.4 Semiconductors
- 7.4.5 The Band Structure of Silicon
- 7.5 The Dynamic Schr¨odinger Equation
- 7.5.1 A Heuristic Derivation
- 7.5.2 Reduction to Static Schr¨odinger's Equation
- 7.5.3 Meaning of the Time-Dependent Phase Factor
- 7.5.4 Interaction with Radiation
- Chapter 8: pn-Junctions
- 8.1 Semiconductors
- 8.1.1 Electrons and Holes
- 8.1.2 p-Type and n-Type Semiconductors
- 8.2 Formation of a pn-Junction
- 8.3 Analysis of pn-Junctions
- 8.3.1 Effect of Bias Voltage
- 8.3.2 Lifetime of Excess Minority Carriers
- 8.3.3 Junction Current
- 8.3.4 Shockley Equation
- 8.4 Light-Emitting Diodes for Illumination
- 8.4.1 Invention of the Blue LED
- 8.4.2 The Working Principle
- 8.4.3 Wavelength Engineering
- 8.4.4 The Freestanding GaN Substrate
- 8.4.5 A Brief Sketch of History
- Chapter 9: Semiconductor Solar Cells
- 9.1 Basic Concepts
- 9.1.1 Generating Electric Power
- 9.1.2 Solar Cell Equation
- 9.1.3 Maximum Power and Fill Factor
- 9.2 The Shockley-Queisser Limit
- 9.2.1 Ultimate Efficiency
- 9.2.2 Role of Recombination Time
- 9.2.3 Detailed-Balance Treatment
- 9.2.4 Nominal Efficiency
- 9.2.5 Shockley-Queisser Efficiency Limit
- 9.2.6 Efficiency Limit for AM1.5 Radiation
- 9.3 Nonradiative Recombination Processes
- 9.3.1 Auger Recombination
- 9.3.2 Trap-State Recombination
- 9.3.3 Surface-State Recombination
- 9.4 Antireflection Coatings
- 9.4.1 Matrix Method
- 9.4.2 Single-Layer Antireflection Coating
- 9.4.3 Double-Layer Antireflection Coatings
- 9.5 Crystalline Silicon Solar Cells
- 9.5.1 Production of Pure Silicon
- 9.5.2 Solar Cell Design and Processing
- 9.5.3 Module Fabrication
- 9.6 Thin-Film Solar Cells
- 9.6.1 CdTe Solar Cells
- 9.6.2 CIGS Solar Cells
- 9.6.3 Amorphous Silicon Thin-Film Solar Cells
- 9.7 Tandem Solar Cells
- Chapter 10: Solar Photochemistry
- 10.1 Physics of Photosynthesis
- 10.1.1 Chlorophyll
- 10.1.2 ATP: Universal Energy Currency of Life
- 10.1.3 NADPH and NADP+
- 10.1.4 Calvin Cycle
- 10.1.5 C4 Plants versus C3 Plants
- 10.1.6 Chloroplast
- 10.1.7 Efficiency of Photosynthesis
- 10.2 Artificial Photosynthesis
- 10.3 Genetically Engineered Algae
- 10.4 Dye-Sensitized Solar Cells
- 10.5 Bilayer Organic Solar Cells
- Chapter 11: Solar Thermal Energy
- 11.1 Early Solar Thermal Applications
- 11.2 Solar Heat Collectors
- 11.2.1 Selective Absorption Surface
- 11.2.2 Flat-Plate Collectors
- 11.2.3 All-Glass Vacuum-Tube Collectors
- 11.2.4 Thermosiphon Solar Heat Collectors
- 11.2.5 High-Pressure Vacuum Tube Collectors
- 11.3 Solar Water Heaters
- 11.4 Solar Thermal Power Systems
- 11.4.1 Parabolic Trough Concentrator
- 11.4.2 Central Receiver with Heliostats
- 11.4.3 Paraboloidal Dish Concentrator with Stirling Engine
- Chapter 12: Physical Energy Storage
- 12.1 Pumped Hydro Storage
- 12.2 Sensible Heat Energy Storage
- 12.2.1 Water
- 12.2.2 Solid Sensible Heat Storage Materials
- 12.2.3 Synthetic Oil in Packed Beds
- 12.3 Phase Transition Thermal Storage
- 12.3.1 Water-Ice Systems
- 12.3.2 Paraffin Wax and Other Organic Materials
- 12.3.3 Salt Hydrates
- Chapter 13: Rechargeable Batteries
- 13.1 An Electrochemistry Primer
- 13.1.1 Basic Terms and Definitions
- 13.1.2 Oxidation State
- 13.1.3 Standard Oxidation-Reduction Potentials
- 13.2 Lithium-Ion Batteries
- 13.2.1 Benefit to Humankind
- 13.2.2 Intercalation of Metal Ions
- 13.2.3 The Cathode Materials
- 13.2.4 The Anode Materials
- 13.2.5 Electrolytes
- 13.2.6 The Separator
- 13.2.7 Packaging
- 13.2.8 Mineral Resource of Lithium
- 13.3 Sodium-Ion Batteries
- 13.3.1 The Cathode Materials
- 13.3.2 The Anode Materials
- 13.3.3 Rest of the System
- 13.4 Traditional Rechargeable Batteries
- 13.4.1 Lead-Acid Batteries
- 13.4.2 Nickel Metal Hydride Batteries
- Chapter 14: Building with Sunshine
- 14.1 Early Solar Architecture
- 14.1.1 Ancient Solar Architecture
- 14.1.2 Holistic Architecture in Rural China
- 14.2 Building Materials
- 14.2.1 Thermal Resistance
- 14.2.2 Specific Thermal Resistance
- 14.2.3 Heat Transfer Coefficient: The U-Value
- 14.2.4 Thermal Mass
- 14.2.5 Glazing
- 14.3 Example of Holistic Design
- Appendix A: Energy Unit Conversion
- Appendix B: Spherical Trigonometry
- B.1 Spherical Triangle
- B.2 Cosine Formula
- B.3 Sine Formula
- B.4 Formula C
- Appendix C: Vector Analysis and Determinants
- C.1 Vector Analysis
- C.2 Determinants
- Appendix D: Real Spherical Harmonics
- D.1 The Spherical Coordinate System
- D.2 Spherical Harmonics
- Appendix E: Complex Numbers
- E.1 Definition of Complex Numbers
- E.2 The Euler Formula
- Appendix F: Statistics of Particles
- F.1 Maxwell-Boltzmann Statistics
- F.2 Fermi-Dirac Statistics
- F.3 Bose-Einstein Statistics
- Appendix G: Measurement in Quantum Mechanics
- G.1 The Measurement Postulate
- G.2 Experiments in Position Detection
- G.3 Tomographic Imaging of Wavefunctions
- G.4 Einstein's Opinion on Quantum Mechanics
- G.5 A Modern View of Schr¨odinger's Cat
- G.6 A Natural Presentation of Quantum Mechanics
- Bibliography
- Index
- EULA
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