
Introduction to Propellants
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Content
- Intro
- Contents
- Preface
- Chapter 1
- The Overview of Solid Propellants
- Abstract
- 1. Advantages of Solid Propellants
- 2. A Brief History of the Development
- of Solid Propellants
- 3. Classification of Solid Propellants
- 4. Main Component of Solid Propellant
- References
- Chapter 2
- Research Progress for Binders of Solid Propellants
- Abstract
- 1. Introduction
- 1.1. Function of Binders for Solid Propellants
- 1.2. Development of Binders for Solid Propellants
- 1.3. Development Trend of Binders for Solid Propellants
- 2. Requirements of Solid Propellants for Polymer Binders
- 2.1. Properties Requirement for Binder of Solid Propellants
- 2.2. Requirements for Binders of Cross-Linked Modified Double - Base Propellants
- 2.3. Requirements for Binders for Composite Solid Propellants
- 2.4. Requirements for Binder for NEPE Propellants
- 2.5. Requirements for Energetic Binders for Solid Propellants
- 3. Effect of Polymer Binders on Properties of Solid Propellants
- 3.1. Effect of Energy Performance
- 3.1.1. Enthalpy for Formation of Binders
- 3.1.2. Oxygen Content of Binder
- 3.1.3. Hydrogen/Carbon Ratio of the Binder
- 3.2. Effect of Combustion Performance
- 3.3. Effect of Mechanical Properties
- 3.3.1. Effect of Binder on Mechanical Properties of Double Base Propellants
- 3.3.2. Effect of Binder on Mechanical Properties of Composite Solid Propellants
- 3.3.2.1. Chain Structure of Binder Prepolymer
- 3.3.2.2. Relative Molecular Weight and Distribution of Binder Prepolymer
- 3.3.2.3. Function and Its Distribution
- 3.3.2.4. Properties of the Cured Cross-Linking Agent
- 3.3.2.5. Effect of Plasticizer
- 3.3.3. The Effect of Binder on the Mechanical Properties of NEPE Propellant
- 3.4. Effect of Storage Performance
- 3.5. Effect of Security Performance
- 4. Types of Polymer Binders for Solid Propellants
- 4.1. Inertia Binder
- 4.1.1. Thermosetting Binder
- 4.1.1.1. Polysulfide Rubber Binder (PSR)
- 4.1.1.2. Polyurethane Binder (PU)
- 4.1.1.3. Polybutadiene Binder
- 1. Binders of Copolymer of Butadiene and Acrylic Acid (PBAA)
- 2. Butadiene/Acrylic/Acrylonitrile Trimer Binder (PBAN)
- 3. Carboxyl Terminated Polybutadiene Binder (CTPB)
- 4. Hydroxyl Terminated Polybutadiene Binder (HTPB)
- 4.1.1.4. NEPE Propellants Binder
- 4.1.2. Thermoplastic Binders
- 4.1.2.1. Binder of PVC Plastic Sol
- 4.1.2.2. Thermoplastic Elastomer (TPE)
- 4.1.3. Interpenetrating Network Structure Binder
- 4.2. Energetic Binder
- 4.2.1. Thermosetting Energetic Binder
- 4.2.1.1. Azide Energetic Prepolymer Binder
- 4.2.1.2. Nitrate Ester Energetic Prepolymer Binder
- 4.2.1.3. Nitrate-Containing Prepolymer Binder
- 4.2.1.4. Difluoroamino Energetic Prepolymer Binder
- 4.2.1.5. Energetic Prepolymer Binder with Two or More Energetic Groups
- 4.2.2. Thermoplastic Energy-Containing Binder
- 4.2.2.1. Polyazide Glycidyl Ether Based Energetic Thermoplastic Elastomer
- 4.2.2.2. 3, 3-bis (Azide Methyl) Oxygen Hetero-Butyl Group Energetic Thermoplastic Elastomer
- 4.2.2.3. Other Thermoplastic Elastomers Containing Energy
- 4.3. Comprehensive Review of Binders
- Conclusion
- References
- Chapter 3
- Recent Simple Methods for Prediction of the Specific Impulse of Energetic Compounds Rather Than Using Complex Computer Codes
- Abstract
- Introduction
- Methods
- Specific Impulse
- Computer Codes for Prediction of the Specific Impulse
- CEA
- ProPep
- RPA
- ISPBKW
- Empirical Methods for Assessment of Specific Impulse
- Combustion Temperature
- Molecular Structure
- Heat of Detonation
- Oxygen Balance (OB)
- The Relation between Specific Impulse and Detonation Parameters
- Detonation Pressure
- Detonation Velocity
- Correlations between Gurney Velocity and the Specific Impulse
- Conclusion
- References
- Biographical Sketch
- Chapter 4
- On the Thermodynamics of Propellant Solids
- Abstract
- 1. Introduction
- 2. Laws of Thermodynamics
- 3. Thermodynamics of Gases
- 4. Adiabatic Flame Temperature
- 5. Cryogenic Reactants
- 5.1. Molecular Weight
- 5.2. Specific Heat Ratio
- 6. Mixtures of Gases
- 6.1. Chemical Reactions
- Conclusion
- References
- Chapter 5
- Two-Phase Internal Flows in Solid Propellant Environments
- Chapter 6
- Combustion Performance of Solid Propellant
- Abstract
- 1. Introduction
- 2. Measures to Improve the Combustion Performance of Solid Propellant
- 2.1. Influence of Binders
- 2.1.1. Composite Propellant
- 2.1.2. Double Base Propellants and Double Base Modified Propellants
- 2.1.3. NEPE Propellant
- 2.2. Effects of Oxidizer and Aluminum Powder
- 2.3. Action of Catalyst
- 2.3.1. Composite Propellant
- 2.3.2. Double Base Propellant and Modified Double Base Propellant
- 3. Measures to Reduce Combustion Rate of Solid Propellant
- 3.1. Measures to Reduce the Combustion Performance of Double Base Propellant
- 3.1.1. Application of Rate Reducer
- 3.1.2. Change the Particle Size of High-Energy Components
- 3.2. Measures to Reduce the Combustion Performance of HTPB Composite Solid Propellant
- 3.2.1. Regulation of Combustion Performance of HTPB Solid Propellant by Rate Reducer
- 3.2.2. Adjust the Particle Size to Reduce the Burn Rate of HTPB Composite Propellant
- 3.3. Improving the Process Performance of HTPB Composite Propellant to Reduce Burn Rate
- 3.4. Measures to Reduce Combustion Performance of NEPE Composite Propellant
- 3.4.1. Influence of Rate Reducer on NEPE Combustion Performance
- 3.4.2. Influence of Nitrate Type on Combustion Performance of NEPE Propellant
- 3.4.3. Influence of Oxidizer Particle on Combustion Performance of NEPE Propellant
- 3.5. Influence of Binder on Burn Rate
- Conclusion
- References
- Chapter 7
- Research Progress on Storage Performance Regulation of Solid Propellant
- Abstract
- 1. Summary
- 2. The Mechanism and Influence Factors of Solid Propellant Storage and Aging
- 2.1. Physical Aging of Solid Propellant during Storage
- 2.2. Chemical Aging of Solid Propellant during Storage
- 2.2.1. Factors Affecting Chemical Aging of Solid Propellant
- 2.2.1.1. Influence of Propellant Components
- 2.2.1.2. Influence of Humidity
- 2.2.1.3. Influence of Storage Temperature
- 2.2.2. Chemical Aging Mechanism of Several Solid Propellants
- 2.2.2.1. Solid Propellant Containing Nitrates
- 2.2.2.2. Polybutadiene Composite Solid Propellant
- 3. The Research Progress of Stabilizer, Anti-Aging Agents and Other Auxiliaries in Solid Propellant
- 3.1. Research Progress of Anti-Aging Agents
- 3.1.1. Introduction to Anti-Aging Agent
- 3.1.2. Anti-Aging Agent H
- 3.1.2.1. Influence of Anti-Aging Agent H on Mechanical Properties of Propellants Cured by TDI and IPDI
- 3.1.2.2. Comparison of Effects of Anti-Aging Agent H on Mechanical Properties of Propellants cured by TDI and IPDI
- 3.1.2.3. The Reason Why the Elongation of Propellant cured by TDI at Low Temperature Is Higher Than That of Propellant cured by IPDI When Containing Anti-Aging Agent H
- 3.1.2.4. IPDI/HTPB Propellant and Anti-Aging Agent H
- 3.1.3. Synergistic and Antagonistic Effects of Anti-Aging Agents
- 3.2. Research Progress of Stabilizers
- 4. The Research Progress of the Methods for Predicting Solid Propellant Service Life
- 4.1. Prediction of the Storage Period of Nitrate-Containing Propellant
- 4.1.1. Take the Quality Change of Stabilizer as the Failure Model
- 4.1.1.1. Sample Types, i.e., the Main Components
- 4.1.1.1.1. Test Methods
- 4.1.1.1.2. Test Improvement-Single Temperature Short-Period Prediction Method
- 4.1.1.1.3. Experimental Conclusions
- 4.1.2. Take the Mechanical Property Change of Stabilizer as the Failure Model [14]
- 4.1.2.1. Estimation Method
- 4.1.2.2. Estimation Conclusion
- 4.2. Aging Performance Research Methods and Storage Life Prediction of Composite Propellant
- Conclusion and Prospect
- References
- Chapter 8
- Molecular Simulation Study of Solid Propellant
- Abstract
- 1. Molecular Simulation Method
- 2. Application of Molecular Simulation Methods in the Field of Energetic Materials
- 2.1. Interface Interaction for the Bonding Agents
- 2.2. Binder-Solid Filler Interaction in PBX
- 2.3. Binder-Solid Filler Interaction in Solid Propellants
- 2.4. Binders and Plasticizers
- 2.5. Plasticizer Migration
- 2.6. Energetic Compound Crystal
- 2.7. Compatibility
- 2.7.1. Importance of Compatibility Research
- 2.7.2. Progress in Compatibility Research
- 2.8. Mesoscopic Simulation
- Conclusion
- References
- About the Editors
- Index
- Blank Page
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