Spin-1 NMR
Published on 6. December 2012
VIII, 122 pages
978-3-642-61089-9 (ISBN)
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"For someone just entering the field this work provides a clear introduction covering all aspects...For experts it provides an up-to-date course of references." Applied MAGNETIC ResonanceMore details
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Content
The Basic Physics of Spin-1 Systems.- 1.1 General Introduction.- 1.2 Spin States and Matrix Representations of Operators for Spin-1.- 1.3 Spin-1 Operator Algebra.- 1.4 Löwdin Projectors for Spin-1.- 1.5 Interactions Relevant in Spin-1 NMR.- 1.6 Pulse Rotations.- 1.7 Density Matrix Description of the State of Spin-1 Ensembles.- 1.8 Evolution of the Spin-1 System Under Quadrupolar Coupling.- 1.9 Phase Changes of Spin-1 Wavefunctions Under Rotation.- 1.10 Evolution of the Spin-1-Spin-1/2 System Under Scalar Coupling.- 1.11 Spin Tickling in a Spin-l/2-Spin-l Scalar Coupled System.- 1.12 Evolution of the Spin-l-Spin-1 System Under Scalar Coupling.- 1.13 Coherence Transfer Function for Spin-1 Systems.- 1.14 Quadrupolar Relaxation.- 1.15 Spin-1 Behavior of Two Equivalent Spins-1/2.- NMR of Systems Involving Spin-1 Nuclei in the Isotropic Phase..- 2.1 Chemical Shift Information.- 2.2 General Spectral Features Consequent on Coupling to Spin-1.- 2.3 Laboratory Frame Polarization Transfer Involving Spin-1 Nuclei.- 2.4 INEPT Polarization Transfer from Spin-1 (S) to Spin-1/2 (I).- 2.5 DEPT Polarization Transfer from Spin-1 (S) to Spin-1/2 (I).- 2.6 Polarization Transfer from Spin-1/2 (I) to Spin-1 (S).- 2.7 Pulse Width Calibration for Polarization Transfer Experiments.- 2.8 Polarization Transfer Between Spin-1 Nuclei.- 2.9 Two-Dimensional Experiments Involving Spin-1 Nuclei.- 2.10 Correlation Spectroscopy (COSY).- 2.11 Heteronuclear Multiple Quantum Spectroscopy.- 2.12 Homonuclear Multiple Quantum Spectroscopy.- 2.13 Relayed Correlation Spectroscopy.- 2.14 Instrumentation for High Resolution Spin-1 NMR.- 3 NMR of Spin-1 Systems in the Solid State.- 3.1 Introduction.- 3.2 Quadrupolar Echo.- 3.3 Jeener-Broekaert Sequence.- 3.4 Deuterium NMR Spectroscopy of Single Crystal Systems.-3.5 Two-Dimensional Deuterium COSY Spectra in the Solid State.- 3.6 Deuterium NMR Under Magic Angle Spinning.- 3.7 Double Quantum Spectroscopy.- 3.8 QUADSHIFT Experiment.- 3.9 Overtone Spectroscopy.- 3.10 Spin-1/2-Spin-1 Dipolar Coupling.- 3.11 Spin Alignment.- 3.12 Deuterium Exchange Spectroscopy in Single Crystals.- 3.13 Deuterium Exchange Spectroscopy.- 3.14 Spin-1 Double Quantum Imaging.- 3.15 Instrumentation for Solid State NMR.- 4 Reference.
