
Functional Materials for Solid Oxide Fuel Cells: Processing, Microstructure and Performance
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Solid Oxide Fuel Cells (SOFCs) have received great attention among researchers in the past few decades due to their high electrochemical energy conversion efficiency, environmental friendliness, fuel flexibility and wide range of applications. This volume is a contribution from renowned researchers in the scientific community interested in functional materials for SOFCs. Chapters in this volume emphasize the processing, microstructure and performance of electrolyte and electrode materials. Contributors review the main chemical and physical routes used to prepare ceramic/composite materials, and explain a variety of manufacturing techniques for electrode and electrolyte production and characterization. Readers will also find information about both symmetrical and single fuel cells. The book is a useful reference for students and professionals involved in SOFC research and development.
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Content
- Intro
- CONTENTS
- FOREWORD
- PREFACE
- List of Contributors
- INTRODUCTION
- Introduction to Solid Oxide Fuel Cells
- João Paulo de Freitas Grilo1, Caroline Gomes Moura2 and Daniel Araújo de Macedo3,*
- INTRODUCTION
- SOFC ELECTRODES
- Cathode
- Anode
- CONFLICT OF INTEREST
- ACKNOWLEDGEMENTS
- REFERENCES
- Cathode Materials for High-Performing Solid Oxide Fuel Cells
- Hanping Ding1,2,*
- INTRODUCTION
- Technical Parameters for SOFC Cathodes
- Typical Materials for Cathode and their Conducting Nature
- Perovskite
- Mechanism of ORR Catalysis
- Prediction of Catalysts for ORR
- Basic Guidelines for Tailoring Electrical Properties
- Development of Low-temperature Cathode Materials
- The Parameters for Characterizing the Excellence of Cathodes
- (a). Electrical Conductivity
- (b). Polarization Resistance
- (c). Oxygen Surface Exchange and Diffusion Coefficient
- High-Performance Cathodes Operating at Low Temperatures
- (a). ABO3-type Perovskite
- (b). A2B2O5+d-type Double Perovskite
- CONCLUDING REMARKS
- CONFLICT OF INTEREST
- ACKNOWLEDGEMENTS
- REFERENCES
- A Brief Review on Anode Materials and Reactions Mechanism in Solid Oxide Fuel Cells
- Caroline Gomes Moura1,*, João Paulo de Freitas Grilo2, Rubens Maribondo do Nascimento3,* and Daniel Araújo de Macedo4
- INTRODUCTION
- Anode Materials
- NiO-GDC Composites
- ELECTROCHEMICAL PROCESSES IN SOFC ELECTRODES
- CONCLUDING REMARKS
- CONFLICT OF INTEREST
- ACKNOWLEDGEMENTS
- REFERENCES
- Recent Advances in Synthesis of Lanthanum Silicate Apatite Powders as New Oxygen-Ion Conductor for IT-SOFCs: A Review
- Chieko Yamagata*, Daniel R. Elias, Agatha M. Misso and Fernando S. Santos
- INTRODUCTION
- LANTHANUM SILICATE APATITE (LSA)
- LANTHANUM SILICATE APATITE (LSA) POWDER SYNTHESIS
- Conventional Solid-State Reaction Synthesis
- Sol-gel Synthesis
- Coprecipitation Synthesis Method
- Pechini Synthesis Method
- Hydrothermal Synthesis Method
- Freeze-Drying Synthesis
- Plasma Spraying Synthesis
- High-Energy Ball Milling Synthesis
- Combined Synthesis Methods
- CONFLICT OF INTEREST
- ACKNOWLEDGEMENTS
- REFERENCES
- A Review on Synthesis Methods of Functional SOFC Materials
- Flávia de Medeiros Aquino1,*, Patrícia Mendonça Pimentel2,* and Dulce Maria de Araújo Melo3
- INTRODUCTION
- TYPES OF SYNTHESIS METHODS
- Solid State Reaction (Mixture of Oxides)
- Experimental Procedure of Solid State Reaction
- Combustion Synthesis
- Experimental Procedure of the Combustion Synthesis
- Sol-gel
- Experimental Procedure of Sol-gel Method
- Polymeric Complexing Method
- Experimental Procedure of Polymeric Complexing Method
- Co-precipitation Method
- Experimental Procedure of Co-precipitation Method
- CONFLICT OF INTEREST
- ACKNOWLEDGEMENTS
- REFERENCES
- Ceramic Hollow Fibers: Fabrication and Application on Micro Solid Oxide Fuel Cells
- Xiuxia Meng1, Naitao Yang1,*, Xiaoyao Tan2 and Shaomin Liu3,*
- INTRODUCTION
- MICRO TUBULAR SOLID OXIDE FUEL CELL: ADVANTAGES AND FABRICATIONS
- BASIC PRINCIPLES OF THE PHASE INVERSION TECHNIQUE
- SINGLE-LAYER SPINNING FOR SOFC
- DUAL-LAYER CO-SPINNING FOR MT-SOFC
- TRIPLE-LAYER CO-SPINNING
- CONCLUSION REMARKS
- CONFLICT OF INTEREST
- ACKNOWLEDGEMENTS
- REFERENCES
- Electrolyte Hollow Fiber as Support via Phase-Inversion-Based Extrusion/Sintering Technique for Micro Tubular Solid Oxide Fuel Cell
- Mohd Hafiz Dzarfan Othman*, Siti Munira Jamil, Mukhlis A. Rahman, Juhana Jaafar and A.F. Ismail
- INTRODUCTION
- Phase-Inversion Based Extrusion/Sintering Technique for Fabrication of Ceramic Hollow Fiber
- Electrolyte-supported Hollow Fiber
- Electrolyte as Thin Layer
- CONCLUDING REMARKS
- CONFLICT OF INTEREST
- ACKNOWLEDGEMENTS
- REFERENCES
- Proton Conducting Ceramic Materials for Intermediate Temperature Solid Oxide Fuel Cells
- Narendar Nasani, Francisco Loureiro and Duncan Paul Fagg*
- INTRODUCTION
- Choice of Materials for PCFCs
- ELECTROLYTES
- Synthesis
- Sintering and Microstructure
- ANODES
- Cermet Compositions
- Synthesis, Phase Analysis and Microstructure
- CATHODES
- CONFLICT OF INTEREST
- ACKNOWLEDGEMENTS
- REFERENCES
- SUBJECT INDEX
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