
Plastics Technology
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ISNI: 0000 0003 8432 6149
Content
- Intro
- Preface
- The Author: Prof. Christian Bonten
- How to Use This Book
- Contents
- 1 Introduction
- 1.1 Plastics - Material of the Modern Age
- 1.2 Applications of Plastics
- 1.3 Plastics and Design
- 1.4 References
- 2 Fundamentals
- 2.1 From Monomer to Polymer - Basics of Polymer Chemistry
- 2.1.1 Origin of Monomers
- 2.1.2 Polymer Synthesis
- 2.1.2.1 Polymerization
- 2.1.2.2 Copolymerization (Special Form of Polymerization)
- 2.1.2.3 Polycondensation
- 2.1.2.4 Polyaddition
- 2.1.3 The Molar Mass of Polymers
- 2.1.4 Binding Forces and Brownian Molecular Movement
- 2.1.4.1 Intermolecular Physical Bonds
- 2.1.4.2 Brownian Molecular Motion - Mobility of Polymer Chains
- 2.1.5 Mechanisms of Solidification and Subdivision of Polymers
- 2.1.6 Primary Structure of Polymers: Constitution and Configuration
- 2.1.7 Secondary and Tertiary Structures of Polymers: Conformation
- 2.1.7.1 Amorphous Structures
- 2.1.7.2 Crystalline Structures
- 2.1.7.3 Influence of the Primary Structure
- 2.1.7.4 Superstructures
- 2.1.8 Polymers - Raw Materials Not Only for Plastics
- 2.2 Fundamentals of Force Transmission
- 2.2.1 Important Terms
- 2.2.1.1 Strength
- 2.2.1.2 Stiffness
- 2.2.1.3 Toughness
- 2.2.1.4 Stress-Strain Diagrams
- 2.2.2 State Ranges of Plastics
- 2.2.2.1 Glass Transition Temperature Tg
- 2.2.2.2 Crystalline Melting Temperature Tm
- 2.2.2.3 State Ranges of Crosslinked Polymers
- 2.2.3 Mechanical Replacement Models
- 2.3 Plastics and Plastics Technology - Definition of Terms
- 2.4 References
- 3 Plastics Materials Engineering
- 3.1 Behavior in the Melt - Flow Properties and Their Measurement
- 3.1.1 Fluid Mechanics Basics
- 3.1.2 Influences on the Flow Behavior
- 3.1.3 The Concept of Representative Viscosity
- 3.1.4 Elongation of Melt
- 3.1.5 Die Swell and Shrinkage
- 3.1.6 Rheometry - the Measurement of Flow Properties
- 3.1.6.1 Measurement of the Melt Flow Rate MFR
- 3.1.6.2 The High-Pressure Capillary Rheometer
- 3.1.6.3 Rotational Rheometer
- 3.1.6.4 Extensional Rheometer
- 3.2 Behavior as a Solid - Solid Properties and Their Measurement
- 3.2.1 Mechanical Properties of Plastics
- 3.2.1.1 The Tensile Test
- 3.2.1.2 The High Speed Tensile Test
- 3.2.1.3 Influence of Time and Temperature on the Mechanical Behavior
- 3.2.1.4 The Creep Test
- 3.2.1.5 The Vibration Test
- 3.2.1.6 The Bending Test
- 3.2.2 Physical Properties
- 3.2.2.1 Electrical Properties
- 3.2.2.2 Magnetic Properties
- 3.2.2.3 Optical Properties
- 3.2.2.4 Acoustic Properties
- 3.2.3 Values for Thermal and Mass Exchange
- 3.2.3.1 Specific Enthalpy h
- 3.2.3.2 Specific Heat Capacity cp
- 3.2.3.3 Density ?
- 3.2.3.4 Thermal Conductivity ?
- 3.2.3.5 Coefficient of Thermal Expansion a
- 3.2.3.6 Thermal Diffusivity a
- 3.2.3.7 Heat Penetration Coefficient b
- 3.2.3.8 Mass Transport
- 3.3 Influence of Additives on Properties
- 3.3.1 Reinforcing Materials - Active Additives
- 3.3.1.1 Fibers and the Principle of Reinforcement
- 3.3.1.2 The Tasks of the Matrix
- 3.3.1.3 Force Transmission of Fiber-Reinforced Plastic Composites
- 3.3.1.4 Defects in Fiber-Reinforced Plastic Composites
- 3.3.1.5 Nanoparticles as Active Additives
- 3.3.2 Functional Additives
- 3.3.2.1 Viscosity-Changing Additives - Flowing Agents
- 3.3.2.2 Plasticizers
- 3.3.2.3 Blending of Polymers
- 3.3.2.4 Impact Modifiers
- 3.3.2.5 Nucleating Agents
- 3.3.2.6 Coupling Agents
- 3.3.2.7 Conductive Additives
- 3.3.3 Fillers - Inactive Additives
- 3.4 From Polymer to Plastic - Introduction to Plastic Compounding
- 3.4.1 The Twin-Screw Extruder
- 3.4.2 Process Technology
- 3.4.3 Characteristic Values
- 3.4.4 Additional Units
- 3.5 Process, Structure, Properties - Influences due to the Converting Process
- 3.5.1 Residual Stresses
- 3.5.2 Orientation of Macromolecules
- 3.5.3 Orientation of Fibers
- 3.5.4 Crystallization
- 3.5.5 Formation of a Macrostructure: Foaming of Plastics
- 3.6 Changes over Time - Overview into the Aging of Plastics
- 3.6.1 Causes of Aging
- 3.6.2 Aging Processes
- 3.6.2.1 Mechanical Aging Mechanisms
- 3.6.2.2 Physical Aging Mechanisms
- 3.6.2.3 Chemical Aging Mechanisms
- 3.6.2.4 Mode of Action of Aging Stabilizers
- 3.6.3 Aging Phenomena
- 3.6.4 Characterization of the Aging Progress
- 3.7 Brief Description of Some Important Plastics
- 3.8 Polyethylene (PE)
- 3.9 Polypropylene (PP)
- 3.10 Ethylene-Propylene-(Diene) Copolymers (EPDM)
- 3.11 Polyvinyl Chloride (PVC)
- 3.12 Polystyrene (PS)
- 3.13 Styrene-Butadiene-Styrene Copolymers (SBS)
- 3.14 Styrene-Acrylonitrile Copolymers (SAN)
- 3.15 Acrylonitrile-Butadiene-Styrene Copolymers (ABS)
- 3.16 Acrylonitrile-Styrene-Acrylate Copolymers (ASA)
- 3.17 Polyamide (PA)
- 3.18 Polybutylene Terephthalate (PBT)
- 3.19 Polyethylene Terephthalate (PET)
- 3.20 Polycarbonate (PC)
- 3.21 Polymethyl Methacrylate (PMMA)
- 3.22 Polyoxymethylene (POM)
- 3.23 Polytetrafluoroethylene (PTFE)
- 3.24 Polyether Ether Ketone (PEEK)
- 3.25 Polyethersulfone (PES) und Polysulfone (PSU)
- 3.26 Polyphenylene Sulfide (PPS)
- 3.27 Cellulose Derivatives
- 3.28 Polyhydroxyalkanoates (PHA)
- 3.29 Polylactide (PLA)
- 3.30 Thermoplastic Polyurethane (TPE-U, also TPU)
- 3.31 Polyurethane (PUR)
- 3.32 Epoxy Resins (EP)
- 3.33 Melamine Formaldehyde Resin (MF)
- 3.34 Phenol-Formaldehyde or Phenol Resin (PF)
- 3.35 Urea-Formaldehyde Resin (UF)
- 3.36 Unsaturated Polyester Resin (UP)
- 3.37 References
- 4 Plastics Processing Technology
- 4.1 Extrusion
- 4.1.1 Extruder Screw and Barrel
- 4.1.2 The Helibar® High-Performance Extruder
- 4.1.3 Pipe and Profile Extrusion
- 4.1.4 Flat Film and Sheet Extrusion
- 4.1.5 Tube and Blown Film Extrusion
- 4.1.6 Extrusion Blow Molding
- 4.1.7 Co-extrusion
- 4.2 Injection Molding
- 4.2.1 The Injection Molding Process
- 4.2.2 The Plasticizing Unit
- 4.2.3 The Clamping Unit with Injection Mold
- 4.2.3.1 Rheological Design
- 4.2.3.2 Thermal Design
- 4.2.4 Influence of the Injection Molding Process on the Properties of the Component
- 4.2.5 Special Processes
- 4.2.5.1 Injection-Compression Molding
- 4.2.5.2 Thermoplastic Foam Injection Molding
- 4.2.5.3 Cascade Injection Molding
- 4.2.5.4 Injection Molding Compounding
- 4.2.5.5 Multi-component Processes
- 4.2.5.6 Sandwich Injection Molding
- 4.2.5.7 Fluid Injection Techniques
- 4.2.5.8 Back Injection Technology
- 4.2.5.9 Injection Stretch Blow Molding
- 4.2.5.10 Variothermal Mold Temperature Control
- 4.3 Processing of Crosslinking Plastics
- 4.3.1 Compression Molding
- 4.3.2 Transfer Molding
- 4.3.3 Injection Molding
- 4.3.4 Polyurethane Processing
- 4.4 Technology of Fiber-Reinforced Plastics
- 4.4.1 Hand Lay-up and Fiber Spraying
- 4.4.2 Pressing of SMC and GMT
- 4.4.3 Pultrusion of Continuous Fibers
- 4.4.4 Working with Prepregs
- 4.4.5 Resin Injection Molding
- 4.4.6 Three-Dimensional Fiber Reinforced Plastic Structures
- 4.5 Further Processing
- 4.5.1 Thermoforming
- 4.5.2 Mechanical Machining of Plastics
- 4.5.3 Welding
- 4.5.3.1 Hot Plate Welding
- 4.5.3.2 Hot Gas Welding
- 4.5.3.3 Extrusion Welding
- 4.5.3.4 Ultrasonic Welding
- 4.5.3.5 Vibration Friction Welding
- 4.5.3.6 Laser Welding
- 4.5.4 Adhesive Bonding
- 4.5.5 Joining by Snap Connections, Screws, and Rivets
- 4.5.6 Coating of Plastics
- 4.5.6.1 Coated Components
- 4.5.6.2 Coating Processes
- 4.6 References
- 5 Product Development with Plastics
- 5.1 Plastics as Construction Materials
- 5.1.1 Plastic-Specific Unique Selling Points
- 5.1.2 Material Preselection
- 5.2 Geometric Subdivision of Products
- 5.2.1 Large-Area Products
- 5.2.2 Housing-Like Products
- 5.2.3 Container-Like Products
- 5.2.4 Complex Products
- 5.2.5 Function-Specific Products
- 5.2.6 Importance for the Choice of the Processing Method
- 5.3 Designing with Plastics
- 5.3.1 Requirements for Products and Functions
- 5.3.2 Benefits of Design Freedom - Integration of Functional Elements
- 5.3.3 Use of Design Freedom - Increasing the Surface Moment of Inertia
- 5.3.4 Material-Specific Design
- 5.3.5 Production-Oriented Design
- 5.3.6 Stress-Oriented Design
- 5.3.6.1 Dimensioning against a Permissible Stress
- 5.3.6.2 Dimensioning against Critical Strain
- 5.3.6.3 Dimensioning against the Influence of Time - Service Life Prediction
- 5.3.7 Brief Summary of Designing with Plastics
- 5.4 Benefits of Prototypes in Product Development
- 5.4.1 Rapid Prototyping
- 5.4.1.1 Stereolithography (SLA)
- 5.4.1.2 Selective Laser Sintering (SLS)
- 5.4.1.3 Laminated Object Manufacturing (LOM)
- 5.4.1.4 3D Printing (3-D-P)
- 5.4.1.5 Fused Deposition Modeling (FDM or FFF)
- 5.4.2 Rapid Tooling
- 5.4.2.1 Casting
- 5.4.2.2 Laser Sintering
- 5.4.3 Selection of a Prototype Method
- 5.4.3.1 Requirements Placed on the Prototype
- 5.4.3.2 Prototypes for Large-Area Products and for Housing-Like Products
- 5.4.3.3 Prototypes for Container-Like Products
- 5.4.3.4 Prototypes for Complex Products
- 5.5 References
- 6 Plastics and the Environment
- 6.1 Plastic Waste
- 6.2 Are Plastics Toxic?
- 6.3 Biopolymers and Bioplastics
- 6.3.1 Biodegradable Plastics
- 6.3.2 Bio-based Plastics
- 6.3.3 From Biopolymer to Bioplastic - Compounding of Biopolymers
- 6.4 Conserving Resources with Plastics
- 6.4.1 Origin of the Term "Sustainability"
- 6.4.2 The Brundtland Report and the Kyoto Protocol
- 6.4.3 Conservation of Resources with Plastics
- 6.4.4 Regenerative Energy Generation with Plastics
- 6.5 Conclusion
- 6.6 References
- A - Recommendations for Writing a Bachelor's/Master's Thesis at the IKT
- A.1 Different Demands of Bachelor's, Master's, and Doctoral Theses
- A.2 Scientific Methods
- A.2.1 Source-Examining Methods
- A.2.2 Theoretical Methods
- A.2.3 Empirical Methods
- A.3 Scientific Work
- A.4 Bachelor's or Master's Thesis
- A.4.1 About the Title of the Thesis
- A.4.2 About the Content of the Thesis
- A.4.2.1 Summary
- A.4.2.2 Introduction
- A.4.2.3 Main Part
- A.4.2.4 Concluding Remarks
- A.4.2.5 Appendix
- A.4.3 About the Scope of the Thesis
- A.4.4 About the Writing Style of the Thesis
- Index
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