
Li-ion batteries
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Lithium Batteries Laboratory Manager at CEANgô Christian :
Christian Ngô a publié plus d'une douzaine d'ouvrages, seul ou en collaboration avec un autre auteur, sur plusieurs sujets allant de la physique de base (physique statistique, mécanique quantique, physique nucléaire, physique des semi-conducteurs) à des domaines plus appliqués comme l'énergie, les nanotechnologies, les déchets et la pollution, le soleil, etc. Il a fait de la recherche fondamentale pendant une vingtaine d'années avant de s'orienter vers la recherche appliquée où il a occupé plusieurs postes de responsabilité. Il dirige actuellement la société EDMONIUM.
Content
- Intro
- Li-ion Batteries
- Preface
- Contents
- Introduction
- Brief History of Primary and Secondary Batteries
- General Information on Li-ion Batteries
- Bibliography
- Positive Electrode Materials for "Lithium-ion" Accumulators
- Positive Electrode Materials of "Spinel" Structure
- Positive Electrode Materials with Lithiated Layered Oxide Structure
- Positive Electrode Materials with Olivine Structure
- References
- Negative Electrode Materials
- Negative Electrode Materials: Several Solutions
- Insertion-Intercalation
- Conversion
- Alloying
- Carbon
- Historical Background
- Interest
- Relationship between Structural Characteristics and Performance
- Silicon
- (De)lithiation Mechanisms
- Degradation Mechanisms
- Material Improvement Approaches
- Lithium Metal
- Bibliography
- Organic Electrode Materials
- Different Types of Organic Electrode Materials
- p-Extended System (Conducting Polymers)
- Polypyrrole Derivatives (PPy)
- Polythiophene Derivatives (PTh)
- Polyaniline Derivatives (PANI)
- Stable Radical
- Organosulfides & Thioethers
- Carbonyl Functions
- Aromatic Amines
- Implementation Strategies
- Grafting on Inorganic or Organic Support
- Functionalization of Neutral Polymers
- Functionalization of Conducting Polymers
- Stabilization by Physisorption
- Polyanionic Salt Formation
- References
- Electrolytes and Separators
- Liquid Electrolytes
- Lithium Salts and Organic Solvents
- Basic Properties and General Observation
- State of the Art, Its Limitations and Research to Overcome Them
- Lithium Salts and Ionic Liquids
- Separators
- Properties of Separators
- The Separator Market
- Cost and Security
- Bibliography
- Na-ion Batteries: Should/Can Lithium be Replaced?
- General Aspects
- Should Lithium be Replaced?
- Lithium Resources
- Lithium Cost
- Can Lithium be Replaced? Towards a 100% Abundant Element-Based Battery
- The Na-ion Technology
- Brief History
- Operating Principle
- State of the Art
- Negative Electrode Materials
- Graphite
- Hard Carbon
- Non-Carbon Materials
- Positive Electrode Materials
- Layered Oxides
- Polyanionic Materials
- Electrolytes and Interfaces
- Full System Performance
- Outlook
- Low Cost Approach
- High Power Approach
- References
- Metal-Sulfur Batteries
- The Metal-Sulfur Cell
- Advantages and Comparison with Other Technologies
- Working Mechanism of the Metal-Sulfur Cell
- The (Li,Na)-ion Sulfur Cell
- Technology State of the Art and Performances
- Main Actors
- Understanding the Complex Mechanism
- Development Strategies
- All-Solid-State Metal-Sulfur Batteries
- Industrial Actors
- Perspectives and Applications
- Bibliography
- All Solid-State Batteries
- Introduction and Overview
- Main Families of Solid Ionic Conductors
- Polymeric Solid Electrolytes
- Inorganic Solid Electrolytes
- Oxides
- Oxyhalides with Anti-Perovskite Structure
- Borohydrides - Boranes
- Sulfide Solid Electrolytes: Glasses and Ceramics
- Hybrid Solid Electrolytes
- Electrochemical Stability of Solid Electrolytes
- All-Solid-State Cells
- Academic & Industrial Players
- Bibliography
- Supercapacitors: From Material to Cell
- Operating Principle
- Carbon/Carbon Based Technology
- Electrode Design and Components
- Current Collector
- Activated Carbons for Supercapacitors
- Sec7
- Sec8
- Sec9
- Sec10
- Binders
- Sec12
- Sec13
- Conductive Additives
- Electrolyte
- Impact of Electrolyte on Performance
- Conductivity
- Ions and Concentration Limitations
- Solvents
- Electrochemical Stability and Ageing
- Electrochemical Stability of Ions and Solvents
- Electrolyte-Related Causes of Ageing
- Thermal Stability and Performance
- Toxicity
- Issue with the Substitution of Acetonitrile
- Solid State Electrolyte
- Electrolyte Organization in the Carbon Based Electrodes
- Separators
- Requirement Specifications of Separator
- Cellulose Based and Polymer Based Separators
- Hybrid Systems
- Activated Carbon/MnO2 System
- Lead Oxide/Activated Carbon System
- NiOOH/Activated Carbon System
- Graphite/Activated Carbon System
- Lithium-ion Capacitor Technology
- Sodium-ion Capacitor Technology
- Potassium-ion Capacitor Technology
- Bibliography
- Supercapacitors: Cells and Modules
- Cell Design
- Small Cells
- High-Capacity Cells
- High Power Cells
- Energy Type Cells
- "Pouch" Cell Design
- Cells Working in Aqueous Medium
- Present Performance of EDLC
- Design of Modules and Systems
- Modules Based on Hard Casing Cells
- Metallic Connections between Cells
- Module Terminals
- Insulators in Module
- Cell Balancing and Other Detected Information
- Module Casing
- High Capacity Modules Based on Soft Packaging Cells (Pouch Cells)
- High Capacity Modules Working in Aqueous Medium
- Bibliography
- Characterization of the Electrical Performance of Li-ion Cells
- Characterization of the Electrical Performance of Individual Cells
- Acceptance Tests
- Beginning of Life Performance Tests
- Capacity, Energy, Resistance and Power Measurements
- Faradic and Energy Efficiency
- Comparison of Beginning of Life (BoL) Performance of Li-ion Cells
- Ageing Performance Tests
- Ageing Conditions
- Ageing Follow-Up by Incremental Capacity Analysis (ICA) and Differential Voltage Analysis (DVA)
- Comparison of the Ageing Performance of various Li-ion Cells
- Resistance Measurements of Individual Cells
- Introduction
- How to Define an Internal Resistance?
- Different Methods of Measuring Internal Resistance
- Measurements from Polarization Curves
- Measurement with Open Circuit Voltage Variation
- Current Pulse Measurements
- Current Pulse Measurements and Extrapolation of Voltage Values
- Electrochemical Impedance Spectroscopic Measurements
- Calorimetric Measurements
- Conclusion
- Bibliography
- Microstructural and Physical and Chemical Characterizations of Battery Materials
- Introduction: Characterization Methodology to Understand the Electrochemical Response of a Battery
- Analysis of Mechanisms Associated with Exchangeable Lithium Loss
- SEI Formation and Li Metal Precipitation on Negative Electrode
- Loss of Lithium Content of Positive Electrode
- Analysis of Phase Transformations that Limit Lithium Mobility
- Microstructural Modification of a Positive Electrode
- Mechanical Blocking, Obstruction, Disconnection and Loss of Electrical Contact
- Loss of Graphite Electrode Capacity in Cycling at Low Temperatures
- Exogenous Deposits
- Electrolyte Degradation
- Perspectives
- Bibliography
- Cell and Electrode Manufacturing Process
- General Principles
- Cell Design
- Electrode Manufacturing Process
- Electrode Formulation
- Slurry Preparation
- Mixing Process
- Slurry Control
- Electrodes
- Calendering
- Cell Fabrication Process
- Slitting
- Cell Assembly
- Electrolyte Filling
- Electrical Formation
- Cells Bill of Materials and Cost Aspects
- New Processes/Perspectives
- Conclusion
- Bibliography
- Battery System and Battery Management System (BMS)
- Battery System Architecture
- Battery System in Its Electrical Environment
- Power Component Associated to Battery Pack
- Multiples Functions of BMS
- Design and Manufacture of Battery Packs
- Examples of Innovation on Battery Systems
- References
- Definition of the State Estimation Algorithms of a Battery System and Associated Calculation Methods
- Battery State Indicator Definition
- State of Charge
- State of Energy
- State of Health
- State of Function
- State of Safety
- Battery Diagnosis Methods
- State of Charge Estimation
- Coulomb Equation - Description of the Conventions
- Battery Cell Voltage Modelling
- Modelling and Bayesian Inference
- State-Space Observer
- Optimal Bayesian Filter
- Kalman Filter Design
- Kalman Filter Exploitation for State of Charge Estimation
- Improving the Estimation Performance: The Sigma Point Kalman Filter
- Sigma Point Kalman Filter Application to SOC Estimation
- Battery Total Capacity Estimation
- Framework
- Linear Regression
- Alternative Battery State Diagnosis Method
- Bibliography
- Standards and Safety
- Phenomena Involved in Abusive Conditions
- Phenomena at Cell Level
- Phenomena at Module and Pack Level
- Regulation
- Standards
- Tests and Additional Analysis
- Solutions to Improve Safety at Different Levels
- Improvement of the Components within the Cell
- Separator
- Negative Electrode
- Positive Electrode
- Electrolyte
- Fostering the Formation of the SEI
- Positive Electrode Protection Agents
- Salt Stabilizers
- Protection Agents
- Improving Lithium Deposition (Avoid Growth of Dendrites)
- Other Agents
- Safety Devices at Cell Level
- Positive Temperature Coefficient
- Current Interrupter Device
- Venting
- PCB ("Printed Circuit Board")
- Safety Devices at the Module and Battery System Level
- Electrical Devices
- Electronic Devices
- Chemical Devices
- Thermal Devices
- Mechanical Devices
- Conclusions and Prospects
- Bibliography
- Li-ion Battery Recycling
- Contextual Elements
- Process Head
- Process Core (Separation - Valorization)
- Pyrometallurgy
- Hydrometallurgy
- Leaching of Waste
- Treatment to Recover and Minimise Ultimate Wastes
- Conclusion
- References
- Li-ion Batteries Environmental Impacts and Life Cycle Assessment (LCA)
- Why a Focus on Battery Environmental Impacts?
- How to Quantify Batteries Environmental Impacts?
- What are the Main Impacts of Lithium-ion Batteries?
- What are the Impact Sources?
- Guidelines for Ecodesign
- Bibliography
- Applications and Markets - User Cost
- General Elements of Market Analysis - Focus on the Electrified Vehicle Market
- Issue of User Cost
- References
- Conclusion
- Glossary
- The Authors
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