
Fingerprint Development Techniques
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With contributions from leading experts in the field, Fingerprint Development Techniques offers a comprehensive review of the key techniques used in the development and imaging of fingerprints. It includes a review of the properties of fingerprints, the surfaces that fingerprints are deposited on, and the interactions that can occur between fingerprints, surfaces and environments. Comprehensive in scope, the text explores the history of each process, the theory behind the way fingerprints are either developed or imaged, and information about the role of each of the chemical constituents in recommended formulations.
The authors explain the methodology employed for carrying out comparisons of effectiveness of various development techniques that clearly demonstrate how to select the most effective approaches. The text also explores how techniques can be used in sequence and with techniques for recovering other forms of forensic evidence. In addition, the book offers a guide for the selection of fingerprint development techniques and includes information on the influence of surface contamination and exposure conditions.
This important resource:
* Provides clear methodologies for conducting comparisons of fingerprint development technique effectiveness
* Contains in-depth assessment of fingerprint constituents and how they are utilized by development and imaging processes
* Includes background information on fingerprint chemistry
* Offers a comprehensive history, the theory, and the applications for a broader range of processes, including the roles of each constituent in reagent formulations
Fingerprint Development Techniques offers a comprehensive guide to fingerprint development and imaging, building on much of the previously unpublished research of the Home Office Centre for Applied Science and Technology.
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Persons
Stephen M. Bleay, PhD, Senior Technical Specialist, Home Office Centre for Applied Science and Technology. Stephen has worked at the Home Office since 2003, his work focusing on processes for the visualisation and imaging of fingermarks. He is one of the principal authors of the Home Office Fingermark Visualisation Manual and has contributed to over 40 peer-reviewed articles on fingerprints and related forensic science subjects.
Ruth S. Croxton, PhD, Principal Lecturer, University of Lincoln. Ruth has worked at the University of Lincoln since 2002 and is programme leader for the BSc (Hons) Forensic Science degree. Her main research areas are latent fingermark composition and the development of new methods to study them, contributing to a number of peer-reviewed articles in this area.
Marcel de Puit, PhD, Senior Scientist, Netherlands Forensic Institute and Associate Professor, Delft University of Technology. Marcel started as a forensic scientist at the NFI in 2007. His main interest is the analysis of fingerprints with the purpose of providing information in other forensic disciplines. He has published over 20 scientific articles on fingerprints and related matter.
Content
Series Preface xi
Acknowledgements xiii
1 Introduction 1
Stephen M. Bleay and Marcel de Puit
References 10
2 Formation of fingermarks 11
Stephen M. Bleay and Marcel de Puit
2.1 Introduction 11
2.2 Initial contact 12
2.3 Interaction outcomes 13
2.4 The finger 17
2.5 The surface 24
2.6 Removal of the finger from the surface 30
2.7 Summary of the initial contact 32
References 33
3 Composition and properties of fingermarks 35
Ruth S. Croxton, Stephen M. Bleay and Marcel de Puit
3.1 Chemical composition of fingermarks 35
3.2 Biological properties of fingermarks 55
3.3 Physical properties of fingermarks 57
References 62
4 Ageing of fingermarks 69
Stephen M. Bleay and Marcel de Puit
4.1 The 'triangle of interaction' 69
4.2 The fingermark 70
4.3 The surface 70
4.4 The environment 78
4.5 Interactions 81
4.6 Time 94
References 96
5 Initial examination and the selection of fingermark enhancement processes 99
Stephen M. Bleay
5.1 Introduction 99
5.2 Processing options 100
5.3 Process selection 103
5.4 The processing environment 105
References 109
6 Optical detection and enhancement techniques 111
Stephen M. Bleay
6.1 Introduction 111
6.2 Current operational use 116
6.3 Visual examination 117
6.4 Fluorescence examination 125
6.5 Ultraviolet reflection 138
6.6 Infrared reflection 141
6.7 Colour filtration and monochromatic illumination 144
6.8 Multispectral imaging 149
References 151
Further reading 153
7 Vapour phase techniques 155
Stephen M. Bleay and Marcel de Puit
7.1 Introduction 155
7.2 Current operational use 156
7.3 Superglue/cyanoacrylate fuming 158
7.4 Vacuum metal deposition 172
7.5 Iodine fuming 181
7.6 Radioactive sulphur dioxide 185
7.7 Other fuming techniques 189
References 193
Further reading 196
8 Solid phase selective deposition techniques 199
Stephen M. Bleay
8.1 Introduction 199
8.2 Current operational use 200
8.3 Powders 201
8.4 ESDA 213
8.5 Nanoparticle powders 216
References 219
9 Amino acid reagents 221
Stephen M. Bleay
9.1 Introduction 221
9.2 Current operational use 223
9.3 Ninhydrin 224
9.4 1,8-Diazafluoren-9-one 231
9.5 1,2-Indandione 237
9.6 Ninhydrin analogues 242
9.7 Fluorescamine 246
9.8 o-Phthalaldehyde 250
9.9 Genipin 252
9.10 Lawsone 256
9.11 Alloxan 259
9.12 4-Chloro-7-nitrobenzofuran chloride 260
9.13 Dansyl chloride 262
9.14 Dimethylaminocinnemaldehyde and dimethylaminobenzaldehyde 263
References 268
Further reading 272
10 Reagents for other eccrine constituents 275
Stephen M. Bleay
10.1 Introduction 275
10.2 Current operational use 276
10.3 4-Dimethylaminocinnamaldehyde 277
10.4 Silver nitrate 279
References 281
Further reading 282
11 Lipid reagents 283
Stephen M. Bleay
11.1 Introduction 283
11.2 Current operational use 285
11.3 Solvent Black 3 (Sudan Black) 286
11.4 Basic Violet 3 (Gentian Violet, Crystal Violet) 290
11.5 Oil Red O (Solvent Red 27) 295
11.6 Iodine solution 297
11.7 Ruthenium tetroxide 299
11.8 Osmium tetroxide 301
11.9 Europium chelate 302
11.10 Natural Yellow 3 (curcumin) 305
11.11 Nile Red and Nile Blue A 308
11.12 Basic Violet 2 311
11.13 Rubeanic acid-copper acetate 313
11.14 Phosphomolybdic acid 315
References 317
Further reading 320
12 Liquid phase selective deposition techniques 321
Stephen M. Bleay
12.1 Introduction 321
12.2 Current operational use 323
12.3 Small particle reagent 326
12.4 Powder suspensions 330
12.5 Physical developer 336
12.6 Multi-metal deposition 345
References 352
Further reading 355
13 Enhancement processes for marks in blood 357
Stephen M. Bleay
13.1 Introduction 357
13.2 Current operational use 361
13.3 Protein stains 363
13.4 Peroxidase reagents 369
References 380
Further reading 381
14 Electrical and electrochemical processes 383
Stephen M. Bleay
14.1 Introduction 383
14.2 Current operational use 385
14.3 Etching 386
14.4 Corrosion visualisation 388
14.5 Electrodeposition 392
References 397
Further reading 399
15 Miscellaneous processes: lifting and specialist imaging 401
Stephen M. Bleay
15.1 Introduction 401
15.2 Current operational use 403
15.3 Lifting 404
15.4 Scanning electron microscopy 407
15.5 X-ray fluorescence (and X-ray imaging) 410
15.6 Secondary ion mass spectroscopy (SIMS) 413
15.7 Matrix-assisted laser desorption/ionisation mass spectrometry (MALDI-MS) 414
15.8 Attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) 415
References 417
Further reading 419
16 Evaluation and comparison of fingermark enhancement processes 421
Stephen M. Bleay
16.1 Introduction 421
16.2 Technology Readiness Level 3: Proof of concept 423
16.3 Technology Readiness Level 4: Process optimisation 425
16.4 Technology Readiness Level 5: Laboratory trials 427
16.5 Technology Readiness Level 6: Pseudo-operational trials 437
16.6 Technology Readiness Level 7: Operational trials 439
16.7 Technology Readiness Level 8: Standard operating procedures 439
16.8 Technology Readiness Level 9: Ongoing monitoring 440
References 440
17 Sequential processing and impact on other forensic evidence 443
Stephen M. Bleay and Marcel de Puit
17.1 Sequential processing of fingermarks 443
17.2 Test methodologies for developing processing sequences 449
17.3 Integrated sequential forensic processing 453
References 466
18 Interpreting the results of fingermark enhancement 469
Stephen M. Bleay
18.1 Introduction 469
18.2 Location of the mark 471
18.3 Type of substrate 473
18.4 Constituents of the mark 478
18.5 Enhancement process 480
18.6 The environment 482
18.7 Image processing 483
18.8 Image capture 484
References 487
Index 489
1
Introduction
Stephen M. Bleay1 and Marcel de Puit2
1 Home Office Centre for Applied Science and Technology, Sandridge, UK
2 Ministerie van Veiligheid en Justitie, Nederlands Forensisch Instituut, Digitale Technologie en Biometrie, The Hague, The Netherlands
Key points
- The traces left by contact between the hands and other surfaces are an essential tool in forensic investigations.
- Such traces can be used in several ways: to provide contextual information about the contact event and to identify individuals.
- All potential forensic applications of such contact traces rely on them being visualised by some means.
There are several books that deal with how latent fingermarks, and to some level the visualisation thereof, are used for identification purposes. To a great extent, the comparison and identification of latent fingermarks in criminal investigations remains their principal application.
In this book we will describe the chemistry (and other properties) of fingermarks in more depth and describe how fingermarks can be used for more than just identification purposes. We will describe how fingermarks may be deposited, the chemical and biological composition of the fingermark and its physical properties, the chemical and physical techniques used to visualise latent fingermarks and the importance of combining fingermark visualisation with recovery of other forensic evidence. Consideration is also given to the importance of communication between individuals visualising fingermarks and those responsible for their comparison and identification.
The traces that may be left by the contact between the palmar regions of hands and a surface are potentially the most informative forms of evidence available to the forensic scientist. The skin on the inside of the hands can flex and adapt to perform a wide range of manipulative tasks, and there are few actions (legal or illegal) that can be carried out without holding objects and/or touching surfaces. The nature of each of these contacts will be different, but in all cases Locard's exchange principle (Locard, 1934) applies, and there is the potential for the transfer of material between the hand and the surface.
In the context of crime investigation, there are many levels of information that can potentially be extracted from these areas of contact if it is possible for a forensic scientist to first locate and then enhance and analyse them.
At the coarsest level, the configuration of the palm and fingers during the contact with the surface and their position on it can provide useful contextual information about how the surface was touched or gripped. This can be particularly useful in corroborating or disproving particular accounts of events. Figure 1.1 illustrates a situation where the one individual claimed that an assailant had grasped his shirt, whilst the other individual claimed that he had merely pushed the wearer of the shirt away.
Figure 1.1 A contact (grab) mark on a black cotton shirt developed using vacuum metal deposition.
Reproduced courtesy of the Home Office.
The mark that has been revealed suggests that the fabric of the shirt has been gathered together by the hand, and therefore the account of the shirt being grasped by an assailant is more likely than a push with an open hand. Figure 1.2 shows two different orientations of fingermarks on a glass bottle.
Figure 1.2 The orientation of fingermarks on a glass bottle originating from different actions. (a) Bottle being held to drink from. (b) Fingermarks developed using aluminium powder after drinking. (c) Bottle being held as if to strike. (d) Fingermarks developed using aluminium powder after use as a weapon.
In the first case, the bottle has been held whilst drinking from the neck of the bottle. In the second case, the bottle has been gripped as if the bottle has been picked up for use as a weapon. Again, by examination of the configuration of the marks, it may be possible to infer how an item was handled, and this may become evidentially important.
Obviously, there are many more possible scenarios than the two examples presented here, and it should be noted that these are merely illustrative examples. In real casework the propositions (hypotheses) and subsequent examinations are likely to be more complex.
Revealing the distribution of a contaminant (an exogenous material) on the hand may also provide useful information that can be indicative of certain actions. In another example, the firing of a gun will result in the transfer of gunshot residue onto the hands (Figure 1.3). Although the hands can be swabbed to reveal the presence of gunshot residue, if its distribution across the hand can be shown, this may be far more useful in showing that it was much more likely that the gun was held and fired rather than the residue coming from accidental contact. This distribution of contaminant may also be subsequently reproduced in any marks left by the hand.
Figure 1.3 A white gelatin lift taken from the back of the hand taken after firing a gun and enhanced using a chemical selectively targeting traces of lead.
Reproduced courtesy of the Home Office.
At a slightly finer level, a closer analysis of the areas of palm and finger contact can also reveal information about the events during the time of contact. Although many of these events may consist of single, light contacts, others may be of longer duration and may include movement of the hand or multiple contacts, for example, as a grip on an object is readjusted. By analysis of the traces left by the contacts, it is possible to obtain information about factors including the pressure applied during contact, slippage of the hand across the surface and whether multiple contacts have occurred (Figures 1.4 and 1.5). All of this information can add context to the case being investigated.
Figure 1.4 A sequence of fingermarks developed using aluminium powder showing evidence of slippage on the surface.
Reproduced courtesy of the Home Office.
Figure 1.5 A sequence of fingermarks developed using aluminium powder showing evidence of multiple contacts on the surface.
Reproduced courtesy of the Home Office.
At a finer level of analysis is the examination of the ridge detail that may be reproduced within the fingers and palmar regions of the contact area. These are the features that have traditionally been the primary source of information for identification of individuals. The information available has been described in terms of 'levels' of detail (SWGFAST, 2013), although in practice all of these levels are utilised by identification specialists whilst drawing conclusions about the identity of the donor of a mark.
'Level 1 detail' describes the pattern formed by the flow of the ridges, and three general patterns are generally used to define marks, these being the whorl, loop and arch (Figure 1.6). Further detailed definitions of the general patterns and variations of them have been previously described in specialist texts on fingerprint comparison and identification; this information is however beyond the scope of this book.
Figure 1.6 Examples of the principal types of fingerprint pattern. (a) The whorl. (b) The loop. (c) The arch.
'Level 2 detail' describes the features that arise due to disruptions in the flow of the ridges, which include ridge endings and bifurcations where a single ridge forks into two. Other features can be described in terms of combinations of ridge endings and bifurcations (Figure 1.7). These features are sometimes also described as 'minutiae' or 'Galton details'. Level 2 details are those that are most used by identification specialists during comparison and that are automatically marked up by fingerprint database algorithms for automated searching of fingerprints.
Figure 1.7 An area of a fingerprint showing a number of second-level details.
'Level 3 detail' includes features associated with friction ridges that may also exist within a fingermark and can be used in conjunction with first- and second-level details to infer identity. These features may include pores, the shape of ridge edges and discontinuities within the ridge (Figure 1.8). Permanent scars and creases within the mark may also sometimes be included in this category. The use of fingermarks in identification has been extensively covered in other publications, and it is not the intention of this book to deal further with the comparison and identification process. However, the second-level and third-level details in fingerprints do play a crucial role in the chemistry and other properties of the fingermarks they produce. They are, respectively, responsible for the distribution and the excretion of sweat over and from the skin.
Figure 1.8 A fingermark enhanced using white powder suspension showing level 3 details (in this case pores, illustrated using circles) in the ridges.
Even in cases where the hands and palms are protected with gloves, it may still be possible to obtain useful evidence from the contact area. Not all gloves are totally impervious, and migration of sweat through certain types of glove has been recorded...
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