
Proton Transfer
Description
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Content
- Front Cover
- Comprehensive Chemical Kinetics, Volume 8
- Copyright Page
- Contents
- Preface
- Chapter 1. Homogeneous catalysis of organic reactions (mainly acid-base)
- 1. Introduction
- 2. Dependence of the rate of acid-base catalyzed reactions on pH and buffer concentration
- 3. Investigation of the mechanisms of acid-base catalyzed reactions
- 4. Energy barriers and isotope effects in proton transfer reactions
- 5. Survey of mechanisms of acid-base catalyzed reactions
- 6. Acid-base catalyzed formation and hydrolysis of epoxides
- 7. Acid catalyzed hydrolyses of acetals,ketals, and orthoesters
- 8. Acid catalyzed hydrolysis of aliphatic diazo compounds
- 9. Acid catalyzed aromatic decarboxylation
- 10. Nucleophilic catalysis
- 11. Catalysis of organic reactions by metal ions
- 12. Polyfunctional catalysis and intramolecular catalysis
- References
- Chapter 2. Proton transfer to and from carbon
- 1. Introduction
- 2. Experimental methods
- 3. Rates of proton transfer reactions
- 4. Rate-equilibrium correlations for classes of carbon acids
- 5. Discussion of results for proton transfer to and from carbon
- 6. Kinetic isotope effects in proton transfer to and from carbon
- References
- Chapter 3. Proton transfer to and from atoms other than carbon
- 1. General aspects of fast proton-transfer reactions
- 2. Carboxylic acids
- 3. Alcohols, phenols and indicator acids
- 4. Amines
- 5. Enols
- 6. Electronically excited acids and bases
- 7. Proton-transfer reactions in aprotic solvents
- References
- Index
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