
Non-Radical Polymerisation
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Content
- Front Cover
- Comprehensive Chemical Kinetics, Volume 15
- Copyright Page
- Contents
- Contributors to Volume 15
- Preface
- Chapter 1. Anionic polymerization of olefins
- 1. Introduction
- 2. Some general experimental considerations
- 3. Polymerization of styrene and dienes in hydrocarbon solvents
- 4. Polymerization of styrene and dienes in polar solvents
- 5. Polymerization of polar monomers
- 6. Stereospecificity in the propagation step
- 7. Copolymerization
- References
- Chapter 2. Kinetics of homogeneous cationic polymerization
- 1. Introduction
- 2. Complex nature of cationic systems
- 3. Methods of initiation
- 4. Kinetic schemes
- 5. Free ion-pair equilibria
- 6. Polymerization of vinyl monomers
- 7. Polymerization of cyclic monomers
- References
- Chapter 3. Kinetics of Polymerization initiated by Ziegler-Natta and related catalysts
- 1. Introduction
- 2. Catalyst structure
- 3. Initiation
- 4. Propagation and stereo regulation
- 5. Transfer
- 6. Termination
- 7. Kinetics
- 8. Individual monomers
- 9. Copolymerization
- 10. Equilibrium coordination polymerization
- Note added in proof
- References
- Chapter 4. Polymerization of cyclic ethers and sulphides
- 1. Introduction
- 2. Epoxides and episulphides
- 3. Oxetanes and thietanes
- 4. Tetrahydrofurans and tetrahydrothiophenes
- 5. Cyclic ethers and cyclic sulphides with more than five members in the ring
- 6. Cyclic formals, thials and oxathiolanes
- 7. Copolymers
- 8. Comparisons
- Note added in proof
- References
- Chapter 5. Kinetics of aldehyde polymerization
- 1. Introduction
- 2. Formaldehyde
- 3. Higher aliphatic aldehydes
- 4. Haloaldehydes
- References
- Chapter 6. Lactams
- 1. Introduction
- 2. Equilibria in lactam polymerization
- 3. Polymerizability of lactams
- 4. Anionic polymerization
- 5. Cationic polymerization
- 6. Hydrolytic polymerization
- 7. N-substituted lactams
- 8. Polymerization with isomerization
- References
- Chapter 7. The kinetics of polycondensation reactions
- 1. Introduction
- 2. Statistical treatment of polycondensation reactions
- 3. Physical classification of reaction systems
- 4. Chemical classification of reaction mechanisms
- 5. Polyesterification
- 6. Polyamidation and related polycondensations
- 7. Polyurethane formation
- 8. Polyurea and polyurea-urethane formation
- 9. Miscellaneous reactions
- References
- Chapter 8. The Polymerization of N-carboxy-a-amino acid anhydrides
- Introduction
- General principles
- 1. Addition reactions of amines
- 2. Polymerization involving ionization of the NCA
- 3. Experimental evidence relating to the polymerization of NCAs
- 4. Polymerization of NCAs unsubstituted at the 3-position initiated by primary and secondary amines
- 5. Polymerization of NCAs carrying a substituent at the 3-position
- 6. Special aspects of initiation
- 7. Effects of substituent groups
- 8. Stereoisomeric effects
- 9. The chain effect
- 10. Copolymerization
- 11. Further kinetic consideration
- References
- Index
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