Analytical Methods for Glycerol
Published on 10. July 2017
270 pages
978-1-4832-1617-1 (ISBN)
Description
Analytical Methods for Glycerol covers the detection, identification, determination, and separation of glycerol in analytical procedures. The book discusses the chemical and physical information about glycerol; analytical work on the important naturally occurring and synthetic materials containing combined glycerol; and the analysis of glycerol samples, especially from the point of view of pharmacopoiea specifications. The text also describes the important methods for the enzymic determination of glycerol. Methods based on residual glycerol hydroxyl groups, methods based on the release of glycerol from its combined state in the sample, and methods based on probable participation of the complete molecules of the sample are also considered. Chemists and people involved in the study of analytical methods of glycerol will find the book invaluable.
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M. R. F. Ashworth
Analytical Methods for Glycerol
Book
01/1979
Academic Press
€65.11
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Content
ContentsPreface 1. Glycerol 1 1.1 Oxidation Methods . 1.1.1 Bromine 1.1.2 Cerium(IV) 1.1.3 Chloramine T 1.1.4 Chromium(VI) 1.1.5 Copper(III) 1.1.6 Gold(III) 1.1.7 Hypohalite 1.1.8 Iodate 1.1.9 Iodine 1.1.10 Lead(IV) 1.1.11 Manganate 1.1.12 Mercury(II) 1.1.13 Oxygen 1.1.14 Periodate 1.1.15 Permanganate 1.1.16 Silver 1.1.17 Vanadate 1.2 Esterification Methods 1.2.1 Identification of Glycerol 1.2.2 Quantitative Determination 1.3 Ether Formation 1.3.1 Trimethylsilylation 1.3.2 Other Ether Formation Procedures 1.4 Dehydration and Detection Or Determination of the Acrolein Formed 1.4.1 Pungent Odour of Acrolein 1.4.2 Reaction of the C = C Group to Form Epihydrinaldehyde 1.4.3 Aldehyde Reducing Reactions 1.4.4 Reaction With Nitroprusside-Base 1.4.5 Condensation Reactions of the C = 0 Group 1.5 Reaction With Hydriodic Acid Yielding Isopropyl Iodide 1.6 Reaction With Inorganic Cations and Anions 1.6.1 With Copper(II) 1.6.2 With Other Cations 1.6.3 With Borate 1.6.4 With Other Anions 1.7 Purely Physical Methods 1.7.1 Refractive Index 1.7.2 Density, Surface Tension, and Critical Solution Temperature 1.7.3 Viscosity 1.7.4 Infrared Spectrophotometry 1.7.5 Nuclear Magnetic Resonance 1.8 Non-Chromatographic Separation Methods 1.8.1 Solvent Extraction 1.8.2 Distillation 1.9 Chromatographic Methods 1.9.1 Gas Chromatography 1.9.2 Paper Chromatography 1.9.3 Thin Layer Chromatography 1.9.4 Column and Liquid Chromatography 1.9.5 Paper Electrophoresis 1.9.6 Ion Exchange References2. Glycerol Compounds: Introduction, and Methods Based On Residual Hydroxyl Groups 2.1 Oxidation With Periodate 2.1.1 Use of Excess Reagent and Detection Or Determination of the Unused Reagent 2.1.2 Isomerisation of Glycerol 2-Monoesters 2.1.3 Detection and Determination of Aldehyde Reaction Products 2.2 Oxidation With Lead(IV) 2.3 Formation of Isopropylidene Derivatives 2.4 Complex Formation With Boron Compounds 2.5 Esterification 2.6 Ether Formation 2.6.1 Trimethylsilylation 2.6.2 Other Ether Formation Reactions 2.7 Infrared Spectrophotometry 2.8 Nuclear Magnetic Resonance 2.9 Other Oxidations 2.10 Thermogravimetry 2.11 Non-Chromatographic Separation Methods 2.11.1 Thermal Diffusion 2.11.2 Urea Complexes 2.11.3 Fractional Distillation and Extraction 2.12 Chromatography of Mixtures of Glycerol Mono-, Diand Tri-Esters Or -Ethers 2.12.1 Thin Layer Chromatography 2.12.2 Paper Chromatography 2.12.3 Column and Liquid Chromatography 2.12.4 Gas Chromatography References3. Glycerol Compounds: Methods Based On Release of Glycerol From The Sample 3.1 Hydrolysis 3.1.1 Oxidation with Periodate 3.1.2 Formation of Isopropylidene Groups 3.1.3 Other Oxidations 3.1.4 Dehydration 3.1.5 Esterification 3.1.6 Ether Formation 3.1.7 Reaction With Hydriodic Acid 3.1.8 Infrared Spectrophotometry 3.1.9 Chromatographic Methods 3.2 Aminolysis 3.3 Reduction 3.4 Thermal Cleavage References4. Glycerol Compounds: Methods Based On Probable Participation of the Complete Molecules of the Sample 4.1 Nephelometry 4.2 Critical Solution Temperature 4.3 Differential Thermal Analysis 4.4 Mass Spectrometry 4.5 Infrared Spectrophotometry 4.6 Solvent Extraction 4.7 Chromatography 4.7.1 Gas Chromatography 4.7.
