
Advances in Physical Organic Chemistry
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Content
- Front Cover
- Advances in Physical Organic Chemistry, Volume 13
- Copyright Page
- Contents
- Contributors to Volume 13
- Chapter 1. Calculation of Molecular Structure and Energy by Force-Field Methods
- 1. Introduction
- 2. Calculational Approaches to Molecular Structure
- 3. Summary of Studies Reported
- 4. Alkanes
- 5. Alkenes
- 6. Alkynes
- 7. Molecules containing Delocalized Electronic Systems
- 8. Other Hydrocarbons
- 9. Molecules containing Heteroatoms
- 10. Reaction Rates
- 11. Conclusions
- Chapter 2. Protonation and Solvation in Strong Aqueous Acids
- 1. Introduction
- 2. Standard Free Energies of Proton Transfer and Solvation in Aqueous Acid
- 3. Measured Heats of Ionization in Various Acidic Media
- 4. Heats of Solvation
- 5. Acidity Functions and Solvation
- 6. Summary
- Chapter 3. Formation, Properties and Reactions of Cation Radicals in Solution
- 1. Formation of Cation Radicals
- 2. Electrochemical Methods of Formation and Investigation of Cation Radicals
- 3. Physical Properties of Cation Radicals
- 4. Electron Transfer Reactions of Cation Radicals
- 5. Reactions of Cation Radicals with Nucleophiles
- 6. Cation-Radicals from Bypyridylium Salts
- 7. Concluding Remarks
- Chapter 4. 13C NMR Spectroscopy in Macromolecular Systems of Biochemical Interest
- 1. Introduction
- 2. Carbohydrates
- 3. Nucleic Acids and Constituents
- 4. Proteins and their Residues
- 5. Lipids
- 6. Macromolecular Model Systems
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