Advances in Inorganic Chemistry
Academic Press
Published on 3. February 1994
470 pages
978-0-08-057889-7 (ISBN)
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Advances in Inorganic Chemistry
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02/1994
Academic Press
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Content
- Front Cover
- Advances in Inorganic Chemistry, Volume 40
- Copyright Page
- CONTENTS
- Chapter 1. Bioinorganic Chemistry of Pterin-Containing Molybdenum and Tungsten Enzymes
- I. Scope and Overview
- II. The Molybdenum Cofactor (Mo-co)
- III. Coordination about the Molybdenum Atom
- IV. Synthetic Models of the Molybdenum Centers
- V. Reactions of Oxo-Molybdenum Centers
- VI. The Xanthine Oxidase Cycle
- VII. Intramolecular Electron Transfer in Molybdenum Enzymes
- VIII. Pterin-Containing Tungsten Enzymes
- IX. Future Directions
- X. Abbreviations
- References
- Note Added in Proof
- Chapter 2. Structure and Function of Nitrogenase
- I. Introduction
- II. Properties of the Nitrogenase Proteins
- III. Structural Description of the Nitrogenase Proteins
- IV. Structures of the Metal Centers of Nitrogenase
- V. Mechanistic Features
- VI. Future Outlook
- References
- Chapter 3. Blue Copper Oxidases
- I. Introduction
- II. Occurrence, Sequences, and Biological Function
- III. Molecular and Spectroscopic Properties
- IV. X-Ray Structure of Ascorbate Oxidase
- V. Structural Relationships among the Blue Copper Oxidases
- VI. Fungal Laccases, Ascorbate Oxidases, and Related Proteins
- VII. Evolution of the Blue Oxidases and Related Proteins from a Common Ancestor
- VIII. Oxidation-Reduction Potentials
- IX. Kinetic Properties of Laccase and Ascorbate Oxidase
- X. Functional Derivatives
- XI. The Catalytic Mechanism
- XII. Electron Transfer Processes
- XIII. Summary
- References
- Chapter 4. Quadruply Bridged Dinuclear Complexes of Platinum, Palladium, and Nickel
- I. Introduction
- II. Preparation and Steric Structures
- III. Spectroscopic Properties and Electronic Structures
- IV. Redox Properties
- V. Axial Ligand Substitution Properties
- VI. Concluding Remarks
- References
- Chapter 5. Octacyano and Oxo- and Nitridotetracyano Complexes of Second and Third Series Early Transition Metals
- I. Introduction
- II. Octacyano Complexes
- III. Tetracyano Complexes Containing Oxo or Nitrido Ligands
- References
- Chapter 6. Macrocyclic Complexes as Models for Nonporphine Metalloproteins
- I. Scope
- II. Introduction
- III. Mononuclear Systems
- IV. Dinuclear Sites
- V. Polynuclear Active Sites
- VI. Conclusion
- References
- Chapter 7. Complexes of Sterically Hindered Thiolate Ligands
- I. Aim and Scope
- II. Structures and Syntheses of Sterically Hindered Thiols
- III. Transition Metal Complexes
- IV. Main Group Complexes
- V. Conclusions
- References
- Appendix: Summary Table of Sterically Hindered Thiolate Complexes
- Index
- Contents of Previous Volumes
