Advances in Inorganic Chemistry
Academic Press
Published on 5. August 1992
486 pages
978-0-08-057887-3 (ISBN)
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Advances in Inorganic Chemistry
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A. Geoffrey Sykes | Richard Cammack
Advances in Inorganic Chemistry: Iron-sulfur Proteins v. 38
Book
06/1992
Academic Press
€99.04
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Content
- Front Cover
- Advances in Inorganic Chemistry, Volume 38
- Copyright Page
- Contents
- Helmut Beinert
- Chapter 1. Trinuclear Cuboidal and Heterometallic Cubane-Type Iron-Sulfur Clusters: New Structural and Reactivity Themes in Chemistry and Biology
- I. Introduction
- II. Homometallic Cubane-Type Clusters
- III. Trinuclear Cuboidal Clusters
- IV. Heterometallic MFe3S4 Cubane-Type Clusters
- References
- Chapter 2. Replacement of Sulfur by Selenium in Iron-Sulfur Proteins
- I. Introduction
- II. Selenium in Biology
- III. Preparation of Selenium-Substituted Iron-Sulfur Proteins
- IV. Mechanisms of Iron-Sulfur Cluster Assembly in Vitro and in Vivo
- V. Biochemical Properties of Iron-Selenium Proteins
- VI. Magnetic Properties of Iron-Selenium Clusters
- VII. Ground Spin State Variability in [4Fe-4S(e)]+ Clusters
- VIII. Vibrational Spectroscopy of Iron-Selenium Clusters
- IX. Prospects
- References
- Chapter 3. Dynamic Electrochemistry of Iron-Sulfur Proteins
- I. Introduction
- II. Background
- III. Applications
- IV. Conclusions
- References
- Chapter 4. EPR Spectroscopy of Iron-Sulfur Proteins
- I. Introduction
- II. Fundamentals of Iron-Sulfur EPR
- III. g Strain in Doublet Systems
- IV. High-Spin Kramer's Systems
- V. Non-Kramer's Systems
- VI. Epilogue
- References
- Chapter 5. Structural and Functional Diversity of Ferredoxins and Related Proteins
- I. Introduction
- II. [2Fe-2S] Ferredoxins and Related Proteins
- III. [4Fe-4S] and [3Fe-4S] Ferredoxins and Related Proteins
- IV. 2[4Fe-4S] or [4Fe-4S][3Fe-4S] Ferredoxins and Related Proteins
- V. Polyferredoxins
- VI. Conclusions
- References
- Chapter 6. Iron-Sulfur Clusters in Enzymes: Themes and Variations
- I. Introduction
- II. Methods of Identifying Iron-Sulfur Clusters in Proteins
- III. Classification of Iron-Sulfur Proteins.
- IV. Membrane-Bound Iron-Sulfur Enzymes of Bioenergetic Systems
- V. Soluble Proteins with Iron-Sulfur Clusters
- VI. Concluding Remarks
- References
- Chapter 7. Aconitase: An Iron-Sulfur Enzyme
- I. Introduction
- II. Properties of the Fe-S Cluster
- III. Interaction of Cluster and Substrate in the Enzymatic Reaction
- IV. Crystallographic Structure
- V. Studies on Mutants
- VI. Relationship of Cytoplasmic Aconitase to Iron-Responsive Element Binding Protein
- References
- Chapter 8. Novel Iron-Sulfur Centers in Metalloenzymes and Redox Proteins from Extremely Thermophilic Bacteria
- I. Introduction
- II. Extremely Thermophilic Bacteria
- III. Pyrococcus furiosus
- IV. Thermotoga maritima
- V. Summary
- References
- Chapter 9. Evolution of Hydrogenase Genes
- I. Introduction
- II. Hydrogenase Operons
- III. Evolution of Hydrogenase Genes: ''Redon Shuffling" and Hydrogenase Export
- IV. Functions of Hydrogenases
- V. Perspectives
- References
- Chapter 10. Density-Functional Theory of Spin Polarization and Spin Coupling in Iron-Sulfur Clusters
- I. Introduction
- II. Perturbation Formalism for Spin Coupling in Transition Metal Clusters
- III. The Density-Functional and Broken Symmetry Methods
- IV. Monomeric Iron-Sulfur Complexes
- V. Iron-Sulfur Dimers
- VI. Three-Iron Clusters
- VII. Four-Iron Clusters
- VIII. Conclusions and Prospects for Future Work
- References
- Index
- Contents of Recent Volumes
