Advances in Inorganic Chemistry
Academic Press
Published on 17. July 1989
371 pages
978-0-08-057882-8 (ISBN)
Description
Advances in Inorganic Chemistry
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A. Geoffrey Sykes
Advances in Inorganic Chemistry: v. 33
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05/1989
Academic Press
€112.66
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Content
- Front Cover
- Advances in Inorganic Chemistry, Volume 33
- Copyright Page
- Contents
- Chapter 1. 1,6-Disubstituted Triptycenes
- I. Introduction
- II. Synthesis
- III. Molecular Structure of Substituted Triptycenes
- IV. Mass Spectra
- V. Nuclear Magnetic Resonance Spectra
- VI. Ultraviolet and Infrared Spectra
- VII. Chemistry
- VIII. Conclusions and Suggestions for Further Work
- References
- Chapter 2. Cysteine-Containing Oligopeptide Model Complexes of Iron.Sulfur Proteins
- I. Introduction
- II. Significance of Peptide Ligands
- III. Chelating Effects of Peptide Ligands
- IV. Hydrophobic Effect of Peptide and Related Ligands
- V. Synthetic Mini-FeS Proteins
- VI. Summary
- References
- Chapter 3. Reduction Potentials Involving Inorganic Free Radicals in Aqueous Solution
- I. Introduction
- II. The Hydrated Electron
- III. Hydrogen
- IV. Oxygen
- V. The Halogens
- VI. The Heavier Chalcogens
- VII. Group V
- VIII. Group IV
- IX. Group III
- X. Group II
- XI. The Alkali Metals
- XII. The Rare Gases
- XIII. Appendix
- References
- Note Added in Proof
- Chapter 4. The Nitrogen Fluorides and Some Related Compounds
- I. Introduction
- II. Nitrogen Trifluoride, NF3
- III. The Tetrafluoroammonium Ion, NF4+
- IV. Use of KrF+ and PtF6 as Oxidative Fluorinating Reagents
- V. Metathetical Reactions
- VI. Properties of Tetrafluoroammonium Salts
- VII. Trifluoroamine Oxide, NF3O
- VIII. Salts of Cations of the Type (NFxH4-x)+
- IX. Difluoroamine, HNF2
- X. Chlorodifluoroamine, CINF2
- XI. Other Mixed Halogen Compounds
- XII. Difluorodiazene, N2F2
- XIII. Fluorine Azide (Triazadienyl Fluoride), N3F
- XIV. Tetrafluorohydrazine, N2F4
- XV. Salts of the N2F3+ Cation
- XVI. Organic Reactions of N2F4
- XVII. Reactions of the Difluoroamino Radical with Other Radicals
- References
- Chapter 5. Higher Oxidation State Manganese Biomolecules
- I. Introduction
- II. Superoxide Dismutase
- III. Acid Phosphatase
- IV. Transferrin
- V. Catalase
- VI. Photosystem II
- VII. Concluding Remarks
- References
- Chapter 6. Double Bonds between Phosphorus and Carbon
- I. Introduction and History
- II. Formation of the PC Double Bond
- III. Structure of and Proofs for Genuine .p Bonds
- IV. Reactivity
- V. Compounds with Several PC or Partially CC Double Bonds
- VI. Cumulated Bond Systems with Participation of the PC Double Bond
- VII. Coordination Chemistry of Phosphaalkenes
- VIII. Concluding Remarks
- IX. Compilation of Acyclic Phosphaalkenes
- References
- Index
- Contents of Recent Volumes
