Advances in Inorganic Chemistry
Academic Press
Published on 1. June 1988
405 pages
978-0-08-057881-1 (ISBN)
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Advances in Inorganic Chemistry
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A. Geoffrey Sykes
Advances in Inorganic Chemistry: v. 32
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05/1988
Academic Press
€117.61
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Content
- Front Cover
- Advances in Inorganic Chemistry, Volume 32
- Copyright Page
- Contents
- Preface
- Chapter 1. Dynamics of Spin Equilibria in Metal Complexes
- I. Introduction
- II. Static Properties
- IV. Solution Dynamics
- V. Solid-State Dynamics
- VI. Summary and Interpretation
- VII. Implications
- References
- Chapter 2. Hydroxo-Bridged Complexes of Chromium(lll), Cobalt(llI), Rhodium(lll), and Iridium(lll)
- I. Introduction
- II. Structural Considerations
- III. Spectroscopic and Magnetic Properties
- IV. Formation of Polynuclear Complexes
- V. Stability Constants
- VI. Acid-Base Equilibria
- VII. Kinetics for the Condensation Reaction of Mononuclear Species to Give Dinuclear Species
- VIII. Cleavage of Polynuclear into Mononuclear Species
- IX. Equilibria between Mono- and Dihydroxo-Bridged Dinuclear Complexes of Chromium(III), Rhodium(III), and Iridium(III)
- X. Kinetics of the Hydrolysis of Dihydroxo-Bridged Cobalt(III) Complexes
- XI. Equilibria between Tri- and Dihydroxo-Bridged Complexes
- XII. Bridge Cleavage of Mixed Bridge Complexes
- XIII. Concluding Remarks
- XIV. Abbreviations for Ligands and Solvents
- References
- Chapter 3. Catenated Nitrogen Ligands Part II . Transition Metal Derivatives of Triazoles, Tetrazoles, Pentazoles, and Hexazine
- I. Introduction
- II. Triazole and Triazolate Complexes
- III. Tetrazole and Tetrazolate Complexes
- IV. Pentazolate and Hexazine Complexes
- References
- Chapter 4. The Redox Chemistry of Nickel
- I. Introduction
- II. Steric and Electronic Requirements
- III. Probes of Structure
- IV. Oxidation of Nickel(II)
- V. Reduction of Nickel(II)
- VI. List of Abbreviations
- References
- Chapter 5. Nickel in Metalloproteins
- I. Introduction
- II. Urease
- Ill. Hydrogenase
- IV. Methyl-Coenzyme M Reductase
- V. Carbon Monoxide Oxidoreductase
- VI. Concluding Remarks
- VII. Abbreviations
- References
- Chapter 6. Nitrosyl Complexes of Iron-Sulfur Clusters
- I. Introduction
- II. Synthesis
- III. Molecular Structure: X-Ray Crystallography
- IV. Molecular Structure: NMR Spectroscopy
- V. Electronic Structure
- VI. Chemical Reactivity
- VII. Biological Chemistry
- References
- Index
- Contents of Recent Volume
