Advances in Inorganic Chemistry and Radiochemistry
Academic Press
Published on 1. January 1963
428 pages
978-0-08-057854-5 (ISBN)
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Advances in Inorganic Chemistry and Radiochemistry
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H.J. Emeleus | Alan G. Sharpe
Advances in Inorganic Chemistry and Radiochemistry: v. 5
Book
12/1963
Academic Press
€90.37
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Content
- Front Cover
- Advances in Inorganic Chemistry and Radiochemistry, Volume 5
- Copyright Page
- Contents
- List of Contributors
- Chapter 1. The Stabilization of Oxidation States of the Transition Metals
- I. Introduction and Scope
- II. The Effect of Environment upon the Stability of the Oxidation State of the Metal
- III. Survey of Oxidation States of Various Electron Configurations
- IV.Summary
- References
- Chapter 2. Oxides and Oxyfluorides of the Halogens
- I. Oxygen-Fluorine Compounds
- II. Oxy-Compounds of Chlorine
- III. Oxy-Compounds of Bromine
- IV. Oxy-Compounds of Iodine
- References
- Chapter 3. The Chemistry of Gallium
- I. Introduction
- II. Lower Valencies (Oxidation States I and II)
- III. Binary Compounds of Gallium (III) with Group V Elements
- IV. Binary and Ternary Oxides and Hydroxides
- V. Compounds with Sulfur, Selenium. arid Tellurium
- VI. Gallium Trihalides and Their Adducts
- VII. Other Salts and Complexes of Gallium (III)
- VIII. Gallium Hydrides and Organogallium Compounds
- References
- Chapter 4. Chemical Effects of Nuclear Activation in Gases and liquids
- I. Introduction
- II. Primary Processes Leading to Bond Rupture
- III. Formation of Chemical Bonds by Atoms Activated by Nuclear Formation .
- Acknowledgment
- List of Symbols
- References
- Chapter 5. Gaseous Hydroxides
- I. Introduction
- II. Systems of the Type Hydroxide(s, l) = Hydroxide(g)
- III. Systems of the Type Oxide(s, I) + H2O(g) = = Hydroxide(g)
- Acknowledgment
- References
- Chapter 6. The Borazines
- I. Introduction
- II. Synthesis of the Borazine Ring
- III. Reactions of the Borazine Ring
- IV. Commercial Use of Borazines
- V. Physical Properties of Borazines
- VI. Conclusion
- Acknowledgment
- References
- Chapter 7. Decaborane-14 and Its Derivatives
- I. Introduction
- II. The Preparation and Structure of Decaborane-14
- III. Proton Abstraction from Decaborane-14
- IV. Electrophilic Substitution of Hydrogen in Decaborane-14
- V. Electron Transfer to Decaborane-14
- VI. Substituted Tetradecahydrodecaborate Ions. B10H12X2 Compounds
- VII. Enneaborane-15 Derivatives from Substituted B10H14 2- Ions
- VIII. The BIoH& Ion and Its Reactions
- IX. The Icosahedral B12H12 2- Ion
- X. Decaborane-16
- XI. Conclusion
- Notes Added in Proof
- References
- Chapter 8. The Structure and Reactivity of Organophosphorus Compounds
- I. Introduction
- II. The Electronic Structure of PX5
- III. Configuration of the Transition State
- IV. Reactions of Phosphonium Compounds
- V. Stereochemical Change on Phosphorylation
- VI. The Symmetry of dp-pp, Bonds
- VII. Experimental Evidence for drp, Bonding
- VIII. Phosphorylation
- IX. The Influence of the Nucleophile on Phosphorylation
- X. Substituent Effects in Bimoleciilar Phosphorylntion
- XI. Ionization Reactions
- References
- Author Index
- Subject Index
