Advances in Inorganic Chemistry and Radiochemistry
Academic Press
Published on 1. January 1961
462 pages
978-0-08-057852-1 (ISBN)
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Advances in Inorganic Chemistry and Radiochemistry
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H.J. Emeleus | Alan G. Sharpe
Advances in Inorganic Chemistry and Radiochemistry: v. 3
Book
10/1961
Academic Press
€90.37
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Content
- Front Cover
- Advances in Inorganic Chemistry and Radiochemistry, Volume 3
- Copyright Page
- Contents
- List of Contributos
- Chapter 1. Mechanisms of Substitution Reactions of Metal Complexes
- I. Introduction
- II. Octahedral Complexes
- III. Square Complexes
- IV. Tetrahedral Complexes
- V. Fast Reactions
- VI. Metal Carbonyls
- VII. Photochemistry of Metal Complexes
- References
- Chapter 2. Molecular Complexes of Halogens
- I. Introduction
- II. Physicochemical Methods for Detection and Investigation of Complexes in Solution
- III. Complex Stabilities and the Thermodynamics of Complex Formation
- IV. The Nature of the Interactions of the Complex Components
- References
- Chapter 3. Structures of Interhalogen Compounds and Polyhalides
- I. Introduction
- II. Survey of the Structures and Properties of Polyhalogen Complexes
- III. Theoretical Interpretations of the Structures of Polyhalogen Complexes
- References
- Chapter 4. Kinetic Behavior of the Radiolysis Products of Water
- I. Introduction
- II. Rates of Reactions of the OH Radical
- III. Rates of Reactions of H Atoms
- IV. Heterogeneous Kinetics in Radiation Chemistry
- References
- Chapter 5. Silanes and Their Derivatives
- I. Introduction
- II. Relationship between the Chemistry of Analogous Carbon and Silicon Compounds
- III. The Parent Silanes
- IV. Silane Derivatives Containing Silicon-Carbon Linkages
- V. Silane Derivatives Containing Silicon-Halogen Linkages
- VI. Addition Compounds of Silicon Halides with Amines, Phosphines, or Arsines
- VII. Silane Derivatives Containing Silicon-Pseudohalogen Linkages
- VIII. Silane Derivatives Containing Silicon Linked to Oxygen, Sulfur, or Selenium
- IX. Silane Derivatives Containing Silicon Linked to Nitrogen, Phosphorus, or Arsenic
- X. Silyl-Metallic Compounds
- Notes Added in Proof
- References
- Chapter 6. The General, Selective, and Specific Formation of Complexes by Metallic Cations
- I. Introduction
- II. Stability Constants
- III. Enthalpy and Free Energy
- IV. Precipitation Reactions
- V. Ligands and Ligand Atoms
- VI. A- and B-Metal Cations
- VII. Electrovalent and Nonelectrovalent Interaction
- VIII. Transition Metal Cations
- IX. General and Selective Complex Formation
- X. Structural Principles of Polydentate Chelating Agents
- XI. Selectivity and Specificity
- References
- Chapter 7. Atmospheric Activities and Dating Procedures
- I. Radioactive Components of the Atmosphere
- II. Radioactive Species of Terrestrial Origin
- III. Activities Generated by the Cosmic Radiation
- IV. Radiocarbon
- V. Tritium
- VI. Artificial Activities
- References
- Chapter 8. Polyfluoroalkyl Derivatives of Metalloids and Nonmetals
- I. Introduction
- II. Mercury
- III. Boron
- IV. Silicon
- V. Nitrogen
- VI. Phosphorus, Arsenic, and Antimony
- VII. Oxygen
- VIII. Sulfur and Selenium
- References
- Author Index
- Subject Index
