
Advances in Catalysis
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Content
- Cover
- Copyright
- Contents
- Contributors
- Preface
- Mikhail I. Temkin, 1908-1991
- Chapter 1. Application of Percolation Theory to Describing Kinetic Processes in Porous Solids
- I. Introduction
- II. Elements of Percolation Theory
- III. Desorption from Porous Solids
- IV. Mercury Penetration into Porous Solids
- V. Catalytic Deactivation by Site Coverage and Pore Blockage
- VI. Conclusion
- References
- Chapter 2. Oscillatory Reactions in Heterogeneous Catalysis
- I. Introduction
- II. A Survey of Oscillatory Reactions
- III. Experimental Methods
- IV. Models of Oscillatory Behavior
- V. Synchronization, Spatial Patterns, and Chaos
- VI. Summary
- References
- Chapter 3. Zeolite-Supported Transition Metal Catalysts
- I. Introduction
- II. Preparation of Metal Zeolites
- III. Carbon Monoxide-Induced Reorganizations of Metal Atoms
- IV. Alloy Particles
- V. Metal Redispersion
- VI. Metal Particles from Neutral Complexes
- VII. Formation of Metal Clusters by the Ship-in-a-Bottle Method
- VIII. Metal-Proton Adducts
- IX. Catalytic Reactions
- X. Prospectives for Future Applications
- References
- Chapter 4. Selectivity Control and Catalyst Design in the Fischer-Tropsch Synthesis: Sites, Pellets, and Reactors
- I. Introduction
- II. Background
- III. Experimental Methods
- IV. Results and Discussion
- V. Design of Fischer-Tropsch Catalysts
- VI. Conclusions
- VII. Nomenclature
- References
- Chapter 5. Catalysis by Metal Ions Intercalated in Layer Lattice Silicates
- I. Introduction
- II. Catalytic Materials
- III. Catalytic Activity of Metal Ion-Exchanged Fluorotetrasilicic Mica
- IV. Dehydrogenation of Methanol over Copper Ion-Exchanged TSM
- V. Reaction of Methanol over Ti4+-TSM and Related Catalysts
- VI. Immobilization of Catalyst Solution
- VII. Conclusions
- References
- Chapter 6. Catalytic Synthesis of Chlorofluorocarbon Alternatives
- I. Introduction
- II. Catalytic Synthesis of Key CFC Alternatives
- III. Summary
- References
- Chapter 7. Molecular Mobility Measurement of Hydrocarbons in Zeolites by NMR Techniques
- I. Introduction
- II. Basic Principles of NMR Self-Diffusion Studies
- III. Principles of NMR Techniques to Detect Molecular Reorientations
- IV. Principles of Other Mobility Measurements (Comparison with NMR Data)
- V. Combined Application of Different Experimental Techniques to Study Molecular Translations and Rotations of Hydrocarbons in Zeolites
- VI. Structure-Related Molecular Self-Diffusion in Zeolites by Pulsed-Field Gradient NMR: Influence of Pore Diameter, Si/AI Ratio, and Concentrations of Internal OH Groups and Cations
- Self-Diffusion of Mixtures
- VII. Location of Diffusion Obstacles Inside the ZSM-5 Framework by Pulsed-Field Gradient NMR
- VIII. Detection of Spatial Distributions of Diffusion Obstacles over the Crystal Size by Pulsed-Field Gradient NMR
- IX. Self-Diffusion in ZSM-5 Particles of Different Crystal Morphology
- X. Conclusions
- References
- Index
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