Advances in Catalysis
Academic Press
Published on 18. September 1992
411 pages
978-0-08-056542-2 (ISBN)
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Advances in Catalysis
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Herman Pines | Paul B. Weisz | Daniel Douglas Eley
Advances in Catalysis: v. 38
Book
08/1992
Academic Press
€120.28
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Content
- Front Cover
- Advances in Catalysis, Volume 38
- Copyright Page
- Contents
- Contributors
- Preface
- Chapter 1. Behavior and Characterization of Kinetically Involved Chemisorbed Intermediates in Electrocatalysis of Gas Evolution Reactions
- I. Scope of Review
- II. Relation of Electrocatalysis to Catalysis
- III. Conditions for Electron Charge Transfer with Adsorption of an Intermediate
- IV. Characterization of Kinetically Involved Adsorbed Intermediates in Regular Heterogeneous Catalysis
- V. Chemical Identity of Adsorbed Intermediates in Electrocatalysis
- VI. Involvement of Chemisorbed Intermediates in Electrode Reactions, and Methods of Analysis
- VII. Tafel Slope Factor in Electrocatalysis and Its Relation to Chemisorption of Intermediates
- VIII. Relations between Tafel and Potential-Decay Slopes
- IX. Tafel Slopes and Potential Dependence of Coverage by Intermediates
- X. Reaction Order in Relation to Reaction Mechanisms and Adsorption of Reactants and Intermediates
- XI. Real-Area Factor in Electrocatalysis
- XII. Electrocatalysis in Cathodic Hydrogen Evolution and Nature of Electrode Metal
- XIII. In Situ Activation of Cathodes for Hydrogen Evolution by Electrodeposition
- XIV. Electrocatalysis at Glassy Metals
- XV. Determination of Coverage by Adsorbed H in Hydrogen Evolution Reaction at Transition Metals
- XVI. Metal Film Electrocatalytic Effects in Photoelectrolysis Processes
- XVII. Electrocatalysis and Kinetic Behavior of Oxygen Evolution Reaction
- XVIII. Electrode Kinetic Behavior of Chlorine Evolution Reaction, and Role and Identity of Adsorbed Intermediates
- XIX. Electronic and Structural Features of Oxide Electrocatalysts for Chlorine and Oxygen Evolution
- References
- Chapter 2. Applications of Adsorption Microcalorimetry to the Study of Heterogeneous Catalysis
- I. Introduction
- II. Theoretical Background
- III. Calorimetric Principles
- IV. Study of the Acid-Base Properties of Oxide Surfaces
- V. Acid-Base Properties of Zeolites
- VI. Acid-Base Properties of Amorphous Metal Oxides
- VII. Acid-Base Discussion
- VIII. Properties of Metals and Supported Metals
- IX. Catalytic Applications
- X. Conclusions
- References
- Chapter 3. Organic Syntheses Using Aluminosilicates
- I. Introduction
- II. Organic Reactions on Zeolites
- III. Reactions on Clay
- IV. Epilog
- References
- Chapter 4. Metal Cluster Compounds as Molecular Precursors for Tailored Metal Catalysts
- I. Introduction
- II. Characterization of Clusters on Surfaces
- III. Structure and Reactivity of Clusters on Surfaces
- IV. Cluster-Derived Homometal Catalysts
- V. Cluster-Derived Bimetallic Catalysts
- VI. Clusters in Zeolites
- VII. Clusters on Other Supports
- VIII. Summary and Prospects
- References
- Index
