
Advances in Catalysis
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Content
- Front Cover
- Advances in Catalysis, Volume 33
- Copyright Page
- Contents
- Contributors
- Paul Hugh Emmett, 1900-1985
- Chapter 1. Homogeneous Nickel-Catalyzed Olefin Hydrocyanation
- I. Introduction and Scope
- II. Equilibria Involving Ni(0) Complexes
- III. Dienes and HCN
- IV. Olefin Isomerization
- V. Monoolefins and HCN
- References
- Chapter 2. Supported Chromium Catalysts for Ethylene Polymerization
- Introduction
- I. Hexavalent Cr/Silica
- II. Reduced Cr/Silica
- III. Polymerization over Cr/Silica
- IV. The Porosity of the Support
- V. Modifications of Cr/Silica
- VI. Chromium Oxide on Other Support
- VII. Organochromium Catalysis
- References
- Chapter 3. Catalysis Controlled by the Constitution of Active Sites
- I. Introduction
- II. Isomerization Reaction
- III. Hydrogen Exchange Reaction
- IV. Hydrogenation Reaction
- V. Conclusion
- References
- Chapter 4. Selective Oxidative Dehydrogenation of Butenes on Ferrite Catalysts
- I. Introduction
- II. Selective Oxidation and Combustion Sites
- III. Densities of Oxidation Sites
- IV. Role of Adsorbed Oxygen
- V. Role of Lattice Oxygen
- VI. Kinetics and Mechanism
- VII. Factors Affecting Selectivity: Roles of Crystal Structure, Nature of Transition Metal Ions, and Effect of Promoters
- VIII. Effect of Crystallite Size
- IX. Other Structure-Sensitive Oxidation Reactions
- X. Catalytic Activity of Iron Hydroxide
- XI. Conclusions
- References
- Chapter 5. The Study of Aluminosilicate and Related Catalysts by High- Resolution Solid-state NMR Spectroscopy
- I. Introduction
- II. Relevant Spectroscopic Considerations
- III. Solide-State NMR Studies of Zeolites
- IV. Silica-Alumina Gels
- V. Derivatized Surfaces and "Immobilized" Homogeneous Catalysts
- VI. Probing Supported Metal Catalysts by NMR without Utilizing High-Resolution Techniques
- VII. Bond Lengths, Structure, and Mechanism in Heterogeneous Catalysis and in Chemisorbed States
- VIII. Sheet Silicates and Their Pillared Variants
- IX. Recent Trends in the Study of Catalytic Solids by NMR
- References
- Author Index
- Subject Index
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