Advances in Catalysis
Academic Press
Published on 1. December 1983
506 pages
978-0-08-056536-1 (ISBN)
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Advances in Catalysis
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Herman Pines | Paul B. Weisz | Daniel Douglas Eley
Advances in Catalysis: v. 32
Book
12/1983
Academic Press
€169.27
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Content
- Cover
- Copyright
- Contents
- Contributors
- Preface
- Chapter 1. Characterization and Reactivity of Molecular Oxygen Species on Oxide Surfaces
- I. Introduction
- II. Neutral Oxygen Species
- III. Characterization of Charged Dioxygen Species
- IV. Formation and Stability of Charged Diatomic Species.
- V. Oxygen Ions Containing More Than Two Nuclei
- VI. Reactivity of Molecular Ions
- VII. The Relation of Mononuclear Surface Oxygen Species to Electron Spectroscopic and Catalysis Studies
- VIII. Comparison of Oxygen Species and Their Role in Catralytic Reactions
- Appendix A. Summary of gzz Values for O2- on Surfaces
- Appendix B. The Experimental 17O Hyperfine Parameters (in gauss) of Diatomic Oxygen Species (O2- and ROO)
- Appendix C. Characterization of Oxygen Species by Infrared Spectroscopy References
- References
- Note Added in Proof
- Chapter 2. Catalysis by Alloys in Hydrocarbon Reactions
- I. Introduction
- II. Alloys
- III. Particle Size Effects.
- IV. Mechanism of Hydrocarbon-Hydrogen Reactions
- V. Hydrocarbon Reactions on Alloys
- VI. Conclusions
- References
- Chapter 3. Modified Raney Nickel (MRNi) Catalyst: Heterogeneous Enantio-Differentiating (Asymmetric) Catalyst
- I. What Is MRNi?
- II. History of Discovery and Development of MRNi
- III. Profile of MRNi in Hydrogenation
- IV. Profile of MRNi in Stereo-Differentation
- V. Other Profiles
- VI. Surface Conditions
- VII. Mechanism of Enantio-Differentiation
- VIII. Characterization of Catalyst by Modifying Techinque
- IX. TA-NaBr-MRNi
- X. Other Investigations
- References
- Chapter 4. Analysis of the Possible Mechanisms for a Catalytic Reaction System
- I. Introduction
- II. The Structure of a Chemical System
- III. General Formulas for Mechanisms and Reactions
- IV. A Procedure for Finding Every Direct Mechanism
- V. Systems with a Simple Overall Reaction
- VI. Overall Reactions with a Multiplicity Greater Than One
- VII. Discussion
- List of Symbols
- References
- Chapter 5. Homogeneous Catalytic Hydrogenation of Carbon Monoxide: Ethylene Glycol and Ethanol from Synthesis Gas
- I. Introduction
- II. Cobalt Catalysts
- III. Rhodium Catalysts
- IV. Unpromoted and Carboxylic Acid-Promoted Ruthenium Catalysts
- V. Lewis Base-Promoted Ruthenium Catalysts
- VI. Other Catalysts
- VII. Conclusions
- References
- Chapter 6. Cyclodextrins and Cyclophanes as Enzyme Models
- I. Introduction
- II. Basic Principles of Molecular Recognition
- III. Enhancement of Binding and Catalysis by Host Design
- IV. Enhancement of Binding and Catalysis by Guest Design
- V. Conclusion
- References and Notes
- Author Index
- Subject Index
- Contents of Previous Volumes
