
Advances in Catalysis
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Content
- Front Cover
- Advances in Catalysis, Volume 26
- Copyright Page
- Contents
- Contributors
- Preface
- Sir. Eric. K. Rideal (1890-1974)
- Michael Polanyi (1891-1976)
- Chapter 1. Active Sites in Heterogeneous Catalysis
- I. Introduction
- II. The Atomic Structure of Surfaces. Structures of Low and High Miller Index Crystal Surfaces
- III. Techniques to Study the Relationship between Reactivity and the Structure and Composition of Surfaces in the Atomic Scale
- IV. Chemisorption of Hydrocarbons on Low and High Miller Index Surfaces of Platinum, Iridium, and Gold
- V. Chemical Reactions on Platinum Crystal Surfaces
- VI. Active Sites for C-H, H-H, and C-C Bond Breaking on Platinum Crystal Surfaces
- VII. The Role the Carbonaceous Overlayer in Hydrocarbon Reactions on Platinum Surfaces
- VIII. The Mechanism of the Dehydrogenation of Cyclohexane and Cyclohexene : Expanded Classification of Reactions According to Their Structure Sensitivity
- IX. A Descriptive Model of Hydrocarbon Catalysis on Platinum Surfaces
- X. Theory of Low Coordination Number Active Sites on Surfaces
- XI. Aspects of Enzyme Catalysis on Metal Surfaces
- XII. Possible Correlations between Homogeneous and Heterogeneous Catalysis
- References
- Chapter 2. Surface Composition and Selectivity of Alloy Catalysts
- I. Introduction
- II. Surface Composition of Equilibrated Alloys
- III. Selectivity of Alloys in Hydrocarbon Reactions
- IV. Ensemble and Ligand Etrects
- V. Conclusions
- References
- Chapter 3. Mossbauer Spectroscopy Applications to Heterogeneous Catalysis
- I. Introduction
- II. Experimental
- III. Applications to Heterogeneous Catalysis
- IV. Concluding Remark
- Appendix I: Nuclear Data for Mossbauer Isotopes
- Appendix II: Mossbauer Isotope Feasibility for Catalyst Studies
- References
- Chapter 4. Compensation Effect in Heterogeneous Catalysis
- I. Introduction
- II. Compensation Behavor
- III. Compensation Behavior in Reported Kinetic Data
- IV. Conclusions
- Appendix I : Compensation Behaviour Resulting from Temperature-Dependent Variations in Concentrations of Surface Reactants
- Appendix II : Statistical Formulas Used in Linear Regression (Least Squares) Analyses
- List of Symbols
- References
- Chapter 5. Transition Metal-Catalyzed Reactions of Organic Halides with CO, Olefins, and Acetylenes
- I. Introduction
- II. Carbonylation Reactions
- III. Olefinic Substitution Reactions
- IV. Substitution Reactions of Terminal Acetylenes
- V. Conclusions
- References
- Chapter 6. Manual of Symbols and Terminology for Physicochemical Quantities and Units-Appendix II Part II : Heterogeneous Catalysis
- Preface
- Section 1 . Definitions and Terminology
- 1.1 Catalysis and Catalysts
- 1.2 Adsorption
- 1.3 Composition, Structure and Texture of Catalysts
- 1.4 Catalytic Reactors
- 1.5 Kinetics of Heterogeneous Catalytic Reactions
- I.6 Transport Phenomena in Heterogeneous Catalysis
- 1.7 Loss of Catalytic Activity
- 1.8 Mechanism of Catalytic Reactions
- 1.9 Nomenclature of Catalytic Reactions
- Section 2. List of Symbols and Abbreviations
- Section 3. Alphabetical Index
- Author Index
- Subject Index
- Contents of Previous Volumes
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