
Advances in Catalysis
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Content
- Front Cover
- Advances in Catalysis, Volume 25
- Copyright Page
- Contents
- Contributors
- Preface
- Chapter 1. Application of Molecular Orbital Theory to Catalysis
- I. Introduction
- II. Calculational Procedures
- III. Metal Clusters
- IV. Chemisorption
- V. Conclusions
- References
- Chapter 2. The Stereochemistry of Hydrogenation of a,ß-Unsaturated Ketones
- I. Introduction
- II. Mechanistic Proposals
- III. Effect of Variables on the Hydrogenation of ß-Octalone and Related Compounds
- IV. Hydrogenation of Other Ring Systems
- V. Conclusions
- References
- Chapter 3. Asymmetric Homogeneous Hydrogenation
- I. Introduction
- II. Homogeneous Rhodium-Chiral Phosphine Catalyst Systems
- III. Chiral Amide-Rhodium Complexes as Catalysts
- IV. Chiral Cobalt Catalysts
- V. Chiral Ruthenium Catalysts
- VI. Concluding Remarks
- Note Added in Proof
- References
- Chapter 4. Stereochemical Approaches to Mechanisms of Hydrocarbon Reactions on Metal Catalysts
- I. Introduction
- II. The Horiuti-Polanyi Mechanism
- III. Reactions of Olefins
- IV. Skeletal Rearrangement of Alkanes in Platinum and Other Noble Metals
- V. Recent Experimental Approaches to Skeletal Rearrangements
- VI. Influence of Carbonaceous Deposits
- VII. Conclusions
- References
- Chapter 5. Specific Poisoning and Characterization of Catalytically Active Oxide Surfaces
- I. Introduction
- II. General Scope and Definitions
- III. Experimental Methods
- IV. Interaction of Specific Poisons with Oxide Surfaces
- V. Specific Poisoning on Alumina Surfaces
- VI. Conclusions
- References
- Chapter 6. Metal-Catalyzed Oxidations of Organic Compounds in the Liquid Phase: A Mechanistic Approach
- I. Introduction
- II. Homolytic Mechanisms
- III. Heterolytic Mechanisms
- IV. Heterogeneous Catalysis of Liquid Phase Oxidations
- V. Biochemical Oxidations
- VI. Summary-Directions for Future Development
- References
- Author Index
- Subject Index
- Contents of Previous Volumes
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