Advances in Catalysis
Academic Press
Published on 25. April 1975
420 pages
978-0-08-056528-6 (ISBN)
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Advances in Catalysis
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Advances in Catalysis and Related Subjects: v. 24
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02/1975
Academic Press
€89.28
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Content
- Cover
- Copyright
- Contents
- Contributors
- Preface" Catalysis and Relevance
- Sir Hugh S. Taylor (1890-1974)
- Chapter 1. Kinetics of Coupled Heterogeneous Catalytic Reactions
- I. Introduction
- II. Principles of Some Methods of Kinetic Analysis
- III. Specific Features of the Kinetics of Coupled Heterogeneous Catalytic Reactions
- IV. Experimental Kinetic Studies of Some Systems of Coupled Reactions
- List of Symbols
- References
- Chapter 2. Catalysis for Motor Vehicle Emissions
- I. Introduction
- II. Properties of Automotive Exhaust Gases
- III. Catalysts and Reactors
- IV. Kinetics and Mechanisms
- V. Physical Transport Processes
- VI. Durability of Catalytic Converters
- VII. Reactor Engineering
- VIII. Future Prospects
- List of Symbols
- References
- Chapter 3. The Metathesis of Unsaturated Hydrocarbons Catalyzed by Transition Metal Compounds
- I. Introduction
- II. Reactants and Catalyst Systems
- III. Mechanism
- IV. Thermodynamics and Kinetics
- References
- Chapter 4. One-Component Catalysts for Polymerization of Olefins
- I. Introduction
- II. Chromium Oxide Catalysts
- III. Catalysts Based on the Use of Organometallic Compounds of Transition Metals
- IV. Subhalides of Transition Metals
- V. Determination of the Number of Propagation Centers
- VI. Some General Features of Propagation Center in One-Component Polymerization Catalysts
- VII. Conclusion
- References
- Chapter 5. The Economics of Catalytic Processes
- I. Introduction
- II. Two Classes of Useful Chemical Transformations
- III. The Network of Technological Factors and Constraints Affecting Catalyst Choice
- IV. The Economic Factors and Constraints Affecting Catalyst Choice
- V. Factors Involved in Economic Improvement to Typical Processes and Guidelines for Assessment
- References
- Chapter 6. Catalytic Reactivity of Hydrogen on Palladium and Nickel Hydride Phases
- I. Introduction
- II. Formation, Structure, and Properties of Palladium and Nickel Hydrides
- III. Catalytic Activity of Hydride Phases of Palladium and Its Alloys with Gold or Silver
- IV. The Effect of Transformation into Hydride on the Catalytic Activity of Nickel and Its Alloys with Copper
- V. Catalytic Activity of Other Metal Hydrides in Test Reaction of Hydrogen
- VI. General Remarks and Conclusions
- References
- Chapter 7. Laser Raman Spectroscopy and Its Application to the Study of Adsorbed Species
- I. Introduction
- II. The Origin of the Raman Effect
- III. Instrumentation
- IV. Recording Spectra of Adsorption Systems
- V. Raman Spectra of Adsorbed Molecules
- VI. Conclusion
- Appendix : Normal Coordinates, Vibrational Wavefunctions, and Spectral Activities
- References
- Chapter 8. Analysis of Thermal Desorption Data for Adsorption Studies
- I. Introduction
- II. Fundamental Definitions and Relationships
- III. Temperature Schedules in Thermal Desorption
- IV. Fundamental Relationships for the Determination of the Activation Energy of Desorption, of the Order of Desorption and of the Preexponential Factor
- V. Processing of the Experimental Data to Estimate the Kinetic Parameters of Desorption
- VI. Effects of the Surface Heterogeneity and of the Surface Coverage
- VII. Conclusion
- List of Symbols
- References
- Author Index
- Subject Index
- Contents of Previous Volumes
