Advances in Catalysis
Academic Press
Published on 27. February 1971
401 pages
978-0-08-056525-5 (ISBN)
Description
Advances in Catalysis
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Advances in Catalysis and Related Subjects: v. 21
Book
01/1970
Academic Press
€85.56
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Content
- Front Cover
- Advances in Catalysis and Related Subjects, Volume 21
- Copyright Page
- Contents
- Contributors
- Preface
- Chapter 1. Kinetics of Adsorption and Desorption and the Elovich Equation
- I. Deviations from Equation (1) at Small t
- II. Discontinuities in the Elovich Plot
- III. Effect of Pressure on the Magnitudes of a and b
- IV. Effect of Temperature on a and b Values
- V. Theoretical Interpretations of the Elovich Equation
- VI. Models Based on Site Number Variation
- VII. Models Based on a Variable Activation Energy
- VIII. Nonuniform Surface
- IX. General Solution for Any Distribution Function
- X. Integration of Equation (II)
- XI. Evaluation of E0
- XII. Physical Concept of Site Heterogeneity
- XIII. Uniform Surface-Induced Heterogeneity
- XIV. Kinetic Order of Desorption Process
- XV. Variation of Site Number and of Activation Energy
- XVI. Derivation of Equation for Combined Site and Induced Heterogeneity
- XVII. Effect of Distribution of Heats of Adsorption on the Rates of Adsorption and Desorption
- XVIII. Variation of Parameter b for Readsorption on a Partially Regenerated Surface
- XIX. Effect of Variation of Adsorption Heat for Both Site and Induced Heterogeneity
- XX. Adsorption Rates on Partially Regenerated Surfaces Displaying Both Site and Induced Heterogeneity
- XXI. Application to Published Results
- XXII. Kinetics of Adsorption from a Binary Gas Mixture
- XXIII. General
- References
- Chapter 2. Carbon Monoxide Adsorption on the Transition Metals
- I. Introduction
- II. The Bonding in Carbon Monoxide Adsorption
- III. The Carbon Monoxide on Tungsten Adsorption System
- IV. Adsorption on Molybdenum and Chromium
- V. Adsorption on the Group VIII Transition Metals
- VI. Carbon Monoxide Adsorption on the Remaining Transition Metals
- VII. The Group Ib Metals
- VIII. Conclusions
- References
- Chapter 3. Discovery of Surface Phases by Low Energy Electron Diffraction (LEED)
- I. Introduction
- II. LEED as a Diffraction Tool
- III. Electron Diffraction at Low Energies
- IV. LEED Patterns from Adsorbed Layers
- V. Relocation of Substrate Atoms
- VI. Adsorption Experiments
- VII. Catalysis
- References
- Chapter 4. Sorption, Diffusion, and Catalytic Reaction in Zeolites
- I. Introduction
- II. Sorption Equilibrium
- III. Rates of Sorption, Diffusion, and Desorption
- IV. Rates of Catalytic Reactions
- References
- Chapter 5. Adsorbed Atomic Species as Intermediates in Heterogeneous Catalysis
- I. Introduction
- II. The Thermodynamic Activity of an Atomic Species on the Surface of a Catalyst and Its Determination under Steady-State Conditions of a Catalytic Reaction
- III. The Concept of the Rate-Determining Step
- IV. The Analysis of Empirical Rate Laws
- V. Oxygen Transfer Reactions
- VI. Sulfur Transfer Reactions
- VII. Nitrogen Transfer Reactions
- VIII. Hydrogen Transfer Reactions
- IX. The Electrical Charge of Adsorbed Atomic Species
- X. Concluding Remarks
- References
- Author Index
- Subject Index
