
Advances in Catalysis
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Content
- Front Cover
- Advances in Catalysis, Volume 17
- Copyright Page
- Contents
- Contributors
- Preface
- Contents of Previous Volumes
- Chapter 1. On the Theory of Heterogeneous Catalysis
- I. Introduction
- II. Elementary Reaction Rate
- III. Theory of Steady Reaction
- IV. Application to the Analysis of Steady Reaction
- V. Application to the Temperature Dependence of Steady Reaction Rate
- References
- Chapter 2. Linear Correlations of Substrate Reactivity in Heterogeneous Catalytic Reactions
- I. Introduction
- II. General Features of Linear Free-Energy Relationships
- III. Limitations Introduced by Solid Catalysts
- IV. Linear Correlations of Published Data
- V. Discussion
- List of Symbols
- References
- Chapter 3. Application of a Temperature-Programmed Desorption Technique to Catalyst Studies
- I. Introduction
- II. Experimental Arrangement
- III. Active Sites for Olefin Chemisorption
- IV. Heats of Desorption and Surface Heterogeneity
- V. Study of Surface Reactions
- VI. Conclusions
- References
- Chapter 4. Catalytic Oxidation of Olefins
- I. Introduction
- II. Ethylene Oxide
- III. Dienes and Aldehydes
- IV. Acids
- V. Oxidation to COa
- VI. Terminology
- References
- Chpter 5. The Physical-Chemical Properties of Chromia-Alumina Catalysts
- I. Introduction
- II. Background
- III. Surface Chemistry of Chromia-Alumina Catalysts
- IV. X-Ray Diffraction Studies of Chromia-Alumina Catalysts
- V. Magnetochemistry of Chromia-Alumina Catalysts
- VI. Electron Spin Resonance of Chromia-Alumina Catalysts
- VII. Nuclear Magnetic Resonance of Chromia-Alumina Catalysts
- VIII. Optical Reflectance Spectroscopy of Chromia-Alumina Catalysts
- IX. Electrical Properties of Chromia-Alumina Catalysts
- X. Over-all Structure of Chromia-Alumina Catalysts
- References
- Chapter 6. Catalytic Activity and Acidic Property of Solid Metal Sulfates
- I. Introduction
- II. Acidic Property of Metal Sulfates
- III. Structure of Acid Centers
- IV. Reactions Catalyzed by Metal Sulfates
- V. Catalytic Activity and Acidic Property
- VI. Conclusions
- References
- Chapter 7. Electrocatalysis
- I. Introduction
- II. Electrocatalysis?a Special Case of Heterogeneous Catalysis
- III. Determinations of Mechanisms of Electrocatalytic Reactions
- IV. Some Examples of Mechanism Determination
- V. Phenomenology of Electrocatalysis
- VI. Comparison of Rates of Reactions Carried Out Chemically and Electrochemically
- VII. Special Features of Electrocatalysis
- References
- Author Index, Volume 17
- Subject Index, Volume 17
- Cumulative Author Index, Volumes 1-16
- Cumulative Subject Index, Volumes 1-16
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