Advances in Catalysis
Academic Press
Published on 1. January 1966
288 pages
978-0-08-056520-0 (ISBN)
Description
Advances in Catalysis
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W.G. Frankenberg | etc.
Advances in Catalysis and Related Subjects: v. 16
Book
04/1966
Academic Press
€89.28
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Content
- Cover
- Copyright
- Contributors
- Machines and Systems: A Preface
- Contents
- Chapter 1. The Homogeneous Catalytic Isomerization of Olefins by Transition Metal Complexes
- I. Introduction
- II. The Carbon-Metal Sigma Bond
- III. The Carbon-Metal Pi Bond
- IV. Stability of the Carbon-Metal Bond
- V. The Carbon-Metal Delocalized Pi Bond
- VI. Double-Bond Isomerization in Olefins
- VII. Summary
- References
- Chapter 2. The Mechanism of Dehydration of Alcohols over Alumina Catalysts
- I. Introduction
- II. Purpose
- III. Early Mechanisms and Observations
- IV. Nature of Alumina Catalysts
- V. Isomerization Following Dehydration
- VI. Steric Course of Dehydration
- VII. Dehydration of Aliphatic Alcohols
- VIII. Dehydration of Secondary and Tertiary Alcohols
- IX. Conclusions
- References
- Chapter 3. p Complex Adsorption in Hydrogen Exchange on Group Vlll Transition Metal Catalysts
- I. Introduction
- II. p Complex Adsorption
- III. Associative and Dissociative p Complex Substitution Mechanisms
- IV. Experimental Evidence for p Complex Adsorption and Reaction Mechanisms
- V. Conclusion
- References
- Chapter 4. Stereochemistry and the Mechanism of Hydrogenation of Unsaturated Hydrocarbons
- I. Introduction
- II. The Development of Some Stereochemical Concepts
- III. Variations in Stereochemistry as a Criterion of Mechanism
- IV. Conformational Analysis and the Geometry of the Pertinent Transition States in the Hydrogenation of Cycloalkenes
- V. The Reaction of Aromatic Hydrocarbons with Hydrogen
- VI. Hydrogenation of Multiply Unsaturated Hydrocarbons
- VII. Some General Mechanistic Considerations
- References
- Chapter 5. Chemical Identification of Surface Groups
- I. Introduction
- II. Surface Groups on Carbon
- III. Surface Groups on Silica
- IV. Surface Groups on Titanium Dioxide
- V. Surface Groups on Alumina
- VI. Surface Groups on Silica-Alumina
- VII. Conclusion
- References
- Author Index
- Subject Index
