Advances in Catalysis
Academic Press
Published on 12. September 2001
476 pages
978-0-08-052439-9 (ISBN)
Description
Since 1948, Advances in Catalysis has filled the gap between the papers that report on and the textbooks that teach in the diverse areas of catalysis research. The editors of and contributors to Advances in Catalysis are dedicated to recording progress in this area.Advances in Catalysis, Volume 46 builds foundations of fundamental understanding at the atomic and molecular scales in support of technologically important catalytic processes. The first tow chapters forge links between molecular (homogeneous) catalysis and catalysis occurring analogously-and sometimes more successfully-on surfaces. The following three chapters are concerned with advances in classical surface catlysis building on concepts of reaction kinetics and surface characterization.
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Content
- Front Cover
- ADVANCES IN CATALYSIS
- Copyright Page
- Contents
- Contributors
- Preface
- Chapter 1. Immobilization of Homogeneous Oxidation Catalysts
- I. Introduction
- II. Titanium
- III. Vanadium
- IV. Chromium
- V. Manganese
- VI. Iron
- VII. Cobalt
- VIII. Copper
- IX. Metal-Assisted Oxidations with Sacrificial Use of an Aldehyde
- X. Zirconium
- XI. Molybdenum
- XII. Ruthenium
- XIII. Palladium
- XIV. Cerium
- XV. Tungsten
- XVI. Rhenium
- XVII. Osmium
- XVIII. Metal-Free Oxidation Catalysts
- XIX. Conclusions
- References
- Chapter 2. Olefin Polymerization Catalyzed by Metallocenes
- I. Introduction
- II. New Cocatalysts
- III. Metallocene-Catalyzed Ethylene Polymerization
- IV. Metallocene-Catalyzed Polymerization of a-Olefins
- V. Mechanism of Stereospeci.city
- VI. Anchoring of Metallocene Catalysts to Supports
- VII. Metallocenes for Polymerization of Particular Monomers
- VIII. Conclusions
- Appendix
- References
- Chapter 3. Kinetics of Heterogeneous Catalytic Reactions: Analysis of Reaction Schemes
- I. Introduction
- II. Formulation of the Kinetic Model
- III. Significance of Kinetic Parameters
- IV. Case Studies
- V. Conclusions
- References
- Chapter 4. Surface Structures of Oxides and Halides and Their Relationships to Catalytic Properties
- I. Introduction
- II. The Simplest Classes of Oxides and Chlorides: Structure and Bonding
- III. Surface Characterization of Oxides and Halides
- IV. Oxides and Halides with the Rock Salt Structure: Surface Structure, Reactivity, and Catalytic Activity
- V. Oxides and Halides with the Wurtzite Structure: Surface Structures, Reactivity, and Catalytic Activity
- VI. Lanthanum Oxide
- VII. Cupric Oxide
- VIII. Oxides with the Corundum Structure
- IX. Spinels
- X. Perovskites
- XI. Oxides with AB2 Structure (TiO2 and ZrO2): Surface Structure, Reactivity, and Catalytic Activity
- XII. Transition Metal Ions Supported on Amorphous Silica: Crx+/SiO2
- XIII. Electric Field and Acidity at Cationic Sites
- XIV. Conclusions
- References
- Chapter 5. Catalytic Hydrodenitrogenation
- I. Introduction
- II. HDN on Sulfidic Catalysts
- III. HDN on Metals, Metal Carbides, and Metal Nitrides
- IV. Conclusions
- References
- Index
