Vapour-Liquid Equilibrium Data of Binary Polymer Solutions
Vapour Pressures, Henry-Constants and Segment-Molar Excess Gibbs Free Energies
Christian Wohlfarth(Author)
Elsevier (Publisher)
Published on 26. August 1994
Book
Hardback
884 pages
978-0-444-81717-4 (ISBN)
Description
Knowledge of vapour-liquid equilibrium (VLE) data is necessary for the proper understanding of a large number of industrial and laboratory processes. Such data allow a grasp of the thermodynamic behaviour of mixtures, the study of intermolecular interactions and enable insight into the molecular nature of mixtures. They are also a basis for the development of theoretical thermodynamic models. Scientists and engineers can benefit from a collection of the existing data This book aims to provide a reliable collection of such data. Original data have been gathered from around 450 literature sources, including 80 journals and a number of dissertations and diploma papers. Previously unpublished data from the Thermodynamic Department of the former Merseburg-University and the author's own data sets are included. The VLE-data are divided into three chapters: vapour pressures of binary polymer solutions (or solvent activities); segment-molar excess Gibbs free energies of binary polymer solutions (in the form of Redlich-Kister parameters); and weight fraction Henry-constants for gases and vapours in molten polymers (from inverse gas-liquid chromatography measurements).
A short introduction to the experimental methods and data reduction is included as Chapter 1. There are indices for the polymers and solvents cited.
Knowledge of vapour-liquid equilibrium (VLE) data is necessary for the proper understanding of a large number of industrial and laboratory processes. Such data allow a grasp of the thermodynamic behaviour of mixtures, the study of intermolecular interactions and enable insight into the molecular nature of mixtures. They are also a basis for the development of theoretical thermodynamic models. Scientists and engineers can benefit from a collection of the existing data This book aims to provide a reliable collection of such data. Original data have been gathered from around 450 literature sources, including 80 journals and a number of dissertations and diploma papers. Previously unpublished data from the Thermodynamic Department of the former Merseburg-University and the author's own data sets are included. The VLE-data are divided into three chapters: vapour pressures of binary polymer solutions (or solvent activities); segment-molar excess Gibbs free energies of binary polymer solutions (in the form of Redlich-Kister parameters); and weight fraction Henry-constants for gases and vapours in molten polymers (from inverse gas-liquid chromatography measurements).
A short introduction to the experimental methods and data reduction is included as Chapter 1. There are indices for the polymers and solvents cited.
A short introduction to the experimental methods and data reduction is included as Chapter 1. There are indices for the polymers and solvents cited.
Knowledge of vapour-liquid equilibrium (VLE) data is necessary for the proper understanding of a large number of industrial and laboratory processes. Such data allow a grasp of the thermodynamic behaviour of mixtures, the study of intermolecular interactions and enable insight into the molecular nature of mixtures. They are also a basis for the development of theoretical thermodynamic models. Scientists and engineers can benefit from a collection of the existing data This book aims to provide a reliable collection of such data. Original data have been gathered from around 450 literature sources, including 80 journals and a number of dissertations and diploma papers. Previously unpublished data from the Thermodynamic Department of the former Merseburg-University and the author's own data sets are included. The VLE-data are divided into three chapters: vapour pressures of binary polymer solutions (or solvent activities); segment-molar excess Gibbs free energies of binary polymer solutions (in the form of Redlich-Kister parameters); and weight fraction Henry-constants for gases and vapours in molten polymers (from inverse gas-liquid chromatography measurements).
A short introduction to the experimental methods and data reduction is included as Chapter 1. There are indices for the polymers and solvents cited.
More details
Series
Language
English
Place of publication
Oxford
United Kingdom
Publishing group
Elsevier Science & Technology
Target group
College/higher education
Professional and scholarly
Illustrations
references, indices
Dimensions
Height: 230 mm
ISBN-13
978-0-444-81717-4 (9780444817174)
Copyright in bibliographic data is held by Nielsen Book Services Limited or its licensors: all rights reserved.
Schweitzer Classification
Content
General objectives; experimental methods; measures for the polymer concentration; segment-molar excess Gibbs free energies; how to use the data tables; vapour pressures of binary polymer solutions; Redlich-Kister parameters for the segment-molar excess Gibbs free energies of binary polymer solutions; weight fraction Henry-constants of gases and vapours in molten polymers.