Investigation of Rates and Mechanisms of Reactions: v.6

For over 25 years, Investigation of Rates and Mechanisms of Reactions has been a preeminent source of guidance for research chemists, biochemists, and advanced students engaged in this active area of chemical research. Previous editions have introduced significant methods that have contributed to our understanding of chemical transformations at the molecular level. Now, the 4th Edition of this reference work provides an updated review of current kinetic and non-kinetic methods for investigating reaction mechanisms. Part I of this two-part series deals with general considerations and theoretical aspects of mechanistic studies and with experimental techniques suitable for the study of reactions occurring at conventional rates. 16 chapters contributed by internationally recognized authorities cover a wide range of topics, including kinetics in solution, kinetics in the gas phase, kinetics in heterogeneous systems, transition state theory, kinetic isotope effects, catalysis by small molecules and enzymes, kinetics of complex reactions, linear free energy relationships, and non-kinetic methods such as stereo-chemical studies and the use of tracers and computers.