Crystallographic Statistics in Chemical Physics
An Approach to Statistical Evaluation of Internuclear Distances in Transition Element Compounds
Published on 10. October 2012
Book
Paperback/Softback
X, 185 pages
978-3-662-01601-5 (ISBN)
Description
This book introduces the concept of crystallographic non-
rigidity and asymmetry of the transition elements as central
atoms organometallic compounds. This intrinsic behavior of
central atoms in condensed matter is quantified by applying
statistical approach. Averaging of extrinsic factors in
crystal structures is tested by using variance analysis.
Introductionof the above mentioned concept and applications
of variance analysis as an approximation for considering
factors influencing properties of central atomin the
crystal is original and new.
More details
Series
Edition
Softcover reprint of the original 1st ed. 1988
Language
English
Place of publication
Berlin
Germany
Publishing group
Springer Berlin
Target group
Professional and scholarly
Research
Illustrations
X, 185 p.
Dimensions
Height: 244 mm
Width: 170 mm
Thickness: 11 mm
Weight
349 gr
ISBN-13
978-3-662-01601-5 (9783662016015)
DOI
10.1007/978-3-662-01599-5
Schweitzer Classification
Other editions
Additional editions
Fedor Valach | Jan Ondracek | Milan Melnik
Crystallographic Statistics in Chemical Physics
An Approach to Statistical Evaluation of Internuclear Distances in Transition Element Compounds
Book
09/1988
Springer
€85.59
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Content
1 Statistics of Interatomic Distances.- 1.1 Some Statistical Concepts and Inferences.- 1.2 Statistics of Lengths of Interatomic Vectors.- Glossary of Symbols.- 1.3 References.- 2 Factors Influencing the Dispersion of Lengths of Interatomic Vectors.- 2.1 Application of Variance Analysis.- 2.2 Nonrigid Behavior of Central Monatomic Entities.- Glossary of Symbols.- 2.3 References.- 3 Statistics of Crystallographic Sites of Central Monatomic Entities.- 3.1 Crystallographic Sites.- 3.2 Lattice Complexes.- 3.3 Domains of Influence and Lattice Complexes.- 3.4 Matrix Representations of Symmetry Point Groups of Crystallographic Sites.- 3.5 Occurence of Central Monatomic Entities in Sites of Weissenberg Lattice Complexes.- Glossary of Symbols.- 3.6 References.- 4 Statistics of Bond Distances Between Central Monatomic Entities and Ligands.- 4.1 Terms of Monatomic Entities of Transition Elements and Splitting of their Energy Levels in the Crystal Field.- 4.2 Cu(II) Compounds.- 4.3 Ag(I) Compounds.- 4.4 Cd(II) Compounds.- 4.5 Fe(II) Compounds.- 4.6 Cr(III), Mo(V), Pd(II), Co(III), Ni(II), Zn(II), Nd(III), and Hg(II) Compounds.- Glossary of Symbols.- 4.7 References.- 5 Conclusions.- 5.1 References.- Chemical Abbreviations.- Appendix A.- References.- Appendix B.- Appendix C.- Appendix D.