Mossbauer Spectroscopy

Preface xix Contributors xxi Chapter 1 In-Situ Mössbauer Spectroscopy with Synchrotron Radiation on Thin Films 3 S Stankov, T Zl'zak, M Zajc, M Zl'zak, M Sladecek, R Röhlsberger, B. Sepiol, G Vogl, N Spiridis, J Aa|ewski, K ParliDski, and J Korecki 1 1 Introduction 3 References 39 Chapter 2 Mössbauer Spectroscopy in Studying Electronic Spin and Valence States of Ironin the Earth's Lower Mantle 43 Jung-Fu Lin, Zhu Mao, and Ercan E Alp Acknowledgments 55 References 55 Chapter 3 In-beam Mössbauer Spectroscopy Using a Radioisotope Beam and a Neutron Capture Reaction 58 Yoshio Kobayashi 3 .4 Summary 66 References 67 Part II Radionuclides 71 Chapter 4 Lanthanides(151Eu and 155Gd)-Mössbauer Spectroscopic Study of Defect-FluoriteOxides Coupled with New Defect-Crystal-Chemistry Model 73 Nakamura, N Igawa, Y Okamoto, Y Hinatsu, J, Wang, M Takahashi and M. Takeda Conclusion 92 References 93 Chapter 5 Mössbauer and Magnetic Study of Neptunyl(+1) Complexes 95 T Nakamoto, A Nakamura and M Takeda Conclusion 113 Acknowledgment 113 References 113 Chapter 6 Mössbauer Spectroscopy of 161Dy in Dysprosium Dicarboxylates 116 M Takahashi, C I Wynter, B R Hillery, Virender K Sharma, D Quarless, Leopold May, T Misu, S G Sobel, M Takeda, and E Brown Acknowledgment 122 References 122 Chapter 7 Study of Exotic Uranium Compounds using 238U Mössbauer Spectroscopy 123 Satoshi Tsutsui 1,2 and Masami Nakada 1 Summary 137 Acknowledgment 138 References 138 Part III Spin Dynamics 141 Chapter 8 Reversible Spin-state Switching Involving a Structural Change 143 Satoru Nakashima References 151 Chapter 9 Spin- Crossover and Related Phenomena Coupled with Spin, Photon and Charge 152 N Kokima and A Sugahara 9 3 Charge Transfer Phase Transition 161 9 4 Spin Equilibrium and Succeeding Phenomena 168 References 175 Chapter 10 Spin Crossover in Iron(III) Porphyrins Involving the Intermediate-Spin State 177 Mikio Nakamura and Masashi Takahashi Acknowledgments 198 References 199 Chapter 11 Tin(II) Lone Pair Stereoactivity: Influence on Structures and Properties, and Mössbauer Spectroscopic Properties 202 Georges Dénès, M Cecilia Madamba, Hocine Merazigand Abdualhafed Muntasar 216 Acknowledgments 243 References 243 Part IV Biological Applications 247 Chapter 12 Synchrotron Radiation Based Nuclear Resonant Scattering: Applications to Bioinorganic Chemistry 249 Yisong Guo, Yoshitaka Yoda, Xiaowei Zhang, Yuming Xiao, Stephen P Cram Acknowledgment 269 References 269 Chapter 13 Mössbauer Spectroscopy in Biological and Biomedical Research 272 Alexander A Kamnev,*, Krisztina Kovács, Irina V Alenkina, and Michael I. Oshtrakh Acknowledgments 287 References 287 Chapter 14 Controlled Spontaneous Decay of Mossbauer Nuclei (Theory and Experiments) 292 Vladimir I Vysotskii and Alla A Kornilova References 314 Chapter 15 Natural's Strategy to Oxidize Tryptophan: EPR and Mossbauer Characterization of High-Valent Fe Intermediates 315 Kednerlin Dornevil and Aimin Liu References 322 Chapter 16 Iron in Neurodegeneration 324 Jolanta GaBzka-Friedman, Erika R Bauminger, and Andrzej Friedman References 331 Chapter 17 Emission (57Co) Mössbauer Spectroscopy: Biology-related Applications, Potentials and Prospects 333 Alexander A Kamnev Acknowledgments 345 References 346 Part V Iron Oxides 349 Chapter 18 Mossbauer Spectroscopy in Study of Nanocrystalline Iron Oxides from Thermal Processes 351 JiYí Tu ek, Libor Machala, JiYí Frydrych, JiYí Pechousek, and Radek ZboYil Acknowledgment 389 References 389 Chapter 19 Transmission and Emission 57Fe Mössbauer Studies on Perovskites and Related Oxide Systems 393 Zoltán Homonnay and Zoltán Németh References 413 Chapter 20 Enhancing the Possibilities of 57Fe Mössbauer Spectrometry to Study the Inherent Properties of Rust Layers 415 Karen E García, César A Barrero, Alvaro L Morales, and Jean-Marc Greneche Acknowledgments 426 References 426 Chapter 21 Application of Mössbauer Spectroscopy in Nanomagnetics 429 Lakshmi Nambakkat Conclusion 452 Acknowledgment 453 References 453 Chapter 22 Mössbauer Spectroscopy and Surface Analysis 455 José F Marco, J Ramón Gancedo, Matteo Monti and Juan de la Figuera Acknowledgments 468 References 468 Chapter 23 57Fe Mössbauer Spectroscopy in the Investigation of the Precipitation of Iron Oxides 470 Svetozar Music, Mira Ristic, and Stjepko Krehula Acknowledgment 496 References 497 Chapter 24 Ferrates (IV, V, and VI): Mössbauer Spectroscopy Characterization 505 Virender K Sharma, Yurii Perfiliev, Radek Zboril, Libor Machala, and Clive Wynter Acknowledgments 517 References 517 Chapter 25 Characterization of Dilute Iron-Doped Yttrium Aluminum Garnets by Mössbauer Spectrometry 521 Kiyoshi Nomura and Zoltán Németh Conclusion 531 Acknowledgment 532 References 532 Part VI Industrial Applications 533 Chapter 26 Some Mössbauer Studies of Fe-As Based High Temperature Superconductors 535 Amar Nath and Airat Khasanov Acknowledgment 541 References 541 Chapter 27 Mossbauer Study of New Electrically Conductive Glass 542 Tetsuaki Nishida and Shiro Kubuki Acknowledgments 551 References 551 Chapter 28 Applications of Mössbauer Spectroscopy in the Study of Lithium Battery Materials 552 Ricardo Alcántara, Pedro Lavela, Carlos Pérez Vicente, José L Tirado Conclusions 561 Acknowledgment 561 References 562 Chapter 29 Mössbauer Spectroscopic Investigations of Novel Bimetal Catalysts for Preferential CO Oxidation in H2 564 Wansheng Zhang, Junhu Wang, Kuo Liu, Jie Jin, and Tao Zhang Conclusion 574 Acknowledgments 574 References 575 Chapter 30 The use of Mossbauer Spectroscopy in Coal Research-Is it Relevant or Not? 576 F B Waanders Conclusions 590 References 591 Part VII Environmental Applications 593 Chapter 31 Water Purification and Characterization of Recycled Iron-Silicate Glass 595 Shiro Kubuki and Tetsuaki Nishida Reference 606 Chapter 32 Mössbauer Spectroscopy in the Study of Laterite Mineral Processing 608 Eamonn Devlin, Michail Samouhos, Charalabos Zografidis Reference 619 Index 621