Thermodynamic Data on Oxides and Silicates
An Assessed Data Set Based on Thermochemistry and High Pressure Phase Equilibrium
Published on 17. September 1993
Book
Hardback
VIII, 428 pages
978-3-540-56898-8 (ISBN)
Description
This text aims to provide a consistent thermodynamic base of data which can be used globally for any pressure and temperature on Earth. In recent years, technical developments in the precise measurements of the thermochemical properties of substances and phase equilibrium experiments has been matched by an increased sophistication in applying theoretical methods to obtain new data. The book should be useful not only to scientists who need phase equilibrium computation at room temperature and pressure, but also to chemists, physicists, metallurgists, material scientists and geologists who require the temperature and high pressure properties of solids.
More details
Language
English
Place of publication
Heidelberg
Germany
Publishing group
Springer Berlin
Target group
College/higher education
Professional and scholarly
Illustrations
biography
Dimensions
Height: 23.5 cm
Width: 15.5 cm
Weight
800 gr
ISBN-13
978-3-540-56898-8 (9783540568988)
DOI
10.1007/978-3-642-78332-6
Schweitzer Classification
Other editions
Additional editions
Surendra K. Saxena | Nilanjan Chatterjee | Yingwei Fei
Thermodynamic Data on Oxides and Silicates
An Assessed Data Set Based on Thermochemistry and High Pressure Phase Equilibrium
E-Book
12/2012
Springer
€96.29
Available for download
Surendra K. Saxena | Nilanjan Chatterjee | Yingwei Fei
Thermodynamic Data on Oxides and Silicates
An Assessed Data Set Based on Thermochemistry and High Pressure Phase Equilibrium
Book
12/2011
Springer
€106.99
Shipment within 7-9 days
Content
1. Introduction: Thermodynamic Data Systematics.- 2. Thermodynamic Relations.- Temperature and pressure dependence of the Gibbs free energy.- Heat capacity at high temperature.- Estimation of Cv.- Method of optimization.- Anderson's enthalpy/bulk modulus relationship.- Some comparisons.- Molar volume at high pressure and high temperature.- The use of the Birch-Murnaghan (BM) equation at high temperature.- Comparison with Anderson's model.- 3. Techniques for Data Assessment.- Computational techniques.- The manual adjustment approach using free energy minimization.- The regression technique.- The optimization technique.- Phase equilibrium calculation by SOLGASMIX.- 4. Assessment of Data on Some Oxides and Silicates: Calorimetry and Low-pressure Phase Equilibrium Experiments.- The system Si02.- Andalusite, kyanite and sillimanite.- Wollastonite, gehlenite, akermanite and monticellite.- Enstatite and pyrope.- Forsterite.- Fayalite and ferrosilite.- Orthodiopside.- Clinoenstatite.- Diopside.- Hedenbergite.- Ca-tschermak, anorthite and grossular.- Almandine and hercynite.- Spessartine.- Rutile and ilmenite.- Sanidine and muscovite.- Jadeite, albite and paragonite.- Phlogopite.- Annite and phlogopite-annite solution.- Talc and anthophyllite.- Brucite, chrysotile and antigorite.- Grunerite.- Ferrocordierite and the cordierite-ferrocordierite solution.- Hydrous cordierite.- 5. Assessment of Data on Some Oxides and Silicates: Calorimetry and High-Pressure Phase Equilibrium Experiments.- System Fe-0.- Polymorphism of Fe.- Wustite.- Magnetite and hematite.- System MgO-SiO2.- Polymorphism of SiO2.- Polymorphism of Mg2Si04.- Polymorphism of MgSi03.- System FeO-SiO2.- Polymorphism of Fe2SiO4.- Polymorphism of FeSiO3,.- 6. Assessment of Solid Solution Parameters for Some Silicates.- Solid solution models.- Gehlenite-akermanite.- Spinel-hercynite.- Forsterite-fayalite.- Forsterite-monticellite.- Fayalite-monticellite.- Enstatite-ferrosilite.- Enstatite-diopside.- Clinoenstatite-jadeite.- Diopside-jadeite and hedenbergite-jadeite.- Muscovite-paragonite.- Phlogopite-annite.- Cordierite-ferrocordierite.- Cordierite-hydrous cordierite and ferrocordierite-hydrous cordierite.- Anorthite-albite, anorthite-sanidine and albite-sanidine.- Interaction parameters.- References.- Appendix I: Tables of Thermodynamic Data.- Appendix II: Summary of Reactions in the Mg-Fe-Si-O system.- Species Index.