Comprehensive Organic Functional Group Transformations, Volume 3
Synthesis: Carbon with One Heteroatom Attached by a Multiple Bond
Published on 21. March 2003
Book
Hardback
960 pages
978-0-08-042324-1 (ISBN)
Description
Volume 3 summarises contemporary methods for the synthesis of functional groups where carbon is attached to a heteroatom (notably oxygen, nitrogen, and sulphur) by a double or triple bond. The synthesis of all types of carbon and heteroatom substituted, and unsaturated derivatives are brought together in a coherent fashion, and where possible emphasis has been placed on selectivity and efficiency, together with practical applications in real situations in synthetic chemistry. Thus, the Volume covers synthetic methods for aldehydes and ketones, together with their sulphur (ie. thioaldehydes and thioketones), selenium, tellurium, nitrogen (ie. imines, oximes and hydrazones, including iminium salts and diazo compounds), phosphorus and metal/metalloid analogues. Synthetic methods for heteroatom substituted aldehydes and ketones and their analogues, eg. carbonyl ylides, are also included, and a thorough account of
ketenes and ketenimines and their various heteroatom and metal analogues is given. The Volume also covers the unique chemistry associated with the synthesis of nitriles and N-substituted nitriles, together with isonitriles and all their heteroanalogues.
ketenes and ketenimines and their various heteroatom and metal analogues is given. The Volume also covers the unique chemistry associated with the synthesis of nitriles and N-substituted nitriles, together with isonitriles and all their heteroanalogues.
More details
Series
Language
English
Place of publication
London
United Kingdom
Publishing group
Elsevier Science & Technology
Target group
Professional and scholarly
Illustrations
Illustrations
Weight
2310 gr
ISBN-13
978-0-08-042324-1 (9780080423241)
Copyright in bibliographic data is held by Nielsen Book Services Limited or its licensors: all rights reserved.
Schweitzer Classification
Person
Content
Aldehydes: alkyl aldehydes (K.E.B. Parkes, S. Richardson). &agr;&bgr;-unsaturated aldehydes (W. Ebenezer, P. Wight).
Aryl and heteroaryl aldehydes (D.G. Hollingworth, D. Walter).
Ketones: dialkyl ketones (K.E. Parkes, S. Richardson).
&agr;&bgr;-unsaturated ketones (W. Ebenezer, P. Wight).
Ketones bearing an &agr;, &bgr;-aryl or -heteroaryl substituent (D.G. Hollingworth, D. Walter).
O-substituted aldehydes and ketones (D.A. Whiting).
Thioaldehydes and thioketones (W. Whittingham).
Selenio- and tellurio-aldehydes and ketones (F.S. Guziec, L. Guziec).
Imines and their N-substituted derivatives: NH, NR and N- haloimines (G.M. Robertson).
Imines and their N-substituted derivatives: oximes and their S, Se and Te analogues (R.C.F. Jones).
Imines and their N-substituted derivatives: hydrazones and other =NN derivatives including diazo- compounds (J.S. Clark).
P, As, Sb, and Bi ylides (D. Gilheany, E. Coyne).
Doubly bonded metalloid functions (Si, Ge, B) (M.A. McKervey, Tao Ye).
Doubly bonded metal functions (M.A. McKervey, Tao Ye).
Ketenes, their cumulene analogues and their S, Se and Te analogues (D. Harrowven).
Ketenimines and their P, As, Sb and Bi analogues (J.P. Michael, C.B. De Koning). Nitriles: general methods and aliphatic nitriles (M. North).
Nitriles: &agr;&bgr;-unsaturated and aryl nitriles (M.J. Kiefel).
N-substituted nitriles and other heteroanalogues of nitriles of the type RCZ (R.M. Paton).
Isocyanides and their heteroanalogues (RZC) (I.A. O'Neil).
Aryl and heteroaryl aldehydes (D.G. Hollingworth, D. Walter).
Ketones: dialkyl ketones (K.E. Parkes, S. Richardson).
&agr;&bgr;-unsaturated ketones (W. Ebenezer, P. Wight).
Ketones bearing an &agr;, &bgr;-aryl or -heteroaryl substituent (D.G. Hollingworth, D. Walter).
O-substituted aldehydes and ketones (D.A. Whiting).
Thioaldehydes and thioketones (W. Whittingham).
Selenio- and tellurio-aldehydes and ketones (F.S. Guziec, L. Guziec).
Imines and their N-substituted derivatives: NH, NR and N- haloimines (G.M. Robertson).
Imines and their N-substituted derivatives: oximes and their S, Se and Te analogues (R.C.F. Jones).
Imines and their N-substituted derivatives: hydrazones and other =NN derivatives including diazo- compounds (J.S. Clark).
P, As, Sb, and Bi ylides (D. Gilheany, E. Coyne).
Doubly bonded metalloid functions (Si, Ge, B) (M.A. McKervey, Tao Ye).
Doubly bonded metal functions (M.A. McKervey, Tao Ye).
Ketenes, their cumulene analogues and their S, Se and Te analogues (D. Harrowven).
Ketenimines and their P, As, Sb and Bi analogues (J.P. Michael, C.B. De Koning). Nitriles: general methods and aliphatic nitriles (M. North).
Nitriles: &agr;&bgr;-unsaturated and aryl nitriles (M.J. Kiefel).
N-substituted nitriles and other heteroanalogues of nitriles of the type RCZ (R.M. Paton).
Isocyanides and their heteroanalogues (RZC) (I.A. O'Neil).