The Chemistry of Hypervalent Halogen Compounds, 2 Volume Set
1st Edition
Published on 15. March 2019
Book
Hardback
1072 pages
978-1-119-35230-3 (ISBN)
Description
The understanding of functional groups is the key to understanding organic chemistry. In the tradition of Patai's Chemistry of Functional Groups each volume treats all aspects of functional groups, touching on theoretical, analytical, synthetic, biological, and industrial aspects. Hypervalent halogen compounds, in particular iodine compounds, are very efficient and selective oxidants which tolerate a wide range of functional groups. The electrophilic properties of these reagents can also be used to introduce other functionalizations. The present volume is the first in the series to survey the properties and chemical behaviour of hypervalent iodine and bromine, their use in organic synthesis, as well as their industrial application. As with all new volumes, the chapters are first published online in Patai's Chemistry of Functional Groups. Once a volume is completed online, it is then published in print format. The printed book offers the traditional quality of the Patai Book Series, complete with an extensive index.
More details
Persons
Professor Berit Olofsson, Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, Stockholm, Sweden.
Professor Ilan Marek, Department of Chemistry Technion - Israel Institute of Technology, Haifa, Israel.
Professor Zvi Rappoport, Institute of Chemistry The Hebrew University of Jerusalem, Jerusalem, Israel.
Professor Ilan Marek, Department of Chemistry Technion - Israel Institute of Technology, Haifa, Israel.
Professor Zvi Rappoport, Institute of Chemistry The Hebrew University of Jerusalem, Jerusalem, Israel.
Content
1. Fundamental aspects of structure, bonding, and the reactivity of hypervalent iodine compounds 1
Halua Pinto de Magalhaes, Oliver Sala, and Hans Peter Luethi
2. Structural chemistry of hypervalent iodine compounds 31
Michael W. Justik
3. Aspects of the chemical energetics of the hypervalent benzene-based organohalogen halosyl, halyl, and perhalyl species 119
Maja Ponikvar-Svet Joel F. Liebman
4. Mass spectrometry and gas-phase ion chemistry of hypervalent halogen compounds 141
Richard A. J. O'hair
5. NMR of hypervalent iodine compounds 187
Yichen Wu and Alexandr Shafir
6. Synthesis of hypervalent iodine compounds for oxidation reactions 221
Viktor V. Zhdankin
7. Oxidation of alcohols and amines 261
Muhammet Uyanik and Kazuaki Ishihara
8. Oxidative heteroatom-heteroatom bond formation 307
Luis Bering and Andrey P. Antonchick
9. Carbon-heteroatom bond formation mediated by hypervalent iodine 365
Rafael M. Romero and Kilian Muniz
10. Halogenation and perfluoroalkylation chemistry using hypervalent halogen compounds 409
Dmitry Katayev, Benson Jelier, and Antonio Togni
11. Arylations promoted by hypervalent iodine reagents 461
Piret Villo and Berit Olofsson
12. Alkynylations and vinylations 523
Durga Prasad Hari, Stefano Nicolai, and Jerome Waser
13. Oxidative C?C bond formation (couplings, cyclizations, cyclopropanation, etc.) 581
Toshifumi Dohi and Yasuyuki Kita
14. Rearrangements and fragmentations mediated by hypervalent iodine reagents 665
Sarah E. Wengryniuk, and Sylvain Canesi
15. Industrial applications 707
Tatsuo Kaiho and Viktor V. Zhdankin
16. Hypervalent iodine compounds as precursors for biomedical radiotracers 721
Sanjay Telu, Fabrice G. Simeon, Shuiyu Lu and Victor W. Pike
17. Chemistry of hypervalent bromine 781
Kazunori Miyamoto
18. Stereoselective reactions 807
Fateh V. Singh and ThomasWirth
19. Photochemistry of hypervalent iodine compounds 855
Kunfang Jia and Yiyun Chen
20. Electrochemistry of hypervalent iodine compounds 897
Robert Francke, Timo Broese, and Arend F. Roesel
21. Transition metal-catalyzed reactions with iodine(III) reagents 919
Gergely L. Tolnai, Zsombor Gonda, and Zoltan Novak
Subject index 987
Halua Pinto de Magalhaes, Oliver Sala, and Hans Peter Luethi
2. Structural chemistry of hypervalent iodine compounds 31
Michael W. Justik
3. Aspects of the chemical energetics of the hypervalent benzene-based organohalogen halosyl, halyl, and perhalyl species 119
Maja Ponikvar-Svet Joel F. Liebman
4. Mass spectrometry and gas-phase ion chemistry of hypervalent halogen compounds 141
Richard A. J. O'hair
5. NMR of hypervalent iodine compounds 187
Yichen Wu and Alexandr Shafir
6. Synthesis of hypervalent iodine compounds for oxidation reactions 221
Viktor V. Zhdankin
7. Oxidation of alcohols and amines 261
Muhammet Uyanik and Kazuaki Ishihara
8. Oxidative heteroatom-heteroatom bond formation 307
Luis Bering and Andrey P. Antonchick
9. Carbon-heteroatom bond formation mediated by hypervalent iodine 365
Rafael M. Romero and Kilian Muniz
10. Halogenation and perfluoroalkylation chemistry using hypervalent halogen compounds 409
Dmitry Katayev, Benson Jelier, and Antonio Togni
11. Arylations promoted by hypervalent iodine reagents 461
Piret Villo and Berit Olofsson
12. Alkynylations and vinylations 523
Durga Prasad Hari, Stefano Nicolai, and Jerome Waser
13. Oxidative C?C bond formation (couplings, cyclizations, cyclopropanation, etc.) 581
Toshifumi Dohi and Yasuyuki Kita
14. Rearrangements and fragmentations mediated by hypervalent iodine reagents 665
Sarah E. Wengryniuk, and Sylvain Canesi
15. Industrial applications 707
Tatsuo Kaiho and Viktor V. Zhdankin
16. Hypervalent iodine compounds as precursors for biomedical radiotracers 721
Sanjay Telu, Fabrice G. Simeon, Shuiyu Lu and Victor W. Pike
17. Chemistry of hypervalent bromine 781
Kazunori Miyamoto
18. Stereoselective reactions 807
Fateh V. Singh and ThomasWirth
19. Photochemistry of hypervalent iodine compounds 855
Kunfang Jia and Yiyun Chen
20. Electrochemistry of hypervalent iodine compounds 897
Robert Francke, Timo Broese, and Arend F. Roesel
21. Transition metal-catalyzed reactions with iodine(III) reagents 919
Gergely L. Tolnai, Zsombor Gonda, and Zoltan Novak
Subject index 987