Comprehensive Organic Functional Group Transformations, Volume 2
Synthesis: Carbon with One Heteroatom Attached by a Single Bond
Published on 21. March 2003
Book
Hardback
1460 pages
978-0-08-042323-4 (ISBN)
Description
This Volume describes all methods for the synthesis of compounds containing a
carbon atom singly bonded to a heteroatom substituent. The Volume is arranged in three parts dealing with sp3, sp2 and sp carbon linked to the heteroatoms. For each section careful attention has been given to various features such as substitution patterns, ring effects, strain effects, neighbouring functionality, stereochemistry, etc. which could mediate the synthesis pathway. Emphasis has also been given to the most convenient and practical preparation of the various functional groups. Critical assessment of
the procedures allows the reader to select methods most appropriate for their needs. In this Volume the heteroatom may also be metallic and therefore reflect a highly polarised bonding arrangement with the carbon substituent. Compounds containing single bonds between carbon and heterofunctional groups constitute the largest class and most commonly transformed organic functional groups.
carbon atom singly bonded to a heteroatom substituent. The Volume is arranged in three parts dealing with sp3, sp2 and sp carbon linked to the heteroatoms. For each section careful attention has been given to various features such as substitution patterns, ring effects, strain effects, neighbouring functionality, stereochemistry, etc. which could mediate the synthesis pathway. Emphasis has also been given to the most convenient and practical preparation of the various functional groups. Critical assessment of
the procedures allows the reader to select methods most appropriate for their needs. In this Volume the heteroatom may also be metallic and therefore reflect a highly polarised bonding arrangement with the carbon substituent. Compounds containing single bonds between carbon and heterofunctional groups constitute the largest class and most commonly transformed organic functional groups.
More details
Series
Language
English
Place of publication
London
United Kingdom
Publishing group
Elsevier Science & Technology
Target group
Professional and scholarly
Illustrations
Illustrations
Weight
3300 gr
ISBN-13
978-0-08-042323-4 (9780080423234)
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Schweitzer Classification
Person
Content
Alkyl halides (P.L. Spargo). Alkyl chalcogenides: oxygen-based functional groups (J.B. Sweeney). Alkyl chalcogenides: sulphur-based functional groups (P.C.B. Page). Alkyl chalcogenides: selenium- and tellurium-based functional groups (T. Kataoka, M. Yoshimatsu). Alkylnitrogen compounds: amines and their salts (C.M. Marson, A.D. Hobson). Alkylnitrogen compounds: compounds with N-halogen, N-O, N-S, N-Se and N-Te functional groups (R. Bowman, R.J. Marmon). Alkylnitrogen compounds: compounds with N-N, N-P, N-As, N-Sb, N-Bi, N-Si, N-Ge, N-B and N-metal functional groups (P.R. Huddleston, I.G.C. Coutts). Alkylphosphorus compounds (J.C. Tebby, D. Genov, J.W. Wheeler). Alkyl arsenic, -antimony and -bismuth compounds (Mei-Xiang Wang). Alkyl -silicon, -germanium and -boron compounds (E.W. Colvin, M. Wills). Alkylmetals (S.V. Ley, C. Kouklovsky). Vinyl and aryl halides (C.J. Urch). Vinyl and aryl chalcogenides: oxygen-based functional groups (C.K-F. Chiu). Vinyl and aryl chalcogenides: sulphur-, selenium- and tellurium-based functional groups (P. Taylor). Vinyl- and aryl-nitrogen compounds (G. Sauve, V. Rao). Vinyl- and aryl phosphorus derivatives (T. Minami). Vinyl- and aryl arsenic, -antimony and -bismuth functions (R.W. Read). Vinyl- and aryl-silicon, -germanium and boron compounds (L. Hevesi). Vinyl- and aryl-metals (E. Negishi). Stabilized substituted ions and radicals bearing one heteroatom (S.D. Lindell). Alkynyl halides and chalcogenides (P.J. Stang, V.V. Zhdankin). Alkynyl nitrogen and -phosphorus compounds (K.I. Booker-Milburn). Alkynyl-arsenic, -antimony, -bismuth, -silicon, -germanium -boron and -metal compounds (W. Kitching, K. Kwetkat).