Science of Synthesis: Photocatalysis in Organic Synthesis
Description
The field of photocatalysis has developed rapidly over the last decade and it is time to clarify its impact on organic synthesis. This volume is an opportunity to provide the defining and current reference work for this field. A primary objective is to collect together the most useful, practical, and reliable methods for photocatalysis and to introduce them to a larger audience. The fundamental concepts of photophysics are introduduced and laboratory set-ups are described, enabling newcomers to the field to instantly apply these new tools in synthesis. Rather than aiming for comprehensive coverage, solutions for challenging transformations in synthesis applying visible light and suitable dyes are presented. A team of pioneers and leaders in the field has been assembled, who discuss both the practical and conceptual aspects of this rapidly growing field. Scope, limitations, and mechanism of the reactions are covered and key experimental procedures are included.
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Content
1 Introduction
2 Photocatalysis: The Principles
3 Practical Aspects of Photocatalysis
4 Photocatalytic Oxidative C-C Bond Formation
5 Decarboxylative Coupling Reactions
6 Proton-Coupled Electron Transfer
7 Organocatalysis with Amines in Photocatalysis
8 Copper-Based Photocatalysts for Visible-Light-Mediated Organic Transformations
9 Gold in Photocatalysis
10 Palladium in Photocatalysis
11 Nickel in Photocatalysis
12 Acridinium Dyes and Quinones in Photocatalysis
13 Flavins in Photocatalysis
14 Organic Dyes in Photocatalytic Reductive C-H Arylations
15 Silicates in Photocatalysis
16 Photocatalytic Cycloadditions
17 Photocatalytic Carbon-Heteroatom Bond Formation
18 Photocatalytic Introduction of Fluorinated Groups
19 Heterogeneous Photocatalysis in Organic Synthesis
20 Photocatalysis in the Pharmaceutical Industry