
Supercooled Liquids
Advances and Novel Applications
American Chemical Society (Publisher)
Published on 1. September 1997
Book
Hardback
356 pages
978-0-8412-3531-1 (ISBN)
Description
This book presents some of the most exciting recent work on supercooled liquids. Topics include domain models of supercooled liquids, inhomogeneity and polymorphism, and Mode-Coupling Theory and its applications. It provides in-depth coverage of supercooled water and of the connections between supercooled liquids and the conformational dynamics of proteins. The introduction includes a detailed discussion of terminology, major problems, and leading theoretical and experimental approaches.
More details
Series
Edition
Volume 676 ed.
Language
English
Place of publication
Washington
United States
Target group
Professional and scholarly
Illustrations
Illustrations
Dimensions
Height: 230 mm
Weight
608 gr
ISBN-13
978-0-8412-3531-1 (9780841235311)
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Schweitzer Classification
Content
INTRODUCTION; 1. A Brief Introduction to Supercooled Liquids; OVERVIEW; 2. The Viscous-Liquid Glassy-Solid Problem; THEORETICAL PERSPECTIVES ON SUPERCOOLED LIQUIDS; 3. The Mode-Coupling Theory of the Glass Transition; 4. Basic Physics of the Coupling Model: Direct Experimental Evidences; 5. Frustration-Limited Domain Theory of Supercooled Liquids and the Glass Transition; 6. Soft Modes in Glass-Forming Liquids: The Role of Local Stress; 7. Entropic Approach to Relaxation Behavior in Glass-Forming Liquids; 8. The Replica Approach to Glasses; 9. Growing Length Scales in Supercooled Liquids; 10. Shear Viscosity and Diffusion in Supercooled Liquids; 11. Phase Separation in Silicate Melts: Limits of Solubilities; EXPERIMENTAL ADVANCES IN SUPERCOOLED LIQUIDS; 12. Higher Order Time-Correlation Functions from Fluctuating Energy Landscape Models: Comparison with Reduced Four-Dimensional NMR Spectroscopy; 13. High-Frequency Dielectric Spectroscopy of Glass-Forming Liquids; 14. Structural Relaxation of Supercooled Liquids from Impulsive Stimulated Light Scattering; 15. Multiple Time Scales in the Nonpolar Solvation Dynamics of Supercooled Liquids; POLYAMORPHISM AND SUPERCOOLED WATER; 16. Polyamorphic Transitions in Network-Forming Liquids and Glasses; 17. Facts and Speculation Concerning Low-Temperature Polymorphism in Glass Formers; 18. Phase Diagram for Supercooled Water and Liquid-Liquid Transition; 19. The Liquid-Liquid Critical-Point Hypothesis; 20. Slow Dynamics in a Model and Real Supercooled Water; 21. Raman Evidence for the Clathrate-like Structure of Highly Supercooled Water; NOVEL APPLICATIONS: SUPERCOOLED LIQUIDS AND PROTEIN DYNAMICS; 22. Cold Denaturation of Proteins; 23. Vibrational Echo Studies of Heme-Protein Dynamics